二(2,3,4,5,6-五氯苯基)草酸酯 | 1173-75-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 二(2,3,4,5,6-五氯苯基)草酸酯
• 中文别名: 双(五氯苯基)草酸酯；双(五溴氯苯基)草酸
• 英文名称: Bis--oxalat
• 英文别名: Oxalsaeure-bis-pentachlorphenylester；bis(pentachlorophenyl) oxalate；bis(2,3,4,5,6-pentachlorophenyl) oxalate
• CAS: 1173-75-7
• 化学式: C₁₄Cl₁₀O₄
• 分子量: 586.682
• InChiKey: OXTSSJOQCJZYLA-UHFFFAOYSA-N

物化性质

• 熔点：
  232-233 °C(Solv: 1,2-dichloroethane (107-06-2))
• 沸点：
  598.3±50.0 °C(Predicted)
• 密度：
  1.879±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.8
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2917119000

反应信息

• 作为反应物：
  描述：

  己二酸 、 二(2,3,4,5,6-五氯苯基)草酸酯 以80%的产率得到
  参考文献：
  名称：

  KATSARAVA, R. D.;XARADZE, D. P.;AVALISHVILI, L. M.;ZAALISHVILI, M. M., IZV. AN GSSR. CEP. XIM., 1982, 8, N 2, 102-109

  摘要：

  DOI：
• 作为产物：
  描述：

  五氯酚 、 草酰氯 在 三乙胺 作用下， 生成 二(2,3,4,5,6-五氯苯基)草酸酯
  参考文献：
  名称：

  Chemiluminescence from reactions of electronegatively substituted aryl oxalates with hydrogen peroxide and fluorescent compounds

  摘要：

  DOI：

  10.1021/ja01001a025

文献信息

• Solid, thin chemiluminescent device
  申请人：OMNIGLOW CORPORATION

  公开号：EP0492053A1

  公开（公告）日：1992-07-01

  There is provided a flexible, thin, rectangular, chemiluminescent device comprised of a back sheet of a laminated metal foil having heat sealed thereto at its edges a bi-component front sheet, the first component of which is a laminated metal foil and the second component of which is a transparent or translucent polyolefin sheet, said first and second components being heat sealed to each other at their adjacent latitudinal edge, from about 20% to about 50% of the surface area of said front sheet being comprised of said first component; temporary separation means positioned so as to divide the interior area of said device into two compartments, one under each of said components, the compartment under said second component having positioned therein an absorbent material containing a solvent solution of an oxalate and, optionally, a fluorescer, and the compartment under said first component containing an activator solution.

  提供了一种柔性、薄型、矩形的化学发光装置，该装置由层压金属箔背板和双组分前板组成，前板的第一组分是层压金属箔，第二组分是透明或半透明聚烯烃板，第一组分和第二组分在相邻的纬向边缘热封，前板表面积的约20%至约50%由第一组分组成；临时分隔装置，其作用是将所述装置的内部区域分成两个隔间，每个隔间位于所述组件的下方，所述第二组件下方的隔间内放置有吸收材料，其中含有草酸盐溶剂溶液和可选的荧光剂，而所述第一组件下方的隔间内则含有活化剂溶液。
• A porous, flexible structure for chemiluminescent device
  申请人：OMNIGLOW CORPORATION

  公开号：EP0663560A2

  公开（公告）日：1995-07-19

  The present invention provides a porous, flexible structure comprising A) a non-particulate phase comprising a vinyl halide or vinylidene halide polymer having a molecular weight of about 100,000 to about 500,000 which constitutes 0.5 to about 15.0 weight percent of total polymer, B) an agglomerated particle phase comprising either 1) about 85.0 to about 99.5 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 25 to about 125 µm and a molecular weight of from about 50,000 to about 120,000, or mixtures of said particles, or 2) about 45 to about 98.5 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 25 to about 125 µm and a molecular weight of from about 50,000 to about 120,000, or mixtures of said particles, and about 1 to about 40 weight percent of total polymer of vinyl halide or vinylidene halide polymer particles having a diameter of from about 130 to about 225 µm and a molecular weight of from about 100,000 to about 225,000 and C) a plasticizer comprising a solvent solution of a chemiluminescent compound and, optionally, a fluorescer, dispersed throughout both said phases.

