1,1,9,9-Tetrakis(4-methoxyphenyl)-1,8-nonadiene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,9,9-Tetrakis(4-methoxyphenyl)-1,8-nonadiene
• 英文别名: 1-Methoxy-4-[1,9,9-tris(4-methoxyphenyl)nona-1,8-dienyl]benzene
• 化学式: C₃₇H₄₀O₄
• 分子量: 548.722
• InChiKey: KRHWCTIGHGETST-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  41
• 可旋转键数：
  14
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,1,9,9-Tetrakis(4-methoxyphenyl)-1,8-nonadiene 在 二氯乙酸 、 氧气 作用下， 以 乙腈 、 苯 为溶剂， 反应 0.17h， 以89%的产率得到4,4'-二甲氧基二苯甲酮
  参考文献：
  名称：

  1，ω-双（二芳基乙烯基）烷烃通过光致电子转移的光氧化作用：双环过氧化物的形成

  摘要：

  研究了乙腈中Ar 2 C = CH（CH 2）n CH = CAr 2的9,10-二氰基蒽（DCA）致敏的光氧合反应。当Ar ＝ 4-CH 3 OC 6 H 4，n ＝ 3和4时，经由1，4-自由基阳离子获得双环过氧化物，所述1，4-自由基阳离子是由链二烯的两个乙烯基部分之间的分子内相互作用产生的。

  DOI：

  10.1016/s0040-4039(00)77645-3

文献信息

• Photooxygenation of 1, ω-bis(diarylethenyl)alkanes via photoinduced electron transfer: Formation of bicyclic peroxides
  作者：Toshiyuki Tamai、Kazuhiko Mizuno、Isao Hashida、Yoshio Otsuji

  DOI：10.1016/s0040-4039(00)77645-3

  日期：1993.4

  The 9,10-dicyanoanthracene (DCA)-sensitized photooxygenation of Ar2C=CH(CH2)nCH=CAr2 in acetonitrile was studied. When Ar = 4-CH3OC6H4, n = 3 and 4, bicyclic peroxides were obtained via 1,4-radical cations that are generated by intramolecular interaction between two ethenyl moieties of the alkadienes.

  研究了乙腈中Ar 2 C = CH（CH 2）n CH = CAr 2的9,10-二氰基蒽（DCA）致敏的光氧合反应。当Ar ＝ 4-CH 3 OC 6 H 4，n ＝ 3和4时，经由1，4-自由基阳离子获得双环过氧化物，所述1，4-自由基阳离子是由链二烯的两个乙烯基部分之间的分子内相互作用产生的。
• Photooxygenation of 1,.omega.-Bis(diarylethenyl)alkanes via Photoinduced Electron-Transfer: Formation of 1,4-Radical Cations and Their Trapping by Molecular Dioxygen
  作者：Kazuhiko Mizuno、Toshiyuki Tamai、Isao Hashida、Yoshio Otsuji、Yasunao Kuriyama、Katsumi Tokumaru

  DOI：10.1021/jo00103a025

  日期：1994.12

  The 9,10-dicyanoanthracene (DCA)-sensitized photooxygenation of 1,omega-bis(diarylethenyl)alkanes (Ar2C=CH(CH2)(n)CH=CAr2) was studied. The photooxygenation of the alkadienes in acetonitrile afforded bicyclic peroxides when Ar = 4-CH3OC6H4, n = 3 and 4. When Ar = 4-CH3OC6H4, n = 2, 5, 8 or Ar = C6H5, n = 3, the photooxygenation did not afford bicyclic peroxides, but gave diaryl ketones. Laser flash photolysis studies indicated that the photooxygenation is initiated by a one-electron transfer from the alkadienes to (1)DCA* and proceeds via 1,4-radical cations that are generated by an intramolecular cyclization between an ethenyl moiety and a radical cation of another ethenyl moiety.