Zn[CH=CMe2]2

• 分子结构分类: 有机化合物 - 碳氢化合物衍生物
• 英文名称: Zn[CH=CMe2]2
• 化学式: 2C₄H₇*Zn
• 分子量: 175.589
• InChiKey: MUEIVRPNUGRYGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.38
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  四甲基乙二胺 、 Zn[CH=CMe2]2 以 正己烷 为溶剂， 以92%的产率得到Zn[CH=CMe2]2*(tetramethylethylenediamine)
  参考文献：
  名称：

  Unprecedented Alkene Complex of Zinc(II):  Structures and Bonding of Divinylzinc Complexes

  摘要：

  This report describes the solid-state structures of a series of divinylzinc complexes, one of which represents the only structurally characterized zinc(II) pi-complex. Vinylzinc reagents, Zn[C(Me)=CH2](2) (1) and Zn[C(H)=CMe2](2) (2), have been synthesized and isolated as white crystalline solids in 66 and 72% yield, respectively. Each compound exhibits an infinite polymeric architecture in the solid state via a series of zinc-pi (1) and zinc-sigma-bonded (2) bridging interactions. Addition of chelating ligands to these divinylzinc compounds allowed isolation of the monomeric adducts (bipy)Zn[C(Me)=CH2](2) (1(.)bipy), (tmeda)Zn[C(Me)= CH2](2) (1(.)tmeda), (bipy)Zn[C(H)=CMe2](2) (2(.)bipy), and (tmeda)Zn[C(H)=CMe2](2) (2(.)tmeda), of which 1(.)obipy, 2(.)bipy, and 2(.)tmeda have been characterized crystallographically.

  DOI：

  10.1021/ja058700x
• 作为产物：
  描述：

  1-溴-2-甲基-1-丙烯 、 zinc dibromide 在 lithium 作用下， 以 乙醚 为溶剂， 以72%的产率得到Zn[CH=CMe2]2
  参考文献：
  名称：

  Unprecedented Alkene Complex of Zinc(II):  Structures and Bonding of Divinylzinc Complexes

  摘要：

  This report describes the solid-state structures of a series of divinylzinc complexes, one of which represents the only structurally characterized zinc(II) pi-complex. Vinylzinc reagents, Zn[C(Me)=CH2](2) (1) and Zn[C(H)=CMe2](2) (2), have been synthesized and isolated as white crystalline solids in 66 and 72% yield, respectively. Each compound exhibits an infinite polymeric architecture in the solid state via a series of zinc-pi (1) and zinc-sigma-bonded (2) bridging interactions. Addition of chelating ligands to these divinylzinc compounds allowed isolation of the monomeric adducts (bipy)Zn[C(Me)=CH2](2) (1(.)bipy), (tmeda)Zn[C(Me)= CH2](2) (1(.)tmeda), (bipy)Zn[C(H)=CMe2](2) (2(.)bipy), and (tmeda)Zn[C(H)=CMe2](2) (2(.)tmeda), of which 1(.)obipy, 2(.)bipy, and 2(.)tmeda have been characterized crystallographically.

  DOI：

  10.1021/ja058700x

文献信息

• Unprecedented Alkene Complex of Zinc(II):  Structures and Bonding of Divinylzinc Complexes
  作者：Alfred Wooten、Patrick J. Carroll、Aaron G. Maestri、Patrick J. Walsh

  DOI：10.1021/ja058700x

  日期：2006.4.1

  This report describes the solid-state structures of a series of divinylzinc complexes, one of which represents the only structurally characterized zinc(II) pi-complex. Vinylzinc reagents, Zn[C(Me)=CH2](2) (1) and Zn[C(H)=CMe2](2) (2), have been synthesized and isolated as white crystalline solids in 66 and 72% yield, respectively. Each compound exhibits an infinite polymeric architecture in the solid state via a series of zinc-pi (1) and zinc-sigma-bonded (2) bridging interactions. Addition of chelating ligands to these divinylzinc compounds allowed isolation of the monomeric adducts (bipy)Zn[C(Me)=CH2](2) (1(.)bipy), (tmeda)Zn[C(Me)= CH2](2) (1(.)tmeda), (bipy)Zn[C(H)=CMe2](2) (2(.)bipy), and (tmeda)Zn[C(H)=CMe2](2) (2(.)tmeda), of which 1(.)obipy, 2(.)bipy, and 2(.)tmeda have been characterized crystallographically.