1,4,5,8-tetrakis((4-(tert-butyl)phenyl)amino)anthracene-9,10-dione

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4,5,8-tetrakis((4-(tert-butyl)phenyl)amino)anthracene-9,10-dione
• 英文别名: 1,4,5,8-Tetrakis(4-tert-butylanilino)anthracene-9,10-dione
• 化学式: C₅₄H₆₀N₄O₂
• 分子量: 797.096
• InChiKey: KMQHSNSOQJIIEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.8
• 重原子数：
  60
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  82.3
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  三氟化硼乙醚 、 1,4,5,8-tetrakis((4-(tert-butyl)phenyl)amino)anthracene-9,10-dione 以 邻二甲苯 为溶剂， 反应 24.0h， 以46%的产率得到C₅₄H₅₈B₂F₄N₄O₂
  参考文献：
  名称：

  超亲水二维共价有机框架作为高效太阳能蒸汽产生的宽带吸收剂

  摘要：

  一种基于 1,4,5,8-四（苯氨基）蒽-并苯-9,10-二酮 (TPAD) 的共价有机骨架 (COF)，具有超亲水性和覆盖整个 UV/Vis 至 NIR 区域的宽光吸收性，是专为太阳能蒸汽发电 (SSG) 开发，在一次太阳照射下可提供高达 1.42 kg m -2  h -1的出色水蒸发量，并具有 94% 的高能量转换效率。

  DOI：

  10.1002/anie.202201900
• 作为产物：
  描述：

  4-叔丁基苯胺 、 1,4,5,8-四氯蒽醌 在 tris-(dibenzylideneacetone)dipalladium(0) 、 caesium carbonate 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 作用下， 以 甲苯 为溶剂， 以58%的产率得到1,4,5,8-tetrakis((4-(tert-butyl)phenyl)amino)anthracene-9,10-dione
  参考文献：
  名称：

  From anthraquinone to heterocoronene as stable red chromophore

  摘要：

  通过两步反应合成了一种新的基于杂环冠烯的色素，并展示出与苝四酰亚胺类似的光稳定性。

  DOI：

  10.1039/c7tc05073a

文献信息

• Color-tunable arylaminoanthraquinone dyes through hydrogen-bond-assisted charge transfer interaction
  作者：Takashi Takeda、Yotaro Kasahara、Tomoyuki Akutagawa

  DOI：10.1039/d1ra03985g

  日期：——

  We prepared a series of arylaminoanthraquinone derivatives, including those with electron-accepting sulfone units and/or with electron-donating dialkylamino units. A color-tunable anthraquinone library that reached into the NIR region could be prepared through the precise control of frontier orbitals. Fine color-tuning was achieved through proper selection and positioning of the substituents. Effective

  我们制备了一系列芳基氨基蒽醌衍生物，包括那些具有受电子砜单元和/或具有给电子二烷基氨基单元的衍生物。通过对前沿轨道的精确控制，可以制备一个进入近红外区域的颜色可调的蒽醌库。通过正确选择和定位取代基来实现精细的颜色调整。给电子苯胺/对苯二胺和受电子蒽醌亚结构之间有效的分子内氢键辅助电荷转移相互作用引起了蒽醌的显着红移。取代基的数量和位置以及分子构象也显着有助于确定光物理性质。
• From anthraquinone to heterocoronene as stable red chromophore
  作者：Ruomeng Duan、Dieter Schollmeyer、Klaus Müllen、Chen Li

  DOI：10.1039/c7tc05073a

  日期：——

  A new heterocoronene-based chromophore was synthesized via a two-step reaction and showed similar photostability to perylenetetracaboxdiimides.

