2-(t-butylperoxycarbonyl)benzoyl chloride

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(t-butylperoxycarbonyl)benzoyl chloride
• 英文别名: tert-butyl 2-carbonochloridoylbenzenecarboperoxoate
• 化学式: C₁₂H₁₃ClO₄
• 分子量: 256.686
• InChiKey: DBDGTAFDOAZEHO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  17
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  羟基甲基叔-丁基过氧化物 、 2-(t-butylperoxycarbonyl)benzoyl chloride 在 吡啶 作用下， 以 乙醚 为溶剂， 生成 tert-butylperoxymethyl tert-butyl peroxy-o-phthalate
  参考文献：
  名称：

  Kuznetsov,V.I.; Ivanchev,S.S., Journal of Organic Chemistry USSR (English Translation), 1977, vol. 13, p. 656 - 658

  摘要：

  DOI：
• 作为产物：
  描述：

  Mono-perphthalsaeure-tert.-butylester 、 草酰氯 以99%的产率得到
  参考文献：
  名称：

  OLDEKOP YU. A.; BULOJCHIK ZH. I.; CEMEHOBA V. A.; MATVEENTSEVA M. S., VESTSI AN BSSR. CEP. XIM. N., IZV. AN BSSR. CEP. XIM. N., 1980, HO 1, 88-+

  摘要：

  DOI：

文献信息

• Hydroxy-peroxides useful as polymerization initiators
  申请人：Elf Atochem North America, Inc.

  公开号：US05304649A1

  公开（公告）日：1994-04-19

  Novel hydroxy peroxides of the Structure A HO--R.sub.11 --X--OO--R (A) [wherein R--, --R.sub.11 -- and --X-- are as defined in the Summary of the Invention Section], having 10 hour half-life temperatures of 85.degree.-100.degree. C., the processes for their preparation, and the use of these novel compositions in curing of unsaturated polyester resins and in initiating polymerization of ethylenically unsaturated monomers.

  结构A的新型羟基过氧化物 HO--R.sub.11 --X--OO--R（A）[其中R--，--R.sub.11 --和--X--的定义见发明摘要部分]，其具有85度至100度的10小时半衰期温度，以及它们的制备过程，以及这些新型组合物在固化不饱和聚酯树脂和引发乙烯不饱和单体聚合中的用途。
• Hydroxy-peroxides and their uses
  申请人：Elf Atochem North America, Inc.

  公开号：US05387654A1

  公开（公告）日：1995-02-07

  Novel hydroxy peroxides of the Structure A HO--R.sub.11 --X--OO--R (A) [wherein R--, --R.sub.11 -- and --X-- are as defined in the Summary of the Invention Section], having 10 hour half-life temperatures of 85.degree.-100.degree. C., the processes for their preparation, and the use of these novel compositions in curing of unsaturated polyester resins and in initiating polymerization of ethylenically unsaturated monomers.

  结构A HO--R.sub.11 --X--OO--R（A）的新型羟基过氧化物[其中R-，-R.sub.11-和-X-如发明概述部分所定义]，其10小时半衰期温度为85℃-100℃，其制备过程，以及这些新型组合物在固化不饱和聚酯树脂和引发乙烯基不饱和单体聚合中的应用。
• Diacyl peroxy compounds
  申请人：Pennwalt Corporation

  公开号：US03991109A1

  公开（公告）日：1976-11-09

  I. A novel class of compounds X.sub.n --R.sub.p --Y.sub.m where R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, X is an acylating function; Y is a peroxy containing group and n and m are each equal to 1-2 and p is at least 1. Ii. a novel class of polymers [A.sub.n -(R-D.sub.n).sub.n ].sub.v -P.sub.w -Z where A is a peroxy containing group; R is a 2-4 valence aliphatic, cycloaliphatic or aromatic radical, P is a polyvalent polymeric residue; D is a carbonyl containing connecting group; Z is H, OH, NH.sub.2, NHR.sub.2, SH or R.sub.2 O group; v and w are each equal to 1-100; and n is equal to 1-2. Iii. polymers II are useful with vinyl monomers in the formation of block and graft polymers. Iv. peroxides having an acylating function are prepared by reacting at 0.degree.-80.degree. C an organic peroxide having an hydroxyl or carboxyl group with a defined acylating reactant. V. peroxides having at least one acylating function are prepared by peroxidizing a compound having at least two acylating functions as the only peroxidizable substituents.

