5-phenylthio-2-(2-hydroxy-5-tert-butylphenyl)-2H-benzotriazole

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 5-phenylthio-2-(2-hydroxy-5-tert-butylphenyl)-2H-benzotriazole
• 英文别名: 4-Tert-butyl-2-(5-phenylsulfanylbenzotriazol-2-yl)phenol
• 化学式: C₂₂H₂₁N₃OS
• 分子量: 375.494
• InChiKey: CDGDLSQTCGMBQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.7
• 重原子数：
  27
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  76.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-Trifluoromethyl-2-(2-hydroxy-3-(di-n-butylaminomethyl)-5-tert-octylphenyl)-2H-benzotriazole 、 5-phenylthio-2-(2-hydroxy-5-tert-butylphenyl)-2H-benzotriazole 在 盐酸 、 sodium methylate 作用下， 以8.67 g的产率得到Methylene-2-[4-tert-butyl-6-(5-phenylthio-2H-benzotriazol-2-yl)pheol]-2'-[4-tert-octyl-6-(5-trifluoromethyl-2H-benzotriazol-2-yl)phenol]
  参考文献：
  名称：

  Asymmetrical bisbenzotriazoles substituted by a perfluoroalkyl moiety and compositions stabilized therewith

  摘要：

  公式I中的不对称双苯并三唑，其中G2′是1至12个碳原子的全氟烷基，优选CF3，而G2不含该基团，这些物质发生红移，由于不对称性，它们在许多应用中特别溶解且有用，包括汽车涂料、热塑性塑料，特别是在粘合剂组合物中，这些组合物本身在太阳能电池板和其他层压结构中有用。

  公开号：

  US06337402B2

文献信息

• Asymmertical bisbenzotriazoles substituted by a perfluoroalkyl moiety and compositions stabilized therewith
  申请人：——

  公开号：US20010011113A1

  公开（公告）日：2001-08-02

  Asymmetrical bisbenzotriazoles of the formula I 1 where G 2 ′ is perfluoroalkyl of 1 to 12 carbon atoms, preferably CF 3 , and where G 2 does not contain said group are red-shifted and due to the asymmetry are particularly soluble and useful in a host of applications including automotive coatings, thermoplastics and especially in adhesive compositions, themselves useful in solar panels and other laminate structures.

  公式为I1的不对称双苯并三氮唑，其中G2'是1至12个碳原子的全氟烷基，优选CF3，而G2不含该基团的化合物具有红移特性，并由于不对称性而特别溶解，可用于众多应用，包括汽车涂料、热塑性材料，特别是在粘合剂组合物中，本身可用于太阳能电池板和其他层压结构。
• STABILIZED ADHESIVE COMPOSITIONS CONTAINING HIGHLY SOLUBLE, RED-SHIFTED, PHOTOSTABLE BENZOTRIAZOLE UV ABSORBERS AND LAMINATED ARTICLES DERIVED THEREFROM
  申请人：Ciba Specialty Chemicals Holding Inc.

  公开号：EP1175467A1

  公开（公告）日：2002-01-30
• US6245915B1
  申请人：——

  公开号：US6245915B1

  公开（公告）日：2001-06-12
• US6337402B2
  申请人：——

  公开号：US6337402B2

  公开（公告）日：2002-01-08
• [EN] STABILIZED ADHESIVE COMPOSITIONS CONTAINING HIGHLY SOLUBLE, RED-SHIFTED, PHOTOSTABLE BENZOTRIAZOLE UV ABSORBERS AND LAMINATED ARTICLES DERIVED THEREFROM<br/>[FR] COMPOSITIONS ADHESIVES STABILISEES CONTENANT DES ABSORBEURS D'U.V. A BASE DE BENZOTRIAZOLE DECALEES VERS LE ROUGE TRES SOLUBLES ET PHOTOSTABLES ET ARTICLES STRATIFIES FABRIQUES AVEC CES COMPOSITIONS
  申请人：CIBA SC HOLDING AG

  公开号：WO2000066676A1

  公开（公告）日：2000-11-09

  Adhesive compositions are rendered stable against degradation caused by ultraviolet light through the incorporation of selected highly soluble, red-shifted, photostable benzotriazole UV absorbers which absorb light strongly in the 350 to 400 nm range. Also suitable are 2-(2-hydroxy-3-α-cumyl-5-tert-octylphenyl)-2H-benzotriazole and 2-(2-hydroxy-3-α-cumyl-5-tert-butylphenyl)-2H-benzotriazole in combination with the red shifted benzotriazoles. A further subject of the invention are novel asymmetrical bisbenzotriazoles of formula (IIIc) where G2' is perfluoroalkyl of 1 to 12 carbon atoms, preferably CF3, and where G2 does not contain said group are red-shifted and due to the asymmetry are particularly soluble and useful in a host of applications including automotive coatings, thermoplastics and especially in adhesive compositions, themselves useful in solar panels and other laminate structures. All these UV absorbers exhibit excellent photostability and are highly soluble in adhesive formulations. The laminated articles derived from these compositions include, for example, solar control films, films and glazings, UV absorbing glasses and glass coatings, windscreens, retroreflective sheetings and signs, solar reflectors, optical films and the like.