  通过两步反应合成了一种新的基于杂环冠烯的色素，并展示出与苝四酰亚胺类似的光稳定性。
• Power and lubricant additive concentrates containing at least one anthrachinone derivative as a marking substance
  申请人：Ebert Sophia

  公开号：US20070149415A1

  公开（公告）日：2007-06-28

  The invention relates to fuel and lubricant additive concentrates which comprise at least one anthraquinone derivative as a marker, to the use of such concentrates for additizing mineral oils and also for mineral oils which comprise such concentrates.
• Method For Determining The Presence Of A Chemical Compound Which Is Homogeneously Distributed In A Medium By Means Of Cross-Correlating A Measuring Spectrum With Reference Spectra
  申请人：Sens Ruediger

  公开号：US20080057589A1

  公开（公告）日：2008-03-06

  The present invention relates to a method for determining the identity or non-identity of at least one chemical compound V′ homogeneous y distributed in a medium, by a) exposing the medium containing at least one homogeneously distributed chemical compound V′ to analysis radiation with a variable wavelength λ, and b) determining the spectral measurement function I′(λ) with the aid of the absorbed, reflected, emitted and/or scattered radiation, wherein a correlation function K(δλ,c′,c) is determined according to Equation I K ⁡ ( δ ⁢ ⁢ λ , c ′ , c ) = 1 / N · ∫ - ∞ + ∞ ⁢ I ′ ⁡ ( λ , c ′ ) · I ⁡ ( λ + δ ⁢ ⁢ λ , c ) ⁢ ⁢ ⅆ λ ( I ) in which K(δλ,c′,c) denotes the correlation depending on the relative shift δλ of the functions I′(λ,c′) and I(λ,c) and the concentrations c′ and c of the at least one chemical compound V′ and V, c′ denotes the concentration of the at least one chemical compound V′ homogeneously distributed in the medium, with a known or suspected identity, c denotes the concentration of the at least one chemical compound V homogeneously distributed in the medium, with a known identity, I′(λ,c′) denotes the measurement function of the at least one homogeneously distributed chemical compound V′ in a medium containing the concentration c′, I(λ,c) denotes the comparison function of the at least one homogeneously distributed chemical compound V in a medium containing the concentration c, and N denotes a normalization factor and identity or non-identity between the compounds V and V′ is determined with the aid of the correlation function K(δλ,c′,c).
• Method for Determining the Identity, Absence and Concentration of a Chemical Compound in a Medium
  申请人：Sens Rudiger

  公开号：US20090006004A1

  公开（公告）日：2009-01-01

  A method is proposed for detecting at least one chemical compound V contained in a medium ( 312 ). The method comprises a verification step ( 420 ) which is used to determine whether V is contained in the medium ( 312 ). The method furthermore comprises an analysis step ( 424 ) in which a concentration c of the at least one chemical compound V is determined. The verification step comprises the following substeps: (a1) the medium ( 312 ) is exposed to a first analysis radiation ( 316 ) of a variable wavelength λ, the wavelength λ assuming at least two different values; (a2) at least one spectral response function A(λ) is generated with the aid of the radiation ( 324 ) absorbed and/or emitted and/or reflected and/or scattered by the medium ( 312 ) in response to the first analysis radiation ( 316 ); (a3) at least one spectral correlation function K(δλ) is formed by spectral comparison of the at least one spectral response function A(λ) with at least one pattern function R(λ+δλ), the at least one pattern function R(λ) representing a spectral measurement function of a medium ( 312 ) containing the chemical compound V and δλ being a coordinate shift; (a4) the at least one spectral correlation function K(δλ) is examined in a pattern recognition step ( 418 ), and a conclusion is made as to whether the at least one chemical compound V is contained in the medium ( 312 ); The analysis step ( 424 ) comprises the following substeps: (b1) the medium ( 312 ) is exposed to at least one second analysis radiation ( 318 ) having at least one excitation wavelength λ EX ; (b2) at least one spectral analysis function B(λ EX ,λ RES ) is generated with the aid of the radiation ( 326 ) of the response wavelength λ RES absorbed and/or emitted and/or reflected and/or scattered by the medium ( 312 ) in response to the second analysis radiation ( 318 ) of the wavelength λ EX and the concentration c is deduced therefrom.