二环[2,2,1]庚-2-烯和乙烯的聚合物 | 26007-43-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 中文名称: 二环[2,2,1]庚-2-烯和乙烯的聚合物
• 英文名称: Bicyclo[2.2.1]hept-2-ene;ethene
• CAS: 26007-43-2
• 化学式: C9H14
• 分子量: 122.21
• InChiKey: SFFFIHNOEGSAIH-UHFFFAOYSA-N

物化性质

• 熔点：
  128.8 °C
• 密度：
  0.946 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.77
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• WGK Germany：
  3

反应信息

• 作为产物：
  描述：

  碘 、 降冰片烯 生成 二环[2,2,1]庚-2-烯和乙烯的聚合物
  参考文献：
  名称：

  Homogeneous olefin polymerization catalyst by abstraction with lewis

  摘要：

  一种制备具有限制电荷分离结构的加成聚合催化剂的方法，其对应公式为：LMX.sup.+ XA.sup.-，其中：L是一种取代的共轭π键基团的衍生物，赋予金属活性位点约束几何结构，含有多达50个非氢原子；M是元素周期表中第4组或镧系元素的金属；X是独立的，每次出现都是氢化物或具有多达20个碳、硅或锗原子的烃基、硅基或锗基；A.sup.-是一种Lewis酸的阴离子A，其相对Lewis酸性大于或等于苯基双(全氟苯基)硼烷，该阴离子与金属阳离子相容，该方法的步骤包括将与上述公式相对应的第4组或镧系金属的衍生物即LMX.sub.2与Lewis酸A接触，以在条件下引起X的脱除和阴离子XA.sup.-的形成。

  公开号：

  US05721185A1

文献信息

• Olefin block copolymers processes for producing the same and uses thereof
  申请人：——

  公开号：US20030055179A1

  公开（公告）日：2003-03-20

  The present invention provides polymers having any one of properties including affinity for metals or polar resins, impact resistance, mar resistance, heat resistance, rigidity, oil resistance, transparency, anti-fogging properties, electric insulating properties, high breakdown voltage, coating properties, low-temperature flexibility, moldability, environmental degradation, fluidity and dispersibility, and provides a process for preparation thereof. The olefin block copolymers (A-1) of the invention are represented by the formula (I) PO 1 —g 1 —B 1 (I) (wherein PO 1 is a segment composed of repeating units derived from an olefin having 2 to 20 carbon atoms, g 1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B 1 is a segment containing an unsaturated hydrocarbon or a hetero atom). The olefin block copolymers are suitable for uses in adhesives; various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets; modifiers and dispersions.

  本发明提供了具有以下任一性质的聚合物，包括对金属或极性树脂的亲和性，抗冲击性，抗刮伤性，耐热性，刚度，耐油性，透明性，防雾性能，电绝缘性能，高击穿电压，涂料性能，低温柔性，可塑性，环境降解性，流动性和分散性，并提供其制备方法。本发明的烯烃嵌段共聚物（A-1）由公式（I）表示：PO1-g1-B1（I）（其中PO1是由具有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯，醚，酰胺，亚胺，脲，硅醚或羰基连接，B1是含有不饱和碳氢化合物或杂原子的片段）。烯烃嵌段共聚物适用于粘合剂；各种成型品，如建筑和土木工程材料，汽车内外饰料，汽油箱，电子和电气零件，医疗保健和卫生材料，杂货物料，具有环境降解性能的树脂材料，薄膜和片材；改性剂和分散剂。
• Method for producing cycloolefin (CO) polymers for use in optical data memories
  申请人：Bayer Aktiengesellschaft

  公开号：US06232413B1

  公开（公告）日：2001-05-15

  Cycloolefin copolymers for use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, &agr;-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or &pgr; complex compounds of the formula in which CpI and CpII represent carbanions having a cyclopentadienyl-containing structure, &pgr;I and &pgr;II represent charged or electrically neutral &pgr; systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of elements (Mendeleev), including the lanthanides and the actinides, X denotes an anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

