2,4-bis(4-[1-ethoxycarbonyl-1-methylethoxy]-2-hydroxyphenyl)-6-mono-(4-[1-(N,N-bis-butylaminocarbonyl)-1-methyl-ethoxy]-2-hydroxyphenyl)-1,3,5-triazine

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-bis(4-[1-ethoxycarbonyl-1-methylethoxy]-2-hydroxyphenyl)-6-mono-(4-[1-(N,N-bis-butylaminocarbonyl)-1-methyl-ethoxy]-2-hydroxyphenyl)-1,3,5-triazine
• 英文别名: Ethyl 2-[4-[4-[4-[1-(dibutylamino)-2-methyl-1-oxopropan-2-yl]oxy-2-hydroxyphenyl]-6-[4-(1-ethoxy-2-methyl-1-oxopropan-2-yl)oxy-2-hydroxyphenyl]-1,3,5-triazin-2-yl]-3-hydroxyphenoxy]-2-methylpropanoate；ethyl 2-[4-[4-[4-[1-(dibutylamino)-2-methyl-1-oxopropan-2-yl]oxy-2-hydroxyphenyl]-6-[4-(1-ethoxy-2-methyl-1-oxopropan-2-yl)oxy-2-hydroxyphenyl]-1,3,5-triazin-2-yl]-3-hydroxyphenoxy]-2-methylpropanoate
• 化学式: C₄₅H₅₈N₄O₁₁
• 分子量: 830.976
• InChiKey: BSFUQKKFCJRZBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  60
• 可旋转键数：
  22
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  200
• 氢给体数：
  3
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  2,4,6-tris(2-hydroxy-4-[1-ethyloxycarbonyl-1-methylethoxy]phenyl)-1,3,5-triazine 、 二正丁胺 在 三甲基铝 作用下， 以 正己烷 、 二氯甲烷 、 xylene 为溶剂， 反应 72.25h， 生成 2,4-bis(4-[1-ethoxycarbonyl-1-methylethoxy]-2-hydroxyphenyl)-6-mono-(4-[1-(N,N-bis-butylaminocarbonyl)-1-methyl-ethoxy]-2-hydroxyphenyl)-1,3,5-triazine 、 2-mono(4-[1-ethoxycarbonyl-1-methylethoxy]-2-hydroxyphenyl)-4,6-bis(4-[1-(N,N-bis-butylaminocarbonyl)-1-methylethoxy]-2-hydroxyphenyl)-1,3,5-triazine 、 2,4,6-tris(4-[1-(N,N-bis-butylaminocarbonyl)-1-methylethoxy]-2-hydroxyphenyl)-1,3,5-triazine
  参考文献：
  名称：

  Triresorcinyl triazines

  摘要：

  式中的化合物，其中Z，Z'和Z''彼此独立地是式II的一个基团，而R7是式III，IV或V的一个基团，其中n为1或2；R4，R5和R6彼此独立地是C1-C18烷基；C5-C12环烷基；C2-C18烯基；苯基；C7-C11苯基烷基；C7-C11烷基苯基；被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18烯氧基，COOH，COOR11，O—COR12，CONH2，CONHR13，CONR13NR14，CN，NH2，NHR13，NR13R14，NHCOR12，C6-C15双环烷基，C6-C16双环烷氧基，C6-C16双环烯基氧基或C6-C15三环烷氧基取代的C1-C18烷基；被OH，C1-C4烷基，C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或被O打断和/或取代的C3-C50烷基，OH，苯氧基或C7-C18烷基苯氧基；或R5和R6一起形成一个环结构；X和Y彼此独立地是O，NH，NR13或S；其他符号如权利要求1所定义的对有机材料对抗光，氧和/或热的破坏效应具有稳定作用。

