Benzene-1,2,3,4-tetramine dihydrochloride

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzene-1,2,3,4-tetramine dihydrochloride
• 英文别名: Benzene-1,2,3,4-tetramine;hydrochloride；benzene-1,2,3,4-tetramine;hydrochloride
• 化学式: C₆H₁₀N₄*2ClH
• 分子量: 211.094
• InChiKey: ZCRNURXTOPRDPH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.44
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104
• 氢给体数：
  5
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Benzene-1,2,3,4-tetramine dihydrochloride 在 TEA 作用下， 以 苯 为溶剂， 反应 8.33h， 生成 N,N’-双(对甲苯基)脲
  参考文献：
  名称：

  Mataka, Shuntaro; Irie, Takashi; Ikezaki, Youji, Chemische Berichte, 1993, vol. 126, # 8, p. 1819 - 1822

  摘要：

  DOI：
• 作为产物：
  描述：

  4-Nitro-1,3-dihydro-benzo[1,2,5]thiadiazol-5-ylamine 在 盐酸 、 tin 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 以89%的产率得到Benzene-1,2,3,4-tetramine dihydrochloride
  参考文献：
  名称：

  Mataka, Shuntaro; Shimoiyo, Yoshiro; Hashimoto, Iwao, Liebigs Annalen, 1995, # 10, p. 1823 - 1826

  摘要：

  DOI：

文献信息

• Sulfur Nitrides in Organic Chemistry. 18. Preparation and Reduction of Benzo[1,2-<i>c</i>:3,4-<i>c</i>′:5,6-<i>c</i>″]tris- and Benzo[1,2-<i>c</i>:3,4-<i>c</i>′]bis[1,2,5]thiadiazole. A Convenient Route to Benzenehexamine and 1,2,3,4-Benzenetetramine
  作者：Shuntaro Mataka、Hisao Eguchi、Kazufumi Takahashi、Taizo Hatta、Masashi Tashiro

  DOI：10.1246/bcsj.62.3127

  日期：1989.10

  Benzotris- (3) and benzobis[1,2,5]thiadiazole (4) were prepared in a moderate yield, respectively, by the reaction of tetrasulfur tetranitride (5) with halocatechols (6) and -resorcinols (7). The reduction of 3 and 4 with Sn powder in a mixture of concentrated hydrochloric acid and dioxane gave benzenehexamine (1) and 1,2,3,4-benzenetetramine (2a) and its 5-methyl derivative (2b) in good yields, as

  通过四氮化四硫 (5) 与卤代儿茶酚 (6) 和间苯二酚 (7) 的反应，分别以中等产率制备苯并三- (3) 和苯并双 [1,2,5] 噻二唑 (4)。在浓盐酸和二恶烷的混合物中用锡粉还原 3 和 4 得到苯六胺 (1) 和 1,2,3,4-苯四胺 (2a) 及其 5-甲基衍生物 (2b)，收率良好，如分别是稳定的三盐酸盐 (1·3HCl) 和二盐酸盐 (2·2HCl)。
• [EN] LYOTROPIC LIQUID CRYSTAL SYSTEMS BASED ON BISACENAPHTHOPYRAZINOQUINOXALINE DERIVATIVES AND METHODS OF MAKING<br/>[FR] SYSTÈMES DE CRISTAUX LIQUIDES LYOTROPES BASÉS SUR DES DÉRIVÉS DE BISACÉNAPHTOPYRAZINOQUINOXALINE ET LEURS PROCÉDÉS DE FABRICATION
  申请人：NITTO DENKO CORP

  公开号：WO2009123968A1

  公开（公告）日：2009-10-08

  A family of bisacenaphthopyrazinoquinoxaline derivatives of formula (I) and (II) is disclosed. These compounds are capable of forming liquid crystal systems that can produce optically isotropic or anisotropic films with desirable optical properties : (I), (II) wherein Ri, R2, Rs, R4, R5 and R& are each independently selected from -H, -SO3M, -OH, -NH2, -Cl, -Br, -I, -NO2, -F, -CF3, -CN, -COOH, -CONH2, alkyl, aryl, alkynyl, alkenyl, alkoxyl, alkylamino, phenoxyl, and phenylamino groups; M is one or more counter ions; j is the number of counter ions associated with the compound; and n is an integer in the range of 1 to S.

