5-chloroformyl-1,3-benzenedicarboxylic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-chloroformyl-1,3-benzenedicarboxylic acid
• 英文别名: trimesic acid chloride；trimesic chloride；5-Carbonochloridoylbenzene-1,3-dicarboxylic acid
• 化学式: C₉H₅ClO₅
• 分子量: 228.589
• InChiKey: FQYONHIXNBQFLJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  91.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  5-chloroformyl-1,3-benzenedicarboxylic acid 、 十一烷醇 在 吡啶 作用下， 生成 Benzene-1,3,5-tricarboxylic acid 1-undecyl ester
  参考文献：
  名称：

  Rational Modulation of the Periodicity in Linear Hydrogen-Bonded Assemblies of Trimesic Acid on Surfaces

  摘要：

  We demonstrate a surprising cooperative adsorption process at the liquid-solid interface, involving self-assembly in which a three-fold hydrogen-bonding unit (trimesic acid, TMA) is forced into a linear pattern by noncovalent interaction with an alcohol. Our work shows that the unexpected linear pattern formed by coadsorption of TMA and alcohols can be modulated in size by choosing alcohols with different chain lengths.

  DOI：

  10.1021/ja0602896

文献信息

• Acid decomposable compound
  申请人：——

  公开号：US20040242724A1

  公开（公告）日：2004-12-02

  An acid decomposable compound of the present invention is a compound having acid decomposable groups and thermally-bond-formable groups in one molecule in a certain order. The acid decomposable compound contains at least a core structure, acid decomposable groups which are binding to the core structure and thermally-bond-formable groups which are binding to the acid decomposable groups, wherein the thermally-bond-formable groups undergo Diels-Alder Reactions, metathesis reactions or other thermal-addition reactions.

  本发明涉及的酸可分解化合物是一种在分子内以一定顺序具有酸可分解基团和热可成键基团的化合物。该酸可分解化合物至少包含一个核心结构，连接于该核心结构的酸可分解基团，以及连接于这些酸可分解基团的热可成键基团，其中热可成键基团能够进行Diels-Alder反应、复分解反应或其他热加成反应。
• Halogen Resistant Amides, Polyamides, and Membranes Made From the Same
  申请人：Murphy Andrew P.

  公开号：US20160074817A1

  公开（公告）日：2016-03-17

  A halogen resistant polyamide is formed from the reaction product of an amine monomer and an acid chloride monomer wherein the amino group of the starting amine monomer is separated from the aromatic amine ring system by an alkyl group and (i) minimizes halogenation on the amine and (ii) minimizes N-halogenation at a pH range of approximately 7 to approximately 10.5. A membrane is made from the polyamide for use, for example, in a reverse osmosis desalination unit.

  一种耐卤素的聚酰胺是由胺单体和酸氯化物单体的反应产物形成的，其中起始胺单体的氨基团被烷基分离出芳香胺环系统，并且（i）最小化氨基上的卤素化和（ii）在大约7至大约10.5的pH范围内最小化N-卤素化。从聚酰胺制成膜，例如用于反渗透海水淡化装置。
• [EN] O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF<br/>[FR] COMPOSÉS DE O-IMINO-ISO-URÉE ET LEURS COMPOSITIONS POLYMÉRISABLES
  申请人：BASF SE

  公开号：WO2010128062A1

  公开（公告）日：2010-11-11

  The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R100and R101 are independently H, C1-18 alkyl, C3-C12cycloalkyl, C6-C14aryl, C1-C14heteroaryl, C7-C15aralkyl, C2-C14heteroaralkyl, Cyano, or R100 and R101 form together with the carbon to which they are attached a mono or polycyclic C3-C18 carbocyclic or C1-C18 heterocyclic ring; R102 and R103 are independently C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C6-C14aryl once or more than once substituted by C1-C18alkyl; C7-C15aralkyl, (CH3)3Si-; or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl, C6-C14aryl, C7-C15aralkyl or R102 and R103 are C1-C18alkyl, C3-C12cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C1-C18alkylamino, bis(C1-C18alkyl)amino or tris(C1-C1talkyl)ammonium; R104 if n is 1 is is H, C1-C18alkyl, C3-C12cycloalkyl, C7-C14aralkyl, C6-C14aryl or acyl selected from the group consisting of the following acyls -C(=O)-H, -C(=O)-C1-C18alkyl, -C(=O)-C2-d18alkenyl, -C(=O)-C6-C14aryl, -C(=O)-C2-C18alkenyl-C6-C14aryl, -C(=O)-O-C1C18alkyl, -C(=O)-O-C6-C14aryl, -C(=O)-NH-C1-C18alkyl, -C(=O)-NH-C6-C14aryl and -C(=O)-N(C1C18alkyl)2; or R102 and R104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R104 if n is more than 1 is di-, tri-, tetra-C1-C18alkylidene, diacyls, triacyls or tetraacyls and salts thereof.

