diallylaminodichlorophosphine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diallylaminodichlorophosphine
• 英文别名: diallylamidodichlorophosphite；N,N-diallylamidodichlorophosphite；N-dichlorophosphanyl-N-prop-2-enylprop-2-en-1-amine
• 化学式: C₆H₁₀Cl₂NP
• mdl: MFCD00045683
• 分子量: 198.032
• InChiKey: OLKAPRUJFFXUCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diallylaminodichlorophosphine 在 sodium fluoride 作用下， 生成 diallyl-phosphoramidous acid difluoride
  参考文献：
  名称：

  Reddy,G.S.; Schmutzler,R., Zeitschrift fur Naturforschung. Teil B: Chemie, Biochemie, Biophysik, Biologie, 1970, vol. 25b, # 11, p. 1199 - 1214

  摘要：

  DOI：
• 作为产物：
  描述：

  二烯丙基胺 在 三乙胺 、 三氯化磷 作用下， 以 二氯甲烷 为溶剂， 生成 diallylaminodichlorophosphine
  参考文献：
  名称：

  Synthesis of Amido- and Diamidophosphites with Polyfluoroalkyl Substituents

  摘要：

  Bis(polyfluoroalkyl) chlorophosphites and polyfluoroalkyl dichlorophosphites react easily with secondary amines (from -40 to -22 degrees C, 1-3 h, CH2Cl2) in the presence or absence of triethylamine to form the corresponding bis(polyfluoroalkyl) diorganylamidophosphites or bis(diorganylamido) polyfluoroalkyl phosphites in the yield of up to 74%. Bis(polyfluoroalkyl) diorganylamidophosphites were also synthesized from diorganylamidodichlorophosphites and polyfluoroalkanols (-25 to -22 degrees C, 2 h, Et3N-CH2Cl2) with a yield of 56-60%.

  DOI：

  10.1134/s1070363220020103

文献信息

• Farkens, Michael; Jones, Peter G.; Fischer, Axel, Phosphorus, Sulfur and Silicon and the Related Elements, 1992, vol. 73, # 1-4, p. 195 - 218
  作者：Farkens, Michael、Jones, Peter G.、Fischer, Axel、Schmutzler, Reinhard

  DOI：——

  日期：——
• Synthesis of Amido- and Diamidophosphites with Polyfluoroalkyl Substituents
  作者：S. F. Malysheva、N. K. Gusarova、N. A. Belogorlova、A. M. Nalibayeva、S. V. Yasko、N. A. Chernysheva、S. I. Verkhoturova、G. K. Bishimbayeva、B. A. Trofimov

  DOI：10.1134/s1070363220020103

  日期：2020.2

  Bis(polyfluoroalkyl) chlorophosphites and polyfluoroalkyl dichlorophosphites react easily with secondary amines (from -40 to -22 degrees C, 1-3 h, CH2Cl2) in the presence or absence of triethylamine to form the corresponding bis(polyfluoroalkyl) diorganylamidophosphites or bis(diorganylamido) polyfluoroalkyl phosphites in the yield of up to 74%. Bis(polyfluoroalkyl) diorganylamidophosphites were also synthesized from diorganylamidodichlorophosphites and polyfluoroalkanols (-25 to -22 degrees C, 2 h, Et3N-CH2Cl2) with a yield of 56-60%.
• Reddy,G.S.; Schmutzler,R., Zeitschrift fur Naturforschung. Teil B: Chemie, Biochemie, Biophysik, Biologie, 1970, vol. 25b, # 11, p. 1199 - 1214
  作者：Reddy,G.S.、Schmutzler,R.

  DOI：——

  日期：——