4,5-di(3'-carboxylphenyl)phthalic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,5-di(3'-carboxylphenyl)phthalic acid
• 英文别名: 1,1′:2′,1″-terphenyl-3,3″,4′,5′-tetracarboxylic acid；4,5-Bis(3-carboxyphenyl)phthalic acid；4,5-bis(3-carboxyphenyl)phthalic acid
• 化学式: C₂₂H₁₄O₈
• 分子量: 406.348
• InChiKey: IOBOGFBRJGCORH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  149
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 cobalt(II) perchlorate hydrate 、 4,5-di(3'-carboxylphenyl)phthalic acid 在 potassium hydroxide 作用下， 以 水 为溶剂， 反应 72.0h， 以24.7%的产率得到{[Co(H₂ttac)(1,10-phenanthroline)₂]*4H₂O}_n
  参考文献：
  名称：

  基于四羧酸的零，一，二维和三维配位聚合物：合成，结构，磁性和发光性质

  摘要：

  一系列配位聚合物，即{[Co（H 2 ttac）（phen）2 ] 4H 2 O} n（1），{[Zn（H 2 ttac）（phen）2 ] 4H 2 O} n（2），[Cu（H 2 ttac）（phen）] n（3），[Zn 2（ttac）（DMZ）H 2 O] n（4）和[Cd（ttac）（phen）H 2 O] n（5）（高4在水热条件下制备了ttac = 4,5-二（3'-羧基苯基）-邻苯二甲酸，phen = 1,10-菲咯啉，DMZ =二咪唑），并通过元素分析，红外光谱和单晶X射线表征衍射。结构分析表明，合成后的配位聚合物具有不同的结构，范围从零（1和2），一（3），二（4）到三（5）维，这主要是由于不同金属离子，去质子化程度和H 4 ttac配体的配位模式。值得一提的是，基于多样化的π – π叠加和/或C–H··· πh的相互作用4 TTAC配体和/或含氮的辅助配体，1 - 4

  DOI：

  10.1016/j.dyepig.2015.06.035

文献信息

• Two novel coordination polymers: Synthesis, structure, luminescent properties, and selective sensing of Cu2+ and Mn2+ ions
  作者：C. Lian、X. Guo、Y. S. Long、L. R. Yang

  DOI：10.1134/s1070328417050037

  日期：2017.5

  Two novel coordination polymers, namely [Co(Ttac)0.5(1,4-Bib)(H2O)] · H2O}n (I) and [La(HTtac)2(2H2O)] · H2O}n (II) (H4Ttac = 4,5-di(3'-carboxylphenyl)-phthalic acid, 1,4-Bib = 1,4-bis(1-imidazoly) benzene), have been designed and successfully prepared via hydrothermal process, and characterized by elemental analyses, IR spectroscopy, and single crystal X-ray diffraction (CIF files CCDC nos. 1039298

  两种新型配位聚合物，即[Co（Ttac）0.5（1,4-Bib）（H 2 O）]·H 2 O} n（I）和[La（HTtac）2（2H 2 O）]· H 2 O} n（II）（H4Ttac = 4,5-二（3'-羧基苯基）-邻苯二甲酸，1,4-Bib = 1,4-双（1-咪唑基）苯）已成功设计并成功通过水热法制备，并通过元素分析，IR光谱和单晶X射线衍射进行表征（CIF文件CCDC No. 1039298（I），1039300（II））。结构分析表明，H 4 Ttac配体在合成时采用不同的配位方式I和II，因此产生具有不同构型的目标配位聚合物。值得一提的是，配位聚合物I通过π··π堆积相互作用从低维结构组装成三维（3D），而三维配位聚合物II由共价键形成。已经在环境温度下研究了配位聚合物II的发光特性。显着地，发光测量表明配位聚合物II可以充当针对Cu 2+和Mn 2+离子的潜在发光识别传感器。
• Two new Zn(II) and Ni(II) coordination polymers: treatment effect on acute bacterial sinusitis by inhibiting the methicillin resistant Staphylococcus aureus growth
  作者：Li-Ping Li、Xue Jiang、Lixiu Liu、Xiao-Dong Hu

  DOI：10.1080/24701556.2020.1813763

  日期：2021.7.3

  Abstract In this study, two new coordination polymers (CPs),[(CH3)2NH2][Zn(FDA)(TZ)2]}n (1, H2FDA = furan-2,5-dicarboxyl acid, TZ = 1,2,3-triazole) and [Ni2(H2O)3(HTTCA)]·H2O}n (2, H4TTCA = [1,1':2',1''-terphenyl]-3,3'',4',5'-tetracarboxylic acid), have been prepared under solvothermal conditions and characterized by single-crystal X-ray diffraction analyses successfully. Furthermore, the protective

  摘要 在这项研究中，两种新的配位聚合物（CPs）[（CH 3）2 NH 2 ] [Zn（FDA）（TZ）2 ]} n（1，H 2 FDA =呋喃-2,5-二羧酸， TZ = 1,2,3-三唑）和[Ni 2（H 2 O）3（HTTCA）]·H 2 O} n（2，H 4 TTCA = [1,1'：2'，1'' -三苯基] -3,3''，4'，5'-四羧酸）已在溶剂热条件下制备，并成功地通过单晶X射线衍射分析进行了表征。此外，化合物在体外和体内的保护作用被评估。首先，用化合物处理后测量细菌生长曲线。此外，用酶联免疫吸附试验（ELISA）检测试剂盒可检测血液中的炎性细胞因子。
• A series of divalent metal coordination polymers based on isomeric tetracarboxylic acids: synthesis, structures and magnetic properties
  作者：Min-Le Han、Ya-Ping Duan、Dong-Sheng Li、Guo-Wang Xu、Ya-Pan Wu、Jun Zhao

  DOI：10.1039/c4dt01946f

  日期：——

  A series of M(ii) coordination polymers has been synthesized. 1–3 contain 1D infinite chains, and these 1D chains are further linked by hydrogen bonding to form 3D supramolecular networks. While 4 and 5 show tetra- or penta-nodal 3D network, respectively.