  该发明涉及将O-亚亚胺基-异脲化合物用作自由基的来源，用于包括这些O-亚亚胺基-异脲化合物的聚合物组合物，以及新的O-亚亚胺基-异脲化合物。O-亚亚胺基-异脲化合物是具有以下式（I）的化合物，其中n为1、2、3或4，R100和R101独立地为H、C1-18烷基、C3-C12环烷基、C6-C14芳基、C1-C14杂芳基、C7-C15芳基烷基、C2-C14杂芳基烷基、氰基，或R100和R101与它们连接的碳共同形成一个单环或多环的C3-C18碳环或C1-C18杂环；R102和R103独立地为C1-C18烷基、C3-C12环烷基、C6-C14芳基、C6-C14芳基，或被C1-C18烷基取代一次或多次，C7-C15芳基烷基，（CH3）3Si-；或者R102和R103为C1-C18烷基、C3-C12环烷基、C6-C14芳基、C7-C15芳基烷基，或者R102和R103为被O或N含基团中断或取代的C1-C18烷基胺基、双（C1-C18烷基）胺基或三（C1-C1talkyl）铵；如果n为1，则R104为H、C1-C18烷基、C3-C12环烷基、C7-C14芳基烷基、C6-C14芳基或从以下酰基中选择的酰基 -C（=O）-H、-C（=O）-C1-C18烷基、-C（=O）-C2-d18烯基、-C（=O）-C6-C14芳基、-C（=O）-C2-C18烯基-C6-C14芳基、-C（=O）-O-C1C18烷基、-C（=O）-O-C6-C14芳基、-C（=O）-NH-C1-C18烷基、-C（=O）-NH-C6-C14芳基和-C（=O）-N（C1C18烷基）2；或者如果n为1，则R102和R104共同与它们连接的氮原子形成一个含有额外杂原子的5至12元环；如果n大于1，则R104为二、三、四个C1-C18烷基亚甲基、二酰基、三酰基或四酰基及其盐。
• POLYESTER RESIN COMPOSITION CONTAINING AMINO-TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20160194477A1

  公开（公告）日：2016-07-07

  A polyester resin composition containing 100 parts by mass of a polyester resin and 0.01 to 10 parts by mass of a 2-amino-1,3,5-triazine derivative of Formula [1]: a polyester resin molded body obtained by the composition, and a crystal nucleating agent including the triazine derivative. A polyester resin composition containing a crystal nucleating agent that makes it possible to produce, with high productivity, a polyester resin molded product that promotes polyester resin crystallization and maintains high transparency after crystallization and is applicable for a wide variety of uses can be provided.

  一种聚酯树脂组合物，包含100质量部的聚酯树脂和0.01至10质量部的公式[1]中2-氨基-1,3,5-三嗪衍生物；通过该组合物获得的聚酯树脂成型体，以及包括三嗪衍生物的晶核剂。可以提供一种聚酯树脂组合物，包含能够高效生产聚酯树脂成型产品的晶核剂，促进聚酯树脂结晶并在结晶后保持高透明度，适用于各种用途。
• OPTICAL FILM, RETARDATION PLATE, ELLIPTICA POLARIZING PLATE, LIQUID CRYSTAL DISPLAY DEVICE AND COMPOUND
  申请人：HAMASAKI Ryo

  公开号：US20100239788A1

  公开（公告）日：2010-09-23

  An optical film comprising at least one compound represented by formula (1) is disclosed. In the formula, Y 11 , Y 12 and Y 13 each independently represent methine or a nitrogen atom; R 11 , R 12 and R 13 each independently represent formula (A), (B) or (C) or a hydrogen atom, provided that at least two of R 11 , R 12 and R 13 each independently represent formula (A), (B) or (C). In three formulae, L 12 , L 22 and L 32 each represent a 5 -membered heterocyclic group.

  公开了一种包含至少一种由式（1）表示的化合物的光学薄膜。在该式中，Y11、Y12和Y13分别独立表示亚甲基或氮原子；R11、R12和R13分别独立表示式（A）、（B）或（C）或氢原子，但至少有两个R11、R12和R13分别独立表示式（A）、（B）或（C）。在三个式子中，L12、L22和L32各代表一个5-成员杂环基团。