POLYMER MIXTURES FOR INCREASING STABILITY AND PERFORMANCE OF HYDROLASE-CONTAINING DETERGENTS
申请人:BASF SE
公开号:EP4015629A1
公开(公告)日:2022-06-22
Mixture comprising at least
component (a): graft polymer comprising as a graft base a polyether and as grafted side chains copolymers comprising at least one comonomer selected from
CH2=CH-O-C(O)-R3 (la)
CH2=CH-CH2-O-C(O)-R3 (Ib)
CH2=CZ-CO-OR4 (Ic)
wherein R3 is selected from C1-C21-alkyl, for example methyl, n-propyl, n-pentyl, n-heptyl, n-nonyl, iso-nonyl, n-undecyl, n-tridecyl, n-pentadecyl, n-heptadecyl, or n-nonadecyl.
R4 is selected from C2-C20-alkyl, preferably with an even number of carbon atoms, for example ethyl, n- and iso propyl, n-hexyl, isohexyl, sec-hexyl, n-heptyl, n-octyl, 2-ethylhexyl, n-nonyl, n-decyl or isodecyl, n-C12H25, n-C14H29, n-C16H33 or n-C18H37,
and Z is selected from hydrogen and methyl, hydrogen bring preferred
component (b): Trialkyl citrate according to formula (TAC):
wherein the variables in formula (TAC) are defined as follows:
R1, R2, R3 are selected from H, linear C1-C8 alkyl, and branched C3-C8 alkyl, wherein at least one of R1, R2, and R3 is not H. Examples of linear C1-C8 alkyl are methyl, ethyl, n-propyl, n-butyl, n-pentyl, etc.
Examples of branched C3-C8 alkyl are 2-propyl, 2-butyl, sec.-butyl, tert.-butyl, 2-pentyl, 3-pentyl, iso-pentyl, etc. Preferably, R1, R2, R3 are ethyl.
混合物,至少包括
成分(a):接枝聚合物,包括作为接枝基的聚醚和作为接枝侧链的共聚物,共聚物包括至少一种共聚单体,这些共聚单体选自以下物质
CH2=CH-O-C(O)-R3 (la)
=CH- -O-C(O)-R3 (Ib)
=
CZ-CO-OR4 (Ic)
其中 R3 选自 C1-C21 烷基,例如甲基、正丙基、正戊基、正庚基、正壬基、异壬基、正
十一烷基、正
十三烷基、
正十五烷基、
正十七烷基或正壬基。
R4 选自碳原子数为偶数的 C2-C20 烷基,例如乙基、正丙基和异丙基、正己基、异己基、仲己基、正庚基、
正辛基、2-乙基己基、正壬基、正癸基或异癸基、n-
C12H25、n-
C14H29、n-
C16H33 或 n-
C18H37、
和 Z 选自氢和甲基,首选氢
组分(b):符合式(TAC)的
柠檬酸三烷基酯:
其中式(TAC)中的变量定义如下:
直链 C1-C8 烷基的例子有甲基、乙基、正丙基、正丁基、正戊基等。
支链 C3-C8 烷基的例子有 2-丙基、2-丁基、仲丁基、叔丁基、2-戊基、3-戊基、异戊基等。R1、R2、R3 最好是乙基。