  一系列M（II）配位聚合物已被合成。1-3包含1D无限链，并且这些1D链进一步通过氢键连接形成3D超分子网络。而4和5分别显示四或五节点的3D网络。
• New in situ generated acylhydrazidate-coordinated complexes and acylhydrazide molecules: Synthesis, structural characterization and photoluminescence property
  作者：Yan-Ning Wang、Qi-Sheng Huo、Ping Zhang、Jie-Hui Yu、Ji-Qing Xu

  DOI：10.1016/j.saa.2016.05.021

  日期：2016.10

  By utilizing the hydrothermal in situ acylation of organic acids with N2H4, three acylhydrazidate-coordinated compounds [mn(L1)(2)(H2O)(2)] (L1 = 2,3-quinolinedicarboxylhydrazidate; HL1 = 2,3-dihydropyridazino[4,5-b]quinoline-1,4-dione) 1, [Mn-2(ox)(L-2)(2)(H2O)(6)]center dot 2H(2)O (L2 = benzimidazolate-5,6-dicarboxylhydrazide; HL2 = 6,7-dihydro-1H-imidazo[4,5-g]phthalazine-5,8-dione; ox = oxalate) 2, and [Cd(HL3)(bpy)] (L3 = 4,5-di(3'-carboxylphenyl)phthalhydrazidate; H(3)L3 = 6,7-dihydro-1H-imidazo[4,5-g]phthalazine-5,8-dione; bpy = 2,2'-bipyridine) 3, as well as two acylhydrazide molecules L4 (L4 = oxepino[2,3,4-de:7,6,5-d'e']diphthalazine-4, 10(5H,9H)-dione) 4 and L5 (L5 = 4,5-dibromophthalhydrazide; L5 = 6,7-dibromo-2,3-dihydrophthalazine-1, 4-dione) 5 were obtained. X-ray single-crystal diffraction analysis reveals that (i) I only possesses a mononuclear structure, but it self-assembles into a 2-D supramolecular network via the N-hydrazine-H center dot center dot center dot N-hydrazine and Ow-H center dot center dot center dot O-hydroxylimino interactions; (ii) 2 exhibits a dinuclear structure. Ox acts as the linker, while L2 just serves as a terminal ligand; (iii) In 3,13 acts as a 3-connected node to propagate the 7-coordinated Cd2+ centers into a 1-D double-chain structure; (iv) 4 is a special acylhydrazide molecule. Two-OH groups for the intermediates 3,3'-biphthalhydrazide further lose one water molecule to form 4; (v) 5 is a common monoacylhydrazide molecule. Via the N-hydrazine-H center dot center dot center dot O-hydrazine, O-hydroxylimino-H center dot center dot center dot O-acylamino and the pi center dot center dot center dot pi interactions, it self-assembles into a 2-D supramolecular network. The photoluminescence analysis reveals that 4 emits light with the maxima at 510 nm. (C) 2016 Elsevier B.V. All rights reserved.
• Two new Co(II)-MOFs based on polymeric chain building units: Crystal structures, and magnetic properties
  作者：Min-Le Han、Ya-Pan Wu、Jun Zhao、Dong-Sheng Li、Yao-Yu Wang

  DOI：10.1016/j.jssc.2015.07.001

  日期：2015.10

  Two new Co(II) metal-organic frameworks, namely [Co-2(bpm)(H2O)(3)(L)](n) (1) and [Co(bpe)(H2O)(H2L)]center dot(bPe)(0.5)center dot(H2O)}(n) (2), (H4L = 1,1':2',1 ''-terphenyl-3,3 '',4',5'-tetracarboxylic acid, bpm = bis(4-pyridyl)amine, bpe = 1,2-bis(4-pyridyl)ethene), have been obtained under hydrothermal conditions. Both complexes 1 and 2 have been characterized by elemental analysis, IR spectra, single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), and thermogravimetric analysis (TGA). Complexes 1 and 2 consist of 1D Co(II) chains bridging by carboxylate groups in syn-anti fashion. I shows a novel 3D tri-nodal (4,6,10)-connected net with a (3.4(3).5(2))(2)(3(2).4(14).5(12).6(12).7(4).8)(3(2).4(2).5(5).6(4).7(2)) topology. While 2 exhibits a 2D sql layer. Magnetic susceptibility measurements indicate that both 1 and 2 show weak antiferromagnetic interactions between the adjacent Co(II) ions in 300-8 K for 1 and 300-16 K for 2, respectively, and then 2 also displays ferromagnetic coupling at lower temperatures. Crown Copyright (C) 2015 Published by Elsevier Inc. All rights reserved.