potassium 9-anthracenecarboxylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: potassium 9-anthracenecarboxylate
• 英文别名: K(ant)；9-anthracenecarboxylic acid potassium salt；Potassium;anthracene-9-carboxylate；potassium;anthracene-9-carboxylate
• 化学式: C₁₅H₉O₂*K
• 分子量: 260.334
• InChiKey: WLZAKUFVOAPSLL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.64
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tri(chloro-3-propyl)-1,3,5 hexahydrotriazine 、 potassium 9-anthracenecarboxylate 在 亚硝酰氯 作用下， 以 二氯甲烷 为溶剂， 以0.17 g的产率得到[3-Chloropropyl(nitroso)amino]methyl anthracene-9-carboxylate
  参考文献：
  名称：

  Synthesis and properties of bifunctional chloroalkyl nitrosamines with an intercalating moiety

  摘要：

  Three N-nitroso-N-(arylcarbonyloxymethyl)-3-chloropropylamines were synthesized, and their chemical and biological properties were studied. All arylcarboxylates intercalated with double-stranded DNA, and their mutagenicity and DNA cross-linking activity were affected by their ring structure. The DNA interstrand cross-link formation increased dose dependently after treatment with the acridine analog. The anthraquinone analog showed the highest bacterial mutagenicity among the three nitrosamines in Salmonella typhimurium TA100, while in Salmonella typhimurium TA92, which can detect cross-linking agents, the acridine analog showed the highest mutagenicity. This agreed with the result of a cross-linking assay. These results suggest that the three-ring aromatic moiety gives DNA-intercalating ability to cross-linkable chloropropyl nitrosamine, and the acridine analog is considered as a possible new antitumor lead compound. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmc.2004.05.012
• 作为产物：
  描述：

  9-蒽甲酸 在 potassium hydroxide 作用下， 以 水 为溶剂， 生成 potassium 9-anthracenecarboxylate
  参考文献：
  名称：

  基于 Yb-Nd 配位化合物的近红外发光温度计，适用于 83-393 K 温度范围

  摘要：

  测试了具有 9-蒽酸根和 9-吖啶酸根阴离子的多金属钕-镱-钆化合物，以制造第一个用于高温的发光温度计。由于发射离子被 Gd 3+部分取代，从而实现了浓度猝灭消除，从而实现了高发光强度和高信号分辨率。结果，获得了基于镧系配位化合物（CCs）的宽温度范围（83-393 K）发光测温的近红外发射材料。Yb 0.02 Nd 0.12 Gd 0.86 (ant) 3表现出研究系统中最好的测温性能，其温度灵敏度达到1.8% K -1在 293–393 K 的温度范围内。

  DOI：

  10.1039/d2dt00147k

文献信息

• [EN] SILYL ALKYL ESTERS OF ANTHRACENE- AND PHENANTHRENE CARBOXYLIC ACIDS<br/>[FR] ESTERS ALKYLIQUES SILYLES D'ACIDES ANTHRACENE ET PHENANTHRENE-CARBOXYLIQUES
  申请人：HONEYWELL SPECIALTY CHEMICALS

  公开号：WO2004000853A1

  公开（公告）日：2003-12-31

  The invention relates to silyl alkyl esters, in particular of anthracene and phenanthrene carboxylic acids, a process for their preparation, compositions and polysiloxane compositions which contain the silyl alkyl esters and which can be used in particular in the semiconductor industry for the preparation of anti-reflective layers for photolithographic applications.

  本发明涉及硅烷基烷基酯，特别是蒽酸和菲酸的酯，其制备方法，以及含有硅烷基烷基酯的组合物和聚硅氧烷组合物。这些组合物可以用于半导体工业中的光刻应用中，用于制备抗反射层。
• Lanthanide 9-anthracenate: solution processable emitters for efficient purely NIR emitting host-free OLEDs
  作者：Valentina V. Utochnikova、Alena S. Kalyakina、Ivan S. Bushmarinov、Andrey A. Vashchenko、Lukasz Marciniak、Anna M. Kaczmarek、Rik Van Deun、Stefan Bräse、Natalia P. Kuzmina

  DOI：10.1039/c6tc03586h

  日期：——

  Searching for new NIR emitting materials, lanthanide 9-anthracenates Ln(ant)3 were synthesized and thoroughly characterized. Ytterbium 9-anthracenate Yb(ant)3, that demonstrated the highest NIR luminescence efficiency, was successfully used as an emission layer of a host-free OLED and its electroluminescence quantum efficiency, corresponding to the sole band at 1000 nm, reached 0.21%. This performance

  为了寻找新的近红外发射材料，合成了镧系元素9-蒽酸酯Ln（ant）3并对其进行了彻底的表征。NIR发光效率最高的9-蒽race Yb​​（ant）3被成功用作无主体OLED的发射层，其电致发光量子效率（对应于1000 nm处的唯一带）达到0.21％。Yb（ant）3的高量子产率可以达到这一性能，该量子产率达到1.5％，并且通过用Lu 3+部分取代Yb 3+而提高到2.5％。以及由于其晶体结构的扩展堆叠而具有的高电子迁移率。基于Gd（ant）3制备了第一个基于-的PHOLED 。
• Two-dimensional thallium(I) supramolecular polymer constructed from Tl⋯π interactions: A new precursor for the preparation of thallium(III) oxide with a nano-structural surface
  作者：Kamran Akhbari、Ali Morsali

  DOI：10.1016/j.poly.2011.02.021

  日期：2011.5

  A new two-dimensional thallium(I) supramolecular polymer, [Tl-2(mu(3)-9-Ac)(mu(4)-9-Ac)(H2O)](n) (1) [9-HAc = 9-anthracene carboxylic acid]. has been synthesized and characterized. The single-crystal X-ray data of compound 1 shows two types of Tl-1 ions with coordination numbers of four and five. The thallium atoms have irregular coordination spheres, containing a stereo-chemically active lone pair with eta(5) Tl center dot center dot center dot C interactions in the vacant coordination sphere of the Tl-1 ions, thus attaining total hapticities of 9 and 10 with O(5)Tl1 center dot center dot center dot C-5 and O(4)Tl2 center dot center dot center dot C-5 environments and Tl center dot center dot center dot pi((centroid)) distances of 3.308 and 3.251 angstrom, respectively. The thermal stability of 1 was studied by thermo gravimetric (TG) and differential thermal analyses (DTA). Different morphologies of thallium(III) oxide with a nano-structural surface were prepared from compound 1 powders and compound 1 micro-rods. These nano-structures were characterized by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). (C) 2011 Elsevier Ltd. All rights reserved.
• HALOBUTYL ELASTOMERS
  申请人：Lanxess Inc.

  公开号：EP1913077A1

  公开（公告）日：2008-04-23
• US8198379B2
  申请人：——

  公开号：US8198379B2

  公开（公告）日：2012-06-12