  I. 一种新型化合物X.sub.n --R.sub.p --Y.sub.m，其中R为2-4价的脂肪族、环状脂肪族或芳香族基团，X为酰化功能；Y为过氧化物含有基团，n和m分别等于1-2，p至少为1。 II. 一种新型聚合物[A.sub.n -(R-D.sub.n).sub.n ].sub.v -P.sub.w -Z，其中A为过氧化物含有基团；R为2-4价的脂肪族、环状脂肪族或芳香族基团，P为多价聚合物残基；D为含有羰基的连接基团；Z为H、OH、NH.sub.2、NHR.sub.2、SH或R.sub.2 O基团；v和w分别等于1-100；n等于1-2。 III. 聚合物II与乙烯单体一起使用可形成块状和嫁接聚合物。 IV. 具有酰化功能的过氧化物通过将具有羟基或羧基的有机过氧化物与定义的酰化反应物在0℃-80℃反应制备。 V. 具有至少一个酰化功能的过氧化物是通过过氧化至少具有两个酰化功能作为唯一可过氧化取代基团的化合物制备的。
• Novel hydroxy-peroxides and their uses
  申请人：ATOCHEM NORTH AMERICA, INC.

  公开号：EP0381135A2

  公开（公告）日：1990-08-08

  Novel hydroxy peroxides of the Structure A [wherein R-, -R11- and -X- are as defined in the Summary of the Invention Section], having 10 hour half-life temperatures of 85-100 °C, the processes for their preparation, and the use of these novel compositions in curing of unsaturated polyester resins and in initiating polymerization of ethylenically unsaturated monomers.

  结构 A 的新型羟基过氧化物 [其中 R-、-R11- 和 -X- 的定义见发明概述部分]、 其半衰期为 10 小时，温度为 85-100 °C，其制备工艺，以及这些新型组合物在固化不饱和聚酯树脂和引发乙烯基不饱和单体聚合中的用途。
• Polymeric peroxides derived from hydroxy-hydroperoxides and dihydroxy-dialkyl peroxides and their use
  申请人：ELF ATOCHEM NORTH AMERICA, INC.

  公开号：EP0472819A2

  公开（公告）日：1992-03-04

  A polymeric peroxide comprising a divalent recurring unit having the formula: wherein the recurring unit of Formula I has a 10 hour half-life temperature of at least 80 °C and optionally a divalent recurring unit having the formula: wherein R1, R2, R3, R5, X, X1, Y, Z, y and z are as defined in the Detailed Description of the Preferred Embodiments and the polymeric peroxide has a molecular weight of 1,000 to 200,000. The polymeric peroxides are derived from hydroxy-hydroperoxides or dihydroxy dialkyl peroxides. These polymeric peroxides can be used for preparing block copolymers and compatibilizing polymer blends and alloys.

  一种聚合过氧化物，包含具有以下式子的二价递归单元 其中式 I 的递归单元的 10 小时半衰期温度至少为 80℃，可选地还包括具有式 其中 R1、R2、R3、R5、X、X1、Y、Z、y 和 z 如优选实施例的详细说明中所定义，聚合过氧化物的分子量为 1,000 至 200,000。聚合过氧化物由羟基氢过氧化物或二羟基二烷基过氧化物衍生而来。这些聚合过氧化物可用于制备嵌段共聚物和相容聚合物混合物及合金。