4-((4-chlorophenyl)thio)-2-methylaniline

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 4-((4-chlorophenyl)thio)-2-methylaniline
• 英文别名: 4-(4-chlorophenylthio)-2-methylaniline；4-(4-Chlorophenyl)sulfanyl-2-methylaniline
• 化学式: C₁₃H₁₂ClNS
• mdl: MFCD12169263
• 分子量: 249.764
• InChiKey: ZXTTWTYTCXCSCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.076
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-((4-chlorophenyl)thio)-2-methylaniline 在 双氧水 、 三乙胺 作用下， 生成 4-(4-Chlorphenylsulfonyl)-2-methyl-trifluormethansulfonanilid
  参考文献：
  名称：

  DE2118190

  摘要：

  公开号：
• 作为产物：
  描述：

  4-氯苯硫酚 、 邻甲苯胺 在 5-ethyl-1,3,7,8-tetramethylalloxazinium triflate 、 碘 、 氧气 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以94%的产率得到4-((4-chlorophenyl)thio)-2-methylaniline
  参考文献：
  名称：

  黄素/ I 2催化苯胺的好氧氧化C H亚磺酰基化

  摘要：

  首次提出在温和的反应条件下，黄素/ I 2催化苯胺与硫醇的好氧氧化C H亚磺酰化反应。这种无金属的反应为制备具有出色官能团相容性的各种芳基硫化物提供了一条原子经济途径。此外，它消耗分子氧作为唯一的终端氧化剂，并产生环保的H 2 O作为唯一的副产物。

  DOI：

  10.1016/j.tetlet.2020.152141

文献信息

• Method for preparing poly(carbonate-etherimide) compound
  申请人：PTT Global Chemical Public Company Limited

  公开号：US10759904B2

  公开（公告）日：2020-09-01

  The present invention relates to a method for preparing poly(carbonate-etherimide) compound comprising polycarbonate segment as shown in the structure (A) and polyetherimide segment as shown in the structure (B). Said method does not contain a highly toxic phosgene in its operation, can be performed easily, and can be operated at not high temperature. wherein R1 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; R2 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; m is an integer from 1 to 15; and n is an integer from 1 to 10.

  本发明涉及一种制备聚(碳酸酯-乙醚酰亚胺)化合物的方法，该化合物由结构(A)所示的聚碳酸酯段和结构(B)所示的聚醚酰亚胺段组成。本发明涉及一种制备聚碳酸酯-乙烯酰亚胺化合物的方法，该化合物包括结构（A）所示的聚碳酸酯段和结构（B）所示的聚醚酰亚胺段，该方法在操作过程中不含有剧毒的光气，操作简便，可在不高的温度下进行。
• Metal-Free Iodine-Catalyzed Direct Arylthiation of Substituted Anilines with Thiols
  作者：Daoshan Yang、Kelu Yan、Wei Wei、Jing Zhao、Mengqi Zhang、Xuguang Sheng、Guoqing Li、Shenglei Lu、Hua Wang

  DOI：10.1021/acs.joc.5b00540

  日期：2015.6.19

  Iodine-catalyzed direct arylthiation of substituted anilines for the synthesis of various diaryl sulfides has been developed under metal- and solvent-free conditions. The present method uses readily available thiols as the arylthiation reagents, and environmentally friendly and inexpensive I-2 as the catalyst. Importantly, no base or ligand was necessary. Such a simple, efficient, and economical transformation provides an attractive approach to various diaryl sulfides in good to excellent yields.
• CH557804
  申请人：——

  公开号：——

  公开（公告）日：——
• A METHOD FOR PREPARING POLY(CARBONATE-ETH ERIMIDE) COMPOUND
  申请人：PTT Global Chemical Public Company Limited

  公开号：EP3405453A2

  公开（公告）日：2018-11-28
• METHOD FOR PREPARING POLY(CARBONATE-ETHERIMIDE) COMPOUND
  申请人：PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITED

  公开号：US20190202980A1

  公开（公告）日：2019-07-04

  The present invention relates to a method for preparing poly(carbonate-etherimide) compound comprising polycarbonate segment as shown in the structure (A) and polyetherimide segment as shown in the structure (B). Said method does not contain a highly toxic phosgene in its operation, can be performed easily, and can be operated at not high temperature. wherein R 1 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; R 2 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; m is an integer from 1 to 15; and n is an integer from 1 to 10.