N-(2,2-diphenylvinyl)-N-phenyl-N-(1-naphthyl)amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(2,2-diphenylvinyl)-N-phenyl-N-(1-naphthyl)amine
• 英文别名: N-(2,2-diphenylethenyl)-N-phenylnaphthalen-1-amine
• 化学式: C₃₀H₂₃N
• 分子量: 397.519
• InChiKey: HQTHSKRAFCLEJB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-苯基-1-萘胺 在 吡啶 、 盐酸 、 IrCl(CO){P(OC₆F₅)₃}₂ 作用下， 以 乙醚 、 二氯甲烷 、 甲苯 为溶剂， 反应 24.5h， 生成 N-(2,2-diphenylvinyl)-N-phenyl-N-(1-naphthyl)amine
  参考文献：
  名称：

  Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines

  摘要：

  The appropriate design of a ligand (L) in IrCl(CO)(L)(2) (4) realized the efficient synthesis of pi-conjugated enamines possessing hole-transport properties. The iridium complex with electron-withdrawing phosphorus ligands catalyzed the hydrosilylation of amides to the corresponding silylhemiaminals, which were transformed to the enamines by heat or by treatment with acids. High catalytic efficiency (TON > 10,000) was achieved, which made it possible for the residual iridium in the enamine product to be below 20 ppb.

  DOI：

  10.1021/acs.organomet.5b00636

文献信息

• US7416824B2
  申请人：——

  公开号：US7416824B2

  公开（公告）日：2008-08-26
• US7625681B2
  申请人：——

  公开号：US7625681B2

  公开（公告）日：2009-12-01
• Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π-Conjugated Enamines
  作者：Atsushi Tahara、Yasumitsu Miyamoto、Ryuta Aoto、Keisuke Shigeta、Yuta Une、Yusuke Sunada、Yukihiro Motoyama、Hideo Nagashima

  DOI：10.1021/acs.organomet.5b00636

  日期：2015.10.26

  The appropriate design of a ligand (L) in IrCl(CO)(L)(2) (4) realized the efficient synthesis of pi-conjugated enamines possessing hole-transport properties. The iridium complex with electron-withdrawing phosphorus ligands catalyzed the hydrosilylation of amides to the corresponding silylhemiaminals, which were transformed to the enamines by heat or by treatment with acids. High catalytic efficiency (TON > 10,000) was achieved, which made it possible for the residual iridium in the enamine product to be below 20 ppb.