(4-(dipropylamino)phenyl)(phenyl)methanone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (4-(dipropylamino)phenyl)(phenyl)methanone
• 英文别名: [4-(dipropylamino)phenyl](phenyl)methanone；N-(4-benzoylphenyl)dipropylamine；4-dipropylamino-benzophenone；4-Dipropylamino-benzophenon；[4-(Dipropylamino)phenyl]-phenylmethanone
• 化学式: C₁₉H₂₃NO
• 分子量: 281.398
• InChiKey: OHYKJLXOSAAYGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  21
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  在 氧气 、 caesium carbonate 作用下， 以 甲苯 为溶剂， 以90%的产率得到(4-(dipropylamino)phenyl)(phenyl)methanone
  参考文献：
  名称：

  通过N-磺酰基酰胺中CC双键的氧化裂解合成二芳基酮

  摘要：

  一个C-C双键的氧化裂解从光化学开发[2 + 2]的二芳基-环的Ñ -tosyl烯酰胺，芳基杂芳基Ñ -tosyl烯酰胺，和Ñ -tosyl环状烯酰胺与单线态分子氧，接着是Cs 2 CO 3介导的开环反应在空气和日光下，不使用光敏剂，可以产生对称和不对称的二芳基，杂二芳基和环状酮，收率高至优异。此外，从铜炔催化的[3 + 2]-环加成，Rh催化的烷氧基化，光氧合和开环反应中合成了对称和不对称的酮，证明了1-炔烃中C-C三键的氧化裂解。一锅。因为带有给电子基团的对称和不对称的二芳基和/或杂二芳基酮的合成不容易，所以本方法是值得注意的。

  DOI：

  10.1021/acs.joc.7b03068

文献信息

• METHOD OF PRODUCING GALLIUM PHTHALOCYANINE CRYSTAL AND METHOD OF PRODUCING ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER USING THE METHOD OF PRODUCING GALLIUM PHTHALOCYANINE CRYSTAL
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20130137032A1

  公开（公告）日：2013-05-30

  Provided is a method of producing an electrophotographic photosensitive member having improved sensitivity and capable of outputting an image having less image defects due to a ghost phenomenon not only under a normal-temperature, normal-humidity environment but also under a low-temperature, low-humidity environment as a particularly severe condition. The method of producing a gallium phthalocyanine crystal includes subjecting a gallium phthalocyanine and a specific amine compound, which are added to a solvent, to a milling treatment to perform crystal transformation of the gallium phthalocyanine. In addition, the gallium phthalocyanine crystal is used in the photosensitive layer of the electrophotographic photosensitive member.

  提供了一种制备电子照相成像材料的方法，该方法具有改善灵敏度和能够在正常温度、正常湿度环境和低温、低湿度环境下输出具有较少图像缺陷的图像的能力，特别是在低温、低湿度环境下，该方法包括将镓酞菁和特定胺化合物添加到溶剂中，并对其进行磨研处理以进行镓酞菁的晶体转化。此外，将镓酞菁晶体用于电子照相成像材料的感光层中。
• Some Ketonimine Dyes and Related Compounds
  作者：J. David Reid、D. F. J. Lynch

  DOI：10.1021/ja01299a036

  日期：1936.8
• An Improved Method for the Palladium-Catalyzed Amination of Aryl Iodides
  作者：Mayssam H. Ali、Stephen L. Buchwald

  DOI：10.1021/jo0008486

  日期：2001.4.1

  Aryl iodides are coupled with amines to give the corresponding arylamines in high yield in the presence of palladium, a suitable ligand, and NaOt-Bu. Functionalized aryl iodides give good yields of the corresponding arylamines when Cs2CO3 is substituted as the base.
• Study of a New Rate Increasing “Base Effect” in the Palladium-Catalyzed Amination of Aryl Iodides
  作者：Caroline Meyers、Bert U. W. Maes、Kristof T. J. Loones、Gunther Bal、Guy L. F. Lemière、Roger A. Dommisse

  DOI：10.1021/jo049774e

  日期：2004.9.1

  Evidence for an interphase deprotonation of Pd(II)-amine complexes with weak carbonate base has been gained for the first time. When a rate-limiting deprotonation step is involved in the catalytic cycle, controlling the structure (shape and size of the particles) and/or molar excess of the carbonate base used can significantly increase the reaction rate of Buchwald-Hartwig aminations. By taking such a "base effect" into account a general protocol for the intermolecular amination of aryl iodides with all types of amines has been developed based on a standard Pd-BINAP catalyst, using cesium carbonate as the base.
• MITTEL ZUM FÄRBEN VON KERATINHALTIGEN FASERN
  申请人：Henkel Kommanditgesellschaft auf Aktien

  公开号：EP1139990B1

  公开（公告）日：2004-05-06