oleyl fluoride

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: oleyl fluoride
• 英文别名: (Z)-1-fluorooctadec-9-ene
• 化学式: C₁₈H₃₅F
• 分子量: 270.474
• InChiKey: XOOXYSIWFZYHMH-KTKRTIGZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  19
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  油醇 在 lithium fluoride 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到oleyl fluoride
  参考文献：
  名称：

  Manna, Sukumar; Falck, J. R.; Mioskowski, Charles, Synthetic Communications, 1985, vol. 15, # 8, p. 663 - 668

  摘要：

  DOI：

文献信息

• Selective Terminal Functionalization of Linear Alkanes**
  作者：Jeffrey Bruffaerts、Inbar Kesten、Keren Buhnik‐Rosenblau、Anthony Cohen、Nurit Edri、Morgan Cormier、Yuanfei Zhang、Guo‐Ming Ho、Itai Massad、Hila Halfon‐Verner、Yechezkel Kashi、Ilan Marek

  DOI：10.1002/anie.202306343

  日期：2023.7.24

  dehydrogenation/remote hydrofunctionalization as a unified and versatile approach to selectively convert linear alkanes into a large array of valuable functionalized aliphatic derivatives is reported. The reaction goes through a site-selective functionalization at the unreactive primary C−H bonds of the linear alkane and avoids the use of linear α-olefins.

  据报道，一种两步序贯策略，涉及生物催化脱氢/远程加氢官能化作为一种​​统一且通用的方法，选择性地将直链烷烃转化为大量有价值的官能化脂肪族衍生物。该反应在直链烷烃的非反应性伯 CH 键处进行位点选择性官能化，并避免使用直链 α-烯烃。
• RING OPENING CROSS-METATHESIS REACTION OF CYCLIC OLEFINS WITH SEED OILS AND THE LIKE
  申请人：Elevance Renewable Sciences, Inc.

  公开号：EP2046719A2

  公开（公告）日：2009-04-15
• TELECHELIC OLEFIN METATHESIS POLYMERS FROM RENEWABLE FEEDSTOCKS
  申请人：Materia, Inc.

  公开号：EP2321363A1

  公开（公告）日：2011-05-18
• Ring opening cross-metathesis reaction of cyclic olefins with seed oils and the like
  申请人：Lee Woo Choon

  公开号：US20080064891A1

  公开（公告）日：2008-03-13

  This invention relates generally to olefin metathesis, and more particularly relates to the ring-opening, ring insertion cross-metathesis of cyclic olefins with internal olefins such as seed oils and the like. In one embodiment, a method is provided for carrying out a catalytic ring-opening cross-metathesis reaction, comprising contacting at least one olefinic substrate with at least one cyclic olefin as a cross metathesis partner, in the presence of a ruthenium alkylidene olefin metathesis catalyst under conditions effective to allow ring insertion cross metathesis whereby the cyclic olefin is simultaneously opened and inserted into the olefinic substrate. The invention has utility in the fields of catalysis, organic synthesis, and industrial chemistry.
• US8067623B2
  申请人：——

  公开号：US8067623B2

  公开（公告）日：2011-11-29