  环氧烷共聚物可用于光学数据存储，可通过环氧烷、具有2个或更多C原子的α-烯烃和可选的共轭或非共轭二烯单体的共聚制备，所使用的催化剂为金属茂化合物或具有以下式的π络合物： 其中CpI和CpII代表具有环戊二烯基结构的负离子，πI和πII代表带电或电中性的π系统，D代表给体原子，A代表受体原子，其中D和A通过可逆的配位键连接，使得给体基团呈正（部分）电荷，受体基团呈负（部分）电荷，M代表元素周期表（门捷列夫）的III、IV、V或VI次族的过渡金属，包括镧系和锕系元素，X表示相当于阴离子的离子，n表示取决于M的电荷的0、1、2、3或4个数。
• Imidochromium compounds contained in catalyst systems for olefin polymerization
  申请人：Basell Polyolefine GmbH

  公开号：US06784261B1

  公开（公告）日：2004-08-31

  The present invention relates to catalyst system containing at least one imidochrome compound and at least one activation compound. This invention also relates to imidochrome compounds, to a method for olefin polymerization and to methods for producing said imidochrome compounds.

  本发明涉及至少含有一种咪唑色化合物和至少一种活化剂化合物的催化剂系统。本发明还涉及咪唑色化合物，烯烃聚合的方法以及制备所述咪唑色化合物的方法。
• Olefin block copolymers, processes for producing the same and uses thereof
  申请人：Mitsui Chemicals, Inc.

  公开号：US07160949B2

  公开（公告）日：2007-01-09

  Olefin block copolymers (A-1) are disclosed represented by the formula (I) PO1-g1-B1 . . . (I) wherein PO1 is a segment comprised of repeating units derived from an olefin having 2 to 20 carbon atoms, g1 is an ester, ether, amide, imide, urethane, urea, silylether or carbonyl linkage, and B1 is a segment containing an unsaturated hydrocarbon or a hetero atom. The olefin block copolymers are suitable for uses in adhesives, various molded articles such as construction and civil engineering materials, automobile interior and exterior materials, gasoline tanks, electric and electronic parts, medical care and sanitation materials, materials of miscellaneous goods, resin materials having environmental degradation properties, films and sheets, modifiers and dispersions.

  公开了一种由式(I) PO1-g1-B1表示的烯烃嵌段共聚物(A-1)。其中，PO1是由含有2至20个碳原子的烯烃衍生的重复单元组成的片段，g1是酯、醚、酰胺、亚胺、脲、硅基醚或羰基连接的片段，B1是含有不饱和碳氢化合物或杂原子的片段。该烯烃嵌段共聚物适用于粘合剂、各种模塑制品，如建筑和土木工程材料、汽车内外饰材料、汽油箱、电子部件、医疗保健和卫生材料、杂货物材料、具有环境降解性能的树脂材料、膜和片材、改性剂和分散剂等用途。
• Method for producing cycloolefin (co)polymers for technical applications
  申请人：Bayer Aktiengesellschaft

  公开号：US06156857A1

  公开（公告）日：2000-12-05

  Cycloolefin copolymers for industrial applications, with the exception of the use for optical data memories, can be prepared by copolymerization of monomers from the group consisting of cyclic olefins, .alpha.-olefins having 2 or more C atoms and optionally conjugated or non-conjugated diolefins, the catalysts employed being metallocene compounds or .pi. complex compounds of the formula ##STR1## in which CpI and CpII represent carbanions having a cyclopenadienyl-containing structure, .pi.I and .pi.II represent charged or electrically neutral .pi. systems, D represents a donor atom and A represents an acceptor atom, where D and A are linked by a reversible coordinate bond such that the donor group assumes a positive (part) charge and the acceptor group assumes a negative (part) charge, M represents a transition metal of sub-group III, IV, V or VI of the Periodic Table of the elements (Mendeleev), including the lanthanides and the actinides, X denotes one anion equivalent and n denotes the number zero, one, two, three or four, depending on the charge of M.

  环氧烷基共聚物可用于工业应用，但不包括用于光学数据存储。该共聚物可通过环烯烃、α-烯烃（具有2个或更多碳原子）和可选的共轭或非共轭双烯烃的共聚反应制备，所使用的催化剂为金属茂化合物或公式##STR1##的π配合物。其中CpI和CpII代表具有环戊二烯基结构的碳负离子，π.I和π.II代表带电或电中性的π体系，D代表给体原子，A代表受体原子，其中D和A通过可逆的配位键连接，使得给体基团呈正（部分）电荷，受体基团呈负（部分）电荷，M代表元素周期表（门捷列夫）的III、IV、V或VI族过渡金属，包括镧系和锕系元素，X表示一个阴离子当量，n表示数字0、1、2、3或4，取决于M的电荷。