二烟酸锰 | 28029-54-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 二烟酸锰
• 中文别名: N-环己基-6-(吡啶-3-基)-1,3,5-三嗪-2,4-二胺
• 英文名称: Bis(nicotinato)manganese(II)
• 英文别名: Manganese dinicotinate；manganese(2+);pyridine-3-carboxylate
• CAS: 28029-54-1
• 化学式: C₁₂H₈MnN₂O₄
• 分子量: 299.145
• InChiKey: DGCVKTDQGSVWLG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.11
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  3-氰基吡啶 、 manganese(II) perchlorate hexahydrate 在 C₅H₅N 作用下， 以 乙醇 、 水 为溶剂， 生成 二烟酸锰
  参考文献：
  名称：

  基于间吡啶羧酸盐的三维锰（II）配位聚合物：合成，X射线结构和磁性。

  摘要：

  3-D manganese(II) coordination polymers bis(nico-tinato)manganese, 1, and bis[4-(3-pyridyl)ethynylben-zoato]manganese, 2, were synthesized under hydro(solvo)thermal conditions. Compounds 1 and 2 exhibit remarkably similar network topologies probably as a result of the same bent configurations and rigid structures of the m-pyridinecarboxylate ligands. Magnetic measurements of 1 and 2 indicate dominant antiferromagnetic interactions along the carboxylate-bridged Mn(II)-Mn(II) chains, and they represent new examples of one-dimensional Heisenberg antiferromagnetic chains.

  DOI：

  10.1021/ic000227v

文献信息

• Three-Dimensional Manganese(II) Coordination Polymers Based on <i>m</i>-Pyridinecarboxylates:  Synthesis, X-ray Structures, and Magnetic Properties
  作者：Wenbin Lin、Mary E. Chapman、Zhiyong Wang、Gordon T. Yee

  DOI：10.1021/ic000227v

  日期：2000.9.1

  3-D manganese(II) coordination polymers bis(nico-tinato)manganese, 1, and bis[4-(3-pyridyl)ethynylben-zoato]manganese, 2, were synthesized under hydro(solvo)thermal conditions. Compounds 1 and 2 exhibit remarkably similar network topologies probably as a result of the same bent configurations and rigid structures of the m-pyridinecarboxylate ligands. Magnetic measurements of 1 and 2 indicate dominant antiferromagnetic interactions along the carboxylate-bridged Mn(II)-Mn(II) chains, and they represent new examples of one-dimensional Heisenberg antiferromagnetic chains.