9-butylbicyclo[6.1.0]nonane

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: 9-butylbicyclo[6.1.0]nonane
• 化学式: C₁₃H₂₄
• 分子量: 180.334
• InChiKey: XGJXFQGEGIFPMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.39
• 重原子数：
  13.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  顺-环辛烯 在 溴丁基-镁 、 sodium hydroxide 、 苄基三乙基氯化铵 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 二氯甲烷 为溶剂， 反应 27.17h， 生成 9-butylbicyclo[6.1.0]nonane
  参考文献：
  名称：

  Reactions ofgem-Dibromo Compounds with Trialkylmagnesate Reagents to Yield Alkylated Organomagnesium Compounds

  摘要：

  The reaction of gem-dibromocyclopropanes 5 with nBu(3)MgLi affords butylated cyclopropylmagnesium species that can be trapped with various electrophiles. The reaction of dibromomethylsilanes 12 requires the addition of a catalytic amount of CuCN.2LiCl for smooth migration of the alkyl groups. The resultant alpha-silylpentylmagnesium compounds 16 react with electrophiles, such as acyl chlorides or alpha.beta-unsaturated ketones to afford alpha- or gamma-silyl ketones, respectively. Treatment of dibromodisilylmethanes with Me3MgLi yields 1-bromo-1,1-disilylethanes 25 that can be converted into 1,1-disilylethenes 29 by dehydrobromination.

  DOI：

  10.1002/1521-3765(20020402)8:7<1730::aid-chem1730>3.0.co;2-6

文献信息

• Gai, Yonghua; Julia, Marc; Verpeaux, Jean-Noel, Bulletin de la Societe Chimique de France, 1996, vol. 133, # 9, p. 817 - 829
  作者：Gai, Yonghua、Julia, Marc、Verpeaux, Jean-Noel

  DOI：——

  日期：——
• Reactions ofgem-Dibromo Compounds with Trialkylmagnesate Reagents to Yield Alkylated Organomagnesium Compounds
  作者：Atsushi Inoue、Junichi Kondo、Hiroshi Shinokubo、Koichiro Oshima

  DOI：10.1002/1521-3765(20020402)8:7<1730::aid-chem1730>3.0.co;2-6

  日期：2002.4.2

  The reaction of gem-dibromocyclopropanes 5 with nBu(3)MgLi affords butylated cyclopropylmagnesium species that can be trapped with various electrophiles. The reaction of dibromomethylsilanes 12 requires the addition of a catalytic amount of CuCN.2LiCl for smooth migration of the alkyl groups. The resultant alpha-silylpentylmagnesium compounds 16 react with electrophiles, such as acyl chlorides or alpha.beta-unsaturated ketones to afford alpha- or gamma-silyl ketones, respectively. Treatment of dibromodisilylmethanes with Me3MgLi yields 1-bromo-1,1-disilylethanes 25 that can be converted into 1,1-disilylethenes 29 by dehydrobromination.