  公开号：

  US06346619B1

文献信息

• Trisresorcinyltriazines
  申请人：——

  公开号：US20020086922A1

  公开（公告）日：2002-07-04

  Compounds of the formula 1 in which Z, Z′ and Z″ independently of one another are a group of the formula II 2 (II) and R 7 is a radical of the formula III, IV or V 3 in which n is 1 or 2; R 4 , R 5 and R 6 independently of one another are C 1 -C 18 alkyl; C 5 -C 12 cycloalkyl; C 2 -C 18 alkenyl; phenyl; C 7 -C 11 phenylalkyl; C 7 -C 11 alkylphenyl; C 1 -C 18 alkyl substituted by phenyl, OH, C 1 -C 18 alkoxy, C 5 -C 12 cycloalkoxy, C 3 -C 18 alkenyloxy, COOH, COOR 11 , O—COR 12 , CONH 2 , CONHR 13 , CONR 13 NR 14 , CN, NH 2 , NHR 13 , NR 13 R 14 , NHCOR 12 , C 6 -C 15 bicycloalkyl, C 6 -C 16 bicycloalkyl-alkoxy, C 6 -C 16 bicycloalkenyl-alkoxy or C 6 -C 15 tricycloalkoxy; C 5 -C 12 cycloalkyl substituted by OH, C 1 -C 4 alkyl, C 2 -C 6 alkenyl or O—COR 12 ; or COR 15 ; CO—X—R 11 ; or SO 2 —R 16 ; or C 3 -C 50 alkyl interrupted by O and/or substituted by OH, phenoxy or C 7 -C 18 alkylphenoxy; or R 5 and R 6 together form a ring structure; X and Y independently of one another are O, NH, NR 13 or S; and the other symbols are as defined in claim 1 are effective as stabilizers for organic material against the damaging effect of light, oxygen and/or heat.

  式1的化合物中，其中Z、Z'和Z''互相独立，是式II2(II)的基团，而R7是式III、IV或V3的基团，其中n为1或2；R4、R5和R6互相独立，是C1-C18烷基、C5-C12环烷基、C2-C18烯基、苯基、C7-C11苯基烷基、C7-C11烷基苯基、被苯基、OH、C1-C18烷氧基、C5-C12环烷氧基、C3-C18烯氧基、COOH、COOR11、O—COR12、CONH2、CONHR13、CONR13NR14、CN、NH2、NHR13、NR13R14、NHCOR12、C6-C15双环烷基、C6-C16双环烷氧基、C6-C16双环烯基氧基或C6-C15三环氧基取代的C1-C18烷基；被OH、C1-C4烷基、C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或C3-C50烷基被O打断和/或被OH、苯氧基或C7-C18烷基苯氧基取代；或R5和R6一起形成一个环结构；X和Y互相独立，是O、NH、NR13或S；其它符号如权利要求1所定义的，在有机材料中对抗光、氧和/或热的损害具有有效的稳定剂作用。
• US6346619B1
  申请人：——

  公开号：US6346619B1

  公开（公告）日：2002-02-12
• US6509400B2
  申请人：——

  公开号：US6509400B2

  公开（公告）日：2003-01-21
• Triresorcinyl triazines
  申请人：Ciba Specialty Chemicals Corporation

  公开号：US06346619B1

  公开（公告）日：2002-02-12

  Compounds of the formula in which Z, Z′ and Z″ independently of one another are a group of the formula II and R7 is a radical of the formula III, IV or V in which n is 1 or 2; R4, R5 and R6 independently of one another are C1-C18alkyl; C5-C12cycloalkyl; C2-C18alkenyl; phenyl; C7-C11phenylalkyl; C7-C11alkylphenyl; C1-C18alkyl substituted by phenyl, OH, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C18alkenyloxy, COOH, COOR11, O—COR12, CONH2, CONHR13, CONR13NR14, CN,NH2, NHR13, NR13R14, NHCOR12, C6-C15bicycloalkyl, C6-C16bicycloalkyl-alkoxy, C6-C16bicycloalkenyl-alkoxy or C6-C15tricycloalkoxy; C5-C12cycloalkyl substituted by OH, C1-C4alkyl, C2-C6alkenyl or O—COR12; or COR15; CO—X—R11; or SO2—R16; or C3-C50alkyl interrupted by O and/or substituted by OH, phenoxy or C7-C18alkylphenoxy; or R5 and R6 together form a ring structure; X and Y independently of one another are O, NH, NR13 or S; and the other symbols are as defined in claim 1 are effective as stabilizers for organic material against the damaging effect of light, oxygen and/or heat.

  式中的化合物，其中Z，Z'和Z''彼此独立地是式II的一个基团，而R7是式III，IV或V的一个基团，其中n为1或2；R4，R5和R6彼此独立地是C1-C18烷基；C5-C12环烷基；C2-C18烯基；苯基；C7-C11苯基烷基；C7-C11烷基苯基；被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18烯氧基，COOH，COOR11，O—COR12，CONH2，CONHR13，CONR13NR14，CN，NH2，NHR13，NR13R14，NHCOR12，C6-C15双环烷基，C6-C16双环烷氧基，C6-C16双环烯基氧基或C6-C15三环烷氧基取代的C1-C18烷基；被OH，C1-C4烷基，C2-C6烯基或O—COR12取代的C5-C12环烷基；或COR15；CO—X—R11；或SO2—R16；或被O打断和/或取代的C3-C50烷基，OH，苯氧基或C7-C18烷基苯氧基；或R5和R6一起形成一个环结构；X和Y彼此独立地是O，NH，NR13或S；其他符号如权利要求1所定义的对有机材料对抗光，氧和/或热的破坏效应具有稳定作用。