3,3',4,4'-benzophenonetetracarboxylic acid tetrachloride

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3',4,4'-benzophenonetetracarboxylic acid tetrachloride
• 英文别名: 3,3',4,4'-benzophenonetetracarboxyl tetrachloride；4-(3,4-Dicarbonochloridoylbenzoyl)benzene-1,2-dicarbonyl chloride
• 化学式: C₁₇H₆Cl₄O₅
• 分子量: 432.044
• InChiKey: OJQLSKXVHNKTRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  85.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  十二烷基伯胺 、 3,3',4,4'-benzophenonetetracarboxylic acid tetrachloride 以 氯仿 为溶剂， 反应 4.5h， 以27%的产率得到3,3',4,4'-benzophenonetetracarboxylic acid tetradodecyl amide
  参考文献：
  名称：

  油性化粧料

  摘要：

  提供优异的油性化妆料，具有分散稳定性、优越的附着性、延展性，可在皮肤、睫毛或眉毛上涂抹，赋予持久的光泽或湿润感。本发明的油性化妆料包含以下式（1）中表示的化合物的增稠剂（A）和油剂（B）：R1-(CONH-R2)n（式中，R1是从苯、苯酮、联苯、萘、环己烷或丁烷的结构式中去除n个氢原子的基，R2是碳数大于等于4的脂族烷基，n是大于等于3的整数。n个R2可以相同，也可以不同）。【选择图】无

  公开号：

  JP2016020327A
• 作为产物：
  描述：

  3,3',4,4'-二苯甲酮四甲酸二酐 、 氯化亚砜 以75%的产率得到
  参考文献：
  名称：

  FEDOROVA V. A.; DONCHAK V. A.; PUCHIN V. A.; MUSABEKOV YU. YU., XIM. TEXNOL. (KIEV), 1980, HO 6, 23-25

  摘要：

  DOI：

文献信息

• THICKENING STABILIZER, AND THICKENING/STABILIZING COMPOSITION USING THE SAME
  申请人：DAICEL CORPORATION

  公开号：US20150376119A1

  公开（公告）日：2015-12-31

  Provided is a compound which thickens or gels a fluid organic material to a desired viscosity, or which uniformly stabilizes the formulation of a composition containing the fluid organic material. The compound according to the present invention is represented by Formula (1): R 1 —(CONH—R 2 ) n (1) where R 1 represents an n-valent aromatic hydrocarbon group containing two or more benzene rings; R 2 represents an aliphatic hydrocarbon group containing 6 or more carbon atoms; and n represents an integer of 4 or more. The group R 1 is preferably a group corresponding to an aromatic hydrocarbon selected from the group consisting of benzophenone, biphenyl, and naphthalene, except for removing hydrogen atoms in a number of n from the aromatic hydrocarbon. A thickening/stabilizing agent according to the present invention includes the compound.

  提供的是一种化合物，用于将流体有机材料增稠或凝胶化至所需粘度，或者均匀稳定含有该流体有机材料的配方。根据本发明，该化合物由式（1）表示：R1—(CONH—R2)n（1） 其中，R1代表一个含有两个或更多苯环的n价芳香烃基团；R2代表一个含有6个或更多碳原子的脂肪烃基团；n代表4或更多的整数。基团R1最好是与苯酮、联苯或萘等芳香烃中选取的一个对应的基团，但在芳香烃中去除n个氢原子。根据本发明，一种增稠/稳定剂包括该化合物。
• [EN] MULTIMER FORMS OF MONO- AND BIS-ACYLPHOSPHINE OXIDES<br/>[FR] FORMES MULTIMERIQUES D'OXYDES DE MONOACYLPHOSPHINE ET DE BISACYLPHOSPHINE
  申请人：CIBA SC HOLDING AG

  公开号：WO2003104245A1

  公开（公告）日：2003-12-18

  The invention relates to dimer and multimer forms of BAPO compounds of the formula (1) dimer and multimer forms of MAPO compounds of the formula (II) wherein R1, R2, and R3 independently of one another are unsubstituted or substituted C1-C12alkyl, benzyl, C1-C12alkoxy, C3-C6cycloalkyl or C5-C14aryl; Q is a di-tri or tetravalent arylene residue; n is 1-4, m is 0-2, n+m is 2, 3 or 4, with the proviso, that R1 and R3 are different from each other. The invention further relates to a process for the preparation of dimer or multimer forms of BAPO compounds of the formula (I) and of dimer or multimer forms of MAPO compounds of the formula (II), characterized in the (n + m) equivalents of a dimetalated-phosphine R1P(M)2 is reacted with one equivalent of a di-or polycarboxylic acid halogenide to form an intermediate of the formula III the intermediate is then reacted either with (n + m) equivalents of a further carboxylic acid halogenide (R2-CO-Hal) or with a halogenide R3-Hal, the reaction products are then oxidized to form phosphine oxides of the formula I or II.

