O,S-n-nonyl-1-butylpentyl dithiocarbonate

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: O,S-n-nonyl-1-butylpentyl dithiocarbonate
• 英文别名: O-nonyl nonan-5-ylsulfanylmethanethioate
• 化学式: C₁₉H₃₈OS₂
• 分子量: 346.642
• InChiKey: WFRGGCDXUARYOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  66.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二硫化碳 、 5-壬醇 、 1-壬醇 在 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 二甲基亚砜 为溶剂， 反应 6.0h， 以84%的产率得到O,S-n-nonyl-1-butylpentyl dithiocarbonate
  参考文献：
  名称：

  A high yielding, one-pot synthesis of O,S-dialkyl dithiocarbonates from alcohols using Mitsunobu’s reagent

  摘要：

  A novel Mitsunobu-based protocol has been developed for the synthesis of O,S-dialkyl dithiocarbonates from a variety of primary, secondary and tertiary alcohols using carbon disulfide, in good to excellent yields. This protocol is mild and efficient compared to other reported methods. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.10.149

文献信息

• A high yielding, one-pot synthesis of O,S-dialkyl dithiocarbonates from alcohols using Mitsunobu’s reagent
  作者：Devdutt Chaturvedi、Suprabhat Ray

  DOI：10.1016/j.tetlet.2006.10.149

  日期：2007.1

  A novel Mitsunobu-based protocol has been developed for the synthesis of O,S-dialkyl dithiocarbonates from a variety of primary, secondary and tertiary alcohols using carbon disulfide, in good to excellent yields. This protocol is mild and efficient compared to other reported methods. (c) 2006 Elsevier Ltd. All rights reserved.