N-(2,2,2-trichloroethoxycarbonyl)-4-hydroxyaniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,2,2-trichloroethoxycarbonyl)-4-hydroxyaniline
• 英文别名: O-2,2,2-trichloroethyl N-(4-hydroxyphenyl)carbamate；2,2,2-trichloroethyl N-(4-hydroxyphenyl)carbamate
• 化学式: C₉H₈Cl₃NO₃
• 分子量: 284.526
• InChiKey: QXHKNSWOUOJAHU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  58.6
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,2,2-trichloroethyl-N-4-(tert-butyldimethylsilyloxy)phenylcarbamate 在 溶剂黄146 、 锌 作用下， 反应 24.0h， 生成 对氨基苯酚 、 4-[(tert-butyldimethylsilyl)oxy]aniline 、 N-(2,2,2-trichloroethoxycarbonyl)-4-hydroxyaniline
  参考文献：
  名称：

  A Mild Deprotection of Trichloroethyl Carbamates Using Indium Metal

  摘要：

  三氯乙氧基羧酰基从氨基甲酸酯中高效去除，使用铟金属，得到相应的胺，产率良好到优越。

  DOI：

  10.1055/s-2002-31919

文献信息

• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• Radiation-curable mixture, and radiation-sensitive recording material
  申请人：Hoechst Aktiengesellschaft

  公开号：US05614351A1

  公开（公告）日：1997-03-25

  A radiation-curable mixture is disclosed which contains a compound which forms an acid under the action of high-energy radiation, and contains an acid-curable compound, wherein the compound which forms an acid contains aliphatically bound halogen (chlorine or bromine) and has a pK.sub.a value of less than about 12. A radiation-curable recording material and a process for recording high-energy radiation using the material are also disclosed. The mixture, and in particular the recording material produced therefrom, has relatively high sensitivity and improved resolution and, in addition, does not exhibit image fogging after development.

  本发明披露了一种辐射可固化混合物，其中包含一种在高能辐射作用下形成酸的化合物，并含有一种酸可固化化合物，其中形成酸的化合物含有脂肪族卤素（氯或溴）键，并具有小于约12的pK.sub.a值。本发明还披露了一种辐射可固化记录材料及使用该材料记录高能辐射的方法。该混合物，特别是由此制得的记录材料具有相对较高的灵敏度和改进的分辨率，并且在显影后不会出现图像雾化。
• Positive radiation-sensitive mixture, and radiation-sensitive recording
  申请人：Hoechst Aktiengesellschaft

  公开号：US05217843A1

  公开（公告）日：1993-06-08

  A positive radiation-sensitive mixture is disclosed which contains a compound which forms an acid under the action of high-energy radiation, and an acid-cleavable compound, wherein the compound which forms an acid contains aliphatically bound halogen (chlorine or bromine) and has a pK.sub.a value of less than about 12 or is a derivative of a compound having such a pK.sub.a value which can be converted into the free compound by acid catalysis. A positive recording material and a process for recording high-energy radiation using the material are also disclosed. The mixture, and in particular the recording material produced therefrom, has relatively high sensitivity and improved resolution and, in addition, does not exhibit image fogging after development.

  本发明公开了一种正电子辐射敏感混合物，其包含一种在高能辐射作用下形成酸的化合物和一种可酸解化合物，其中形成酸的化合物含有脂肪族卤素（氯或溴）并具有小于约12的pK.sub.a值，或者是具有这种pK.sub.a值的化合物的衍生物，可通过酸催化转化为自由化合物。本发明还公开了一种正记录材料和使用该材料记录高能辐射的方法。该混合物，特别是由其制备的记录材料具有相对较高的敏感性和改善的分辨率，并且在显影后不会出现图像雾化。
• ACTINIC LIGHT CURABLE INK JET INK SET, IMAGE FORMING METHOD USING THE SAME, AND INK JET RECORDING APPARATUS
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1803781A1

  公开（公告）日：2007-07-04

  An active ray curable ink-jet ink set comprising an active ray curable yellow ink, an active ray curable cyan ink, an active ray curable black ink, and further one or more of active ray curable color inks other than yellow, cyan and black, wherein each of the active ray curable yellow ink, the active ray curable cyan ink, the active ray curable black ink, and the active ray curable color inks other than yellow, cyan and black, contains a photo-polymerization initiator, a photo-polymerizable compound, a pigment, and a dispersing agent, which dispersing agent has an amine value and an acid value, and the acid value is higher than the amine value, and an average particle diameter of the pigment contained in the yellow ink is larger than the average particle diameter of the cyan ink and that of the black ink by 0.025 - 0.090 µm, and further the average particle diameter of the pigment contained in each of the color inks is 0.070 - 0.220 µm.

  一种活性射线固化喷墨墨水组，包括一种活性射线固化黄色墨水、一种活性射线固化青色墨水、一种活性射线固化黑色墨水，以及除黄色、青色和黑色以外的一种或多种活性射线固化彩色墨水，其中每种活性射线固化黄色墨水、活性射线固化青色墨水、活性射线固化黑色墨水，以及除黄色、青色和黑色以外的活性射线固化彩色墨水，都含有光聚合引发剂、光聚合化合物、颜料和分散剂、其中黄色油墨、青色油墨、黑色油墨以及除黄色、青色和黑色以外的其他颜色油墨都含有光聚合引发剂、可光聚合化合物、颜料和分散剂，分散剂具有胺值和酸值，且酸值高于胺值，黄色油墨中所含颜料的平均颗粒直径比青色油墨和黑色油墨的平均颗粒直径大 0.025 - 0.090 µm，而且每种彩色油墨所含颜料的平均颗粒直径为 0.070 - 0.220 µm。
• ACTIVE RAY-CURABLE COMPOSITION, ACTIVE RAY-CURABLE INK AND IMAGE-FORMING METHOD
  申请人：Konica Minolta Medical & Graphic, Inc.

  公开号：EP1829936A1

  公开（公告）日：2007-09-05

  Disclosed is an actinic ray curable ink containing pigment, a photolytic acid generating agent and an epoxy compound represented by the following formula (1-1) or (1-2),

  本发明公开了一种含颜料、光解酸生成剂和由下式（1-1）或（1-2）表示的环氧化合物的光固化油墨、