  本发明涉及公式（I）的BAPO化合物的二聚体和多聚体形式以及公式（II）的MAPO化合物的二聚体和多聚体形式，其中R1，R2和R3彼此独立地是未取代或取代的C1-C12烷基，苯甲基，C1-C12烷氧基，C3-C6环烷基或C5-C14芳基; Q是二-三或四价芳基残基; n为1-4，m为0-2，n+m为2、3或4，但R1和R3不同于对方。本发明还涉及制备公式（I）的BAPO化合物的二聚体或多聚体形式以及公式（II）的MAPO化合物的二聚体或多聚体形式的方法，其特征在于将（n+m）当量的二金属化磷R1P（M）2与一个当量的二或多羧酸卤化物反应形成公式III的中间体，然后将中间体与（n+m）当量的进一步羧酸卤化物（R2-CO-Hal）或卤化物R3-Hal反应，然后将反应产物氧化成公式I或II的氧化磷化合物。
• PARA- OR MESO-FUNCTIONALIZED AROMATIC KETONE COMPOUNDS, PREPARATION METHODS THEREOF, AND PHOTOPOLYMERIZATION INITIATORS COMPRISING THE SAME
  申请人：Zhang Yongbo

  公开号：US20130217877A1

  公开（公告）日：2013-08-22

  The present invention discloses novel aromatic ketone compounds with functional substiution groups at para- or meta positions which can be used as photo-initiators or effective components of photo-initiator mixtures for the photopolymerizations of ethylenically unsaturated systems. The preparation of these compounds is also disclosed.

  本发明公开了一种新型芳香酮化合物，其在对位或间位具有功能性取代基，可用作光引发剂或光引发剂混合物的有效组分，用于乙烯基不饱和体系的光聚合反应。本发明还公开了这些化合物的制备方法。
• Polycarbonate molding composition
  申请人：Bayer MaterialScience AG

  公开号：EP2210916A1

  公开（公告）日：2010-07-28

  An impact modified thermoplastic molding composition comprising aromatic polycarbonate and/or polyester carbonate and a rubber-modified graft polymer prepared by the bulk, solution or bulk-suspension polymerization process is disclosed. The composition that is characterized by its low content of lithium ions and its content of sodium and/or potassium ions exceeding a minimum level features improved hydrolytic resistance.

  本发明公开了一种抗冲击改性热塑性模塑组合物，该组合物包含芳香族聚碳酸酯和/或碳酸聚酯以及一种橡胶改性接枝聚合物，该聚合物是通过散装、溶液或散装悬浮聚合工艺制备的。该组合物的特点是锂离子含量低，钠离子和/或钾离子含量超过最低水平，具有更好的耐水解性。
• Flame resistant polymer blends
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP2366740A2

  公开（公告）日：2011-09-21

  Blends of siloxane copolymers, notably siloxane polyimides, with polyaryl esters or polyaryl ester carbonates containing linkages derived from resorcinol, show improved flame resistance, as measured by two minute and peak heat release, compared to conventional polycarbonates. In some instances transparent flame retardant blends can also be prepared. The compositions show good melt processability, high impact strength and high elongation, and can be used to make various flame retardant articles including sheets and films.

  硅氧烷共聚物，特别是硅氧烷聚酰亚胺，与含有间苯二酚链节的聚芳基酯或聚芳基酯碳酸盐的混合物，与传统的聚碳酸酯相比，通过两分钟和峰值热释放测量，显示出更好的阻燃性。在某些情况下，还可以制备透明的阻燃混合物。这些组合物具有良好的熔融加工性、高冲击强度和高伸长率，可用于制造各种阻燃制品，包括板材和薄膜。