thieno[3,2-c][1,2]dithiin

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: thieno[3,2-c][1,2]dithiin
• 英文别名: Thieno[3,2-c][1,2]dithiin；thieno[3,2-c]dithiine
• 化学式: C₆H₄S₃
• 分子量: 172.296
• InChiKey: CNAFOANPGHXARD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  78.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  thieno[3,2-c][1,2]dithiin 以 氘代二甲亚砜 为溶剂， 反应 2.0h， 生成 噻吩并[3,2-b]噻吩
  参考文献：
  名称：

  1,2-Dithiins and precursors, XVII: Synthesis and properties of thieno anellated 1,2-dithiins, structural influence on colour

  摘要：

  Various thieno[3,2-c] anellated (59, 26) and dithieno[3,2-c:2,3-e] anellated I,2-dithiins (32 a-c, 45) were obtained starting from appropriate thiophene precursors. The absorption maxima covered the range from 430 to 467 nm indicating olefinic rather than aromatic character of the anellating thiophene units. Access to the isomeric thieno[2,3-c] anellated series failed due to competing reactions in the final stage, e.g. by the formation of the 12-membered cyclic bis-disulfide 53. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00439-0
• 作为产物：
  描述：

  (Z)-3-acetylthio-2-(2-acetylthiovinyl)thiophene 在 氢氧化钾 、 碘 、 (E)-3-acetylthio-2-(2-acetylthiovinyl)thiophene 作用下， 生成 thieno[3,2-c][1,2]dithiin
  参考文献：
  名称：

  1,2-Dithiins and precursors, XVII: Synthesis and properties of thieno anellated 1,2-dithiins, structural influence on colour

  摘要：

  Various thieno[3,2-c] anellated (59, 26) and dithieno[3,2-c:2,3-e] anellated I,2-dithiins (32 a-c, 45) were obtained starting from appropriate thiophene precursors. The absorption maxima covered the range from 430 to 467 nm indicating olefinic rather than aromatic character of the anellating thiophene units. Access to the isomeric thieno[2,3-c] anellated series failed due to competing reactions in the final stage, e.g. by the formation of the 12-membered cyclic bis-disulfide 53. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(97)00439-0

文献信息

• Thienodithiinderivate als Fungizide
  申请人：Bayer CropScience AG

  公开号：EP2558471B1

  公开（公告）日：2014-05-21
• THIENODITHIINDERIVATE ALS FUNGIZIDE
  申请人：Bayer CropScience AG

  公开号：EP2558471A1

  公开（公告）日：2013-02-20
• Thienodithiine Derivatives
  申请人：SEITZ Thomas

  公开号：US20110281915A1

  公开（公告）日：2011-11-17

  The present invention relates to new thienodithiine derivatives, to processes for preparing them, to their use for controlling unwanted microorganisms, more particularly phytopathogenic fungi, in crop protection, in the household and hygiene sector and in the protection of materials, and also to crop protection compositions comprising these thienodithiine derivatives.
• US8383551B2
  申请人：——

  公开号：US8383551B2

  公开（公告）日：2013-02-26
• [DE] THIENODITHIINDERIVATE ALS FUNGIZIDE<br/>[EN] THIENODITHIIN DERIVATIVES AS FUNGICIDES<br/>[FR] DÉRIVÉS DE THIÉNODITHIINE UTILISÉS EN TANT QUE FONGICIDES
  申请人：BAYER CROPSCIENCE AG

  公开号：WO2011128295A1

  公开（公告）日：2011-10-20

  Die vorliegende Erfindung betrifft die neue Thienodithiin-Derivate, Verfahren zu deren Herstellung, deren Verwendung zum Bekämpfen von unerwünschten Mikroorganismen, insbesondere phytopathogener Pilze, im Pflanzenschutz, im Bereich Haushalt und Hygiene und im Materialschutz, sowie Pflanzenschutzmittel enthaltend diese Thienodithiin-Derivate.