benzylacetylacetonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzylacetylacetonate
• 英文别名: ba(1-)；3-Oxo-1-phenylbut-1-en-1-olate
• 化学式: C₁₀H₉O₂
• 分子量: 161.18
• InChiKey: MPRZBJONKJDMJV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  lead acetate 、 benzylacetylacetonate 以 甲醇 为溶剂， 以85%的产率得到[Pb2(μ3-benzylacetylacetonate)2(μ2-benzylacetylactonate)2]
  参考文献：
  名称：

  Structural and X-ray powder diffraction studies of nano-structured lead(II) coordination polymer with η2 Pb⋯C interactions

  摘要：

  A new nano-sized Pb(II) one-dimensional coordination polymer with eta(2) Pb-C interactions, [Pb-2 (mu(3)-ba)(2)(mu(2)-ba)(2)](n) (1) [ba = benzylacetylacetonate] has been synthesized and characterized by SEM, X-ray powder diffraction, IR spectroscopy and elemental analyses. Single-crystal X-ray diffraction shows the coordination number of Pb(II) ions is seven and the lead atoms have hemidirected coordination sphere containing involving Pb center dot center dot center dot C interactions, C2O7Pb. PbO nanoparticles were obtained by calcinations of the nano-sized compound 1 at 600 degrees C. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.07.016