  本发明提供了一种多孔柔性结构，该结构包括：A) 非颗粒相，包括卤化乙烯基或卤化亚乙烯基聚合物，其分子量约为 100,000 至约 500,000，占聚合物总量的 0.5 至约 15.0 重量百分比；B) 团聚颗粒相，包括 1) 约 85.0 至约 99.5 重量百分比的卤化乙烯基或偏卤化乙烯基聚合物颗粒，其直径约为 25 至约 125 µm，分子量约为 50,000 至约 120,000 或上述颗粒的混合物，或 2) 约 45 至约 98.5 重量百分比的卤化乙烯基或偏卤化乙烯基聚合物颗粒，其直径约为 25 至约 125 微米，分子量约为 50,000 至约 120,000 或上述颗粒的混合物、C) 增塑剂，包括分散在上述两相中的化学发光化合物和荧光剂的溶剂溶液。
• METHOD OF CHEMILUMINESCENCE-UTILIZING MAKEUP AND BEAUTIFICATION, LUMINANT FOR SKIN IRRADIATION BEAUTIFICATION AND MAKEUP/ BEAUTIFICATION EQUIPMENT
  申请人：Fancl Corporation

  公开号：EP1721634A1

  公开（公告）日：2006-11-15

  Presentation of the methods for makeup and beauty treatment by chemical luminescence, luminous bodies for beauty treatment by exposure to skin, and tools for makeup and beauty treatment

  介绍利用化学发光进行化妆和美容的方法、暴露在皮肤上进行美容的发光体以及化妆和美容工具
• Chemiluminescent materials and method of making same
  申请人：The United States of America, as represented by the Secretary of the Air Force

  公开号：US10040993B1

  公开（公告）日：2018-08-07

  Chemiluminescent materials are provided that include an encapsulated oxalate-containing composition that includes a core portion and a polymeric coating, a peroxide source, and a fluorescent dye. The core portion includes an oxalate; a polymerizable component composition that polymerizes upon exposure to ultraviolet radiation; a photosensitizer; and an ultraviolet screening agent. The polymeric coating layer surrounding the core portion comprises a polymer derived from the polymerizable component composition. A fluorescent dye may be intermixed in the oxalate-containing composition, intermixed with the peroxide source, present in the chemiluminescent material as a separate dye layer or particle, or present within another component of the chemiluminescent material. A method for making the chemiluminescent material is also provided.

  所提供的化学发光材料包括一种封装的含草酸盐的组合物，该组合物包括核心部分和聚合物涂层、过氧化物源和荧光染料。核心部分包括草酸盐、在紫外线辐射下聚合的可聚合成分组合物、光敏剂和紫外线屏蔽剂。围绕核心部分的聚合物涂层包括从可聚合成分组合物中提取的聚合物。荧光染料可以混合在含草酸盐的组合物中，与过氧化物源混合，作为单独的染料层或颗粒存在于化学发光材料中，或存在于化学发光材料的另一种成分中。此外，还提供了一种制造化学发光材料的方法。
• Device for dispensing chemiluminescent solution
  申请人：Imperial Toy LLC

  公开号：US10118433B2

  公开（公告）日：2018-11-06

  Devices have a flexible housing with an inside chamber having a closed and open end. A first chemiluminescent fluid is disposed in a breakable container in the chamber, and a second chemiluminescent fluid is in the chamber. A tip assembly is attached to the housing and includes a nib movably disposed in the body, and a filter element may be positioned within the body to prevent passage of broken particles from the container to the nib tip. A resilient element is used to impose an outward biasing force on the nib. A porous material is disposed over an outer surface of the nib tip and securely held in place. The device is activated for use by bending the housing to break the container causing the first and second chemiluminescent fluids to mix and react, providing a chemiluminescent solution that flows to the tip assembly for dispensing onto a desired surface.

  设备有一个柔性外壳，内腔有封闭端和开放端。第一种化学发光流体放置在腔室中的可破损容器中，第二种化学发光流体放置在腔室中。笔尖组件连接到外壳上，包括可移动地设置在主体内的笔尖，过滤元件可设置在主体内，以防止破碎的颗粒从容器进入笔尖。弹性元件用于在笔尖上施加向外的偏压力。多孔材料被放置在笔尖的外表面并牢牢固定。通过弯曲外壳使容器破裂，使第一种和第二种化学发光液体混合并发生反应，从而提供化学发光溶液，该溶液流向笔尖组件，以便分配到所需的表面上。

表征谱图