(E)-[3-([1,3]dioxolan-2-yl)allyl]trimethylsilane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氧戊环
• 英文名称: (E)-[3-([1,3]dioxolan-2-yl)allyl]trimethylsilane
• 英文别名: [(E)-3-(1,3-dioxolan-2-yl)prop-2-enyl]-trimethylsilane
• 化学式: C₉H₁₈O₂Si
• 分子量: 186.326
• InChiKey: STIPWEFTGTWZGB-SNAWJCMRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.25
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-[3-([1,3]dioxolan-2-yl)allyl]trimethylsilane 在 Selectfluor 作用下， 以 乙腈 为溶剂， 反应 48.0h， 生成 2-(1-fluoroallyl)[1,3]dioxolane
  参考文献：
  名称：

  Sequential Cross-Metathesis/Electrophilic Fluorodesilylation:  A Novel Entry to Functionalized Allylic Fluorides

  摘要：

  [GRAPHICS]Various allylic fluorides were prepared using a two-step process involving a cross-metathesis of allyltrimethylsilane with different olefinic partners followed by a fluorodesilylation of the corresponding functionalized allylsilanes with Selectfluor.

  DOI：

  10.1021/ol035991a
• 作为产物：
  描述：

  2-乙烯基-1,3-二氧戊环 、 烯丙基三甲基硅烷 在 RuCl2(1,3-dimesityl-imidazolidin-2-yl)(PCy3)(=CHPh) 作用下， 以 二氯甲烷 为溶剂， 反应 48.0h， 以75%的产率得到(E)-[3-([1,3]dioxolan-2-yl)allyl]trimethylsilane
  参考文献：
  名称：

  Sequential Cross-Metathesis/Electrophilic Fluorodesilylation:  A Novel Entry to Functionalized Allylic Fluorides

  摘要：

  [GRAPHICS]Various allylic fluorides were prepared using a two-step process involving a cross-metathesis of allyltrimethylsilane with different olefinic partners followed by a fluorodesilylation of the corresponding functionalized allylsilanes with Selectfluor.

  DOI：

  10.1021/ol035991a

文献信息

• Sequential Cross-Metathesis/Electrophilic Fluorodesilylation:  A Novel Entry to Functionalized Allylic Fluorides
  作者：Sébastien Thibaudeau、Véronique Gouverneur

  DOI：10.1021/ol035991a

  日期：2003.12.1

  [GRAPHICS]Various allylic fluorides were prepared using a two-step process involving a cross-metathesis of allyltrimethylsilane with different olefinic partners followed by a fluorodesilylation of the corresponding functionalized allylsilanes with Selectfluor.