1-(4-tert-butyl-phenoxy)-2-(2-chloro-ethoxy)-ethane

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-tert-butyl-phenoxy)-2-(2-chloro-ethoxy)-ethane
• 英文别名: 1-(4-tert-Butyl-phenoxy)-2-(2-chlor-aethoxy)-aethan；1-Tert-butyl-4-[2-(2-chloroethoxy)ethoxy]benzene
• 化学式: C₁₄H₂₁ClO₂
• 分子量: 256.773
• InChiKey: XMLRCXMINSKJTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  十六烷基二甲基叔胺 、 1-(4-tert-butyl-phenoxy)-2-(2-chloro-ethoxy)-ethane 反应 24.0h， 生成
  参考文献：
  名称：

  Characterization of fluorescent surfactant aggregates by fluorimetric and viscosimetric techniques

  摘要：

  A combination of fluorimetric and viscosimetric methods was used to characterize N,N-dimethyl-N-2-(4-(t-butylphenoxy)ethoxy)ethyl-N-hexadecylammonium chloride (BDHC), a double-tailed surfactant with dissimilar tail groups. BDHC was observed to fluoresce at 315 nm when excited at 274 nm, a feature which could be utilized to determine its critical micelle concentration (CMC). A value of 3.98 x 10(-5) M was obtained and was observed to be slightly temperature dependent with a T-min of 25.35 degrees C. Fluorescence quenching experiments using 4-nitroaniline as a quencher were performed in order to determine the aggregation number which was found to be 42.0. The hydrodynamic radius of 21.91 Angstrom was obtained using data from viscosimetric experiments. These data, together with the Tanford and Einstein-Stokes relationships, were used to determine the micellar structure (spherical) and the diffusion coefficient (D = 0.97 x 10(-6) cm2/s), respectively. The Delta G of micellization for BDHC was determined to be -34.9 kJ/mol.

  DOI：

  10.1007/bf00807588
• 作为产物：
  描述：

  4-叔丁基苯酚 、 二氯乙醚 在 sodium hydroxide 作用下， 生成 1-(4-tert-butyl-phenoxy)-2-(2-chloro-ethoxy)-ethane
  参考文献：
  名称：

  Surface active materials

  摘要：

  公开号：

  US02299782A1

文献信息

• US2229024
  申请人：——

  公开号：——

  公开（公告）日：——
• Manufacture of amines
  申请人：ROHM &

  公开号：US02170111A1

  公开（公告）日：1939-08-22
• Aromatic polyether amines
  申请人：ROHM & HAAS

  公开号：US02132674A1

  公开（公告）日：1938-10-11
• (aryloxy-alkyl) (thiocyano-alkyl) ether
  申请人：DOW CHEMICAL CO

  公开号：US02218019A1

  公开（公告）日：1940-10-15