di(bromophenyl)carbonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di(bromophenyl)carbonate
• 英文别名: Bis(2-bromophenyl) carbonate
• 化学式: C₁₃H₈Br₂O₃
• 分子量: 372.013
• InChiKey: LUQQDEDMRRRWGN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  二碘二氟甲烷 、 2-溴苯酚 在 对二硝基苯 、 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.5h， 以38%的产率得到di(bromophenyl)carbonate
  参考文献：
  名称：

  The reactions of difluorodiiodomethane with nucleophiles

  摘要：

  Treatment of difluorodiiodomethane with phenoxides (ArO-) in DMF at room temperature gives ArOCF2I in 7-15%, the carbonates (ArOCO2Ar) being the major products, while with thiophenoxides affords difluoromethylene derivatives (ArSCF2I, ArSCF2SAr, and ArSCF2H) also in low yields. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(99)00228-6

文献信息

• [EN] PHOSPHO-SUBSTITUTED ALKOXYAMINE COMPOUNDS<br/>[FR] COMPOSÉS ALCOXYAMINE SUBSTITUÉS PAR DES GROUPES PHOSPHO
  申请人：BASF SE

  公开号：WO2011086114A1

  公开（公告）日：2011-07-21

  The invention relates to compounds of the group of so-called sterically hindered amines (HALS) which are substituted by phospho groups. The invention also relates to flame retardant compositions wherein these compounds are added to the polymer substrate.

  该发明涉及一类所谓的受空间位阻影响的胺化合物（HALS），这些化合物被磷基取代。该发明还涉及阻燃组合物，其中这些化合物被添加到聚合物基质中。
• [EN] AMINOGUANIDINEPHENYLPHOSPHINATE FLAME RETARDANT COMPOSITIONS<br/>[FR] COMPOSITIONS IGNIFUGES À BASE D'AMINOGUANIDINEPHÉNYLPHOSPHINATE
  申请人：BASF SE

  公开号：WO2011138410A1

  公开（公告）日：2011-11-10

  The present invention relates to flame retardant polymer compositions which comprise aminoguanidine phenylphosphinates and mixtures with additional flame retardants. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates like polyesters, polyamides and polycarbonates.

  本发明涉及含有氨基胍苯基膦酸盐和其他阻燃剂混合物的阻燃聚合物组合物。该组合物特别适用于制造基于多官能团环氧树脂或聚酯、聚酰胺和聚碳酸酯的阻燃化合物。
• [EN] CONDENSATION PRODUCTS OF MELAMINE AND PHENYLPHOSPHONIC ACID AND THEIR USE AS FLAME RETARDANTS<br/>[FR] PRODUITS DE CONDENSATION DE MÉLAMINE ET DE L'ACIDE PHÉNYLPHOSPHONIQUE ET LEUR UTILISATION COMME IGNIFUGES
  申请人：BASF SE

  公开号：WO2012123870A1

  公开（公告）日：2012-09-20

  Condensation products of melamine and phenylphophonic acid, a process for their preparation, their compositions with polymeric materials and their use as flame retardants in polymer substrates are provided. The compositions are especially useful for the manufacture of flame retardant compounds based on polyfunctional epoxides or polycondensates, such as polyesters, polyamides and polycarbonates.

  本发明提供了三聚氰胺和苯基膦酸的缩合产物，它们的制备方法，以及它们与聚合材料的组合物和它们作为聚合物基底中阻燃剂的使用。这些组合物特别适用于基于多官能羟基化合物或多缩聚物，如聚酯、聚酰胺和聚碳酸酯的阻燃化合物的制造。
• Polymer conjugates with decreased antigenicity, methods of preparation and uses thereof
  申请人：Mountain View Pharmaceuticals, Inc.

  公开号：US20040062746A1

  公开（公告）日：2004-04-01

  Methods are provided for the preparation of conjugates of a variety of bioactive components, especially proteins, with water-soluble polymers (e.g., poly(ethylene glycol) and derivatives thereof), which conjugates have reduced antigenicity and immunogenicity compared to similar conjugates prepared using poly(ethylene glycol) containing a methoxyl or another alkoxyl group. The invention also provides conjugates prepared by such methods, compositions comprising such conjugates, kits containing such conjugates or compositions and methods of use of the conjugates and compositions in diagnostic and therapeutic protocols.

  提供了一种制备各种生物活性成分（尤其是蛋白质）与水溶性聚合物（例如聚乙二醇及其衍生物）结合物的方法，这些结合物与使用含有甲氧基或其他烷氧基的聚乙二醇制备的类似结合物相比，具有较低的抗原性和免疫原性。本发明还提供了通过这种方法制备的结合物，包含这种结合物的组合物，包含这种结合物或组合物的工具箱以及在诊断和治疗方案中使用这种结合物和组合物的方法。
• Triazine compounds, polymers comprising triazine structural units, and method
  申请人：General Electric Company

  公开号：US20030078347A1

  公开（公告）日：2003-04-24

  In various embodiments the present invention comprises 2,4,6-trisubstituted-1,3,5-triazine capping agents comprising one, two, or three leaving groups as substituents with any remaining substituents being essentially inert to reaction with a nucleophilic group on a polymer or monomer, or reactive with a nucleophilic group on a polymer or monomer at a slower rate than any leaving group. The invention also comprises polymers or monomers with nucleophilic groups capped with a triazine moiety. Still other embodiments of the invention comprise processes for capping nucleophilic groups in a polymer or monomer which comprises combining and reacting the polymer or monomer with a triazine-comprising capping agent.

  在各种实施例中，本发明包括具有一个、两个或三个离去基团作为取代基的2,4,6-三取代-1,3,5-三嗪封顶剂，其余取代基本质上对与聚合物或单体上的亲核基团反应是惰性的，或者与聚合物或单体上的亲核基团反应的速率比任何离去基团慢。本发明还包括具有三嗪基团封顶的含有亲核基团的聚合物或单体。本发明的其他实施例还包括封顶聚合物或单体中的亲核基团的过程，其中包括将聚合物或单体与含三嗪的封顶剂结合并反应。