  本发明揭示了一种双萘并吡嗪喹喔啉衍生物家族，其化学式为(I)和(II)。这些化合物能够形成液晶系统，可以产生具有理想光学性能的光学各向同性或各向异性薄膜：(I)，(II)，其中Ri、R2、Rs、R4、R5和R&各自独立地选择自-H、-SO3M、-OH、-NH2、-Cl、-Br、-I、-NO2、-F、-CF3、-CN、-COOH、-CONH2、烷基、芳基、炔基、烯基、烷氧基、烷基氨基、苯氧基和苯基氨基基团; M是一个或多个计数离子; j是与化合物相关的计数离子数; n是在1到S范围内的整数。
• Strongly Hydrogen-Bonded Networks Formed by Sulfate and Bisulfate Salts of Benzenetetramines
  作者：Johann O. E. Sosoe、Thierry Maris、James D. Wuest

  DOI：10.1021/acs.cgd.3c00950

  日期：2023.12.6

  such as the nature of their salts and their preferred patterns of association, which determine how they can be used to construct predictably ordered redox-active solids. To provide relevant new information, we have studied a series of sulfate and bisulfate salts of the 1,2,4,5- and 1,2,3,4-isomers, which have been found to crystallize as strongly hydrogen-bonded networks. The results of this work promise

  与其他具有多个NH 2基团的芳香族化合物一样，苯四胺很容易被氧化，并且是用作氧化还原活性有机材料组分的有吸引力的候选者。然而，对苯四胺和相关化合物的化学性质的许多方面仍然知之甚少，例如其盐的性质及其优选的缔合模式，这决定了它们如何用于构建可预测有序的氧化还原活性固体。为了提供相关的新信息，我们研究了一系列 1,2,4,5- 和 1,2,3,4- 异构体的硫酸盐和硫酸氢盐，发现它们结晶为强氢键网络。这项工作的结果有望促进苯四胺和其他复杂芳胺作为氧化还原活性有机固体成分的使用。
• Ishi-I, Tsutomu; Matsumoto, Naoki; Hirayama, Tomoyuki, Revue Roumaine de Chimie, 2006, vol. 51, # 7-8, p. 649 - 652
  作者：Ishi-I, Tsutomu、Matsumoto, Naoki、Hirayama, Tomoyuki、Yamasaki, Sumio、Yamasaki, Masataka、Tanabe, Hiroshi、Ueno, Kazunori、Mataka, Shuntaro

  DOI：——

  日期：——
• LYOTROPIC LIQUID CRYSTAL SYSTEMS BASED ON BISACENAPHTHOPYRAZINOQUINOXALINE DERIVATIVES AND METHODS OF MAKING
  申请人：Zheng Shijun

  公开号：US20110026117A1

  公开（公告）日：2011-02-03

  A family of bisacenaphthopyrazinoquinoxaline derivatives of formula (I) and (II) is disclosed. These compounds are capable of forming liquid crystal systems that can produce optically isotropic or anisotropic films with desirable optical properties: (I), (II) wherein Ri, R2, Rs, R4, R5 and R& are each independently selected from —H, —SO 3 M, —OH, —NH 2 , —Cl, —Br, —I, —NO 2 , —F, —CF 3 , —CN, —COOH, —CONH 2 , alkyl, aryl, alkynyl, alkenyl, alkoxyl, alkylamino, phenoxyl, and phenylamino groups; M is one or more counter ions; j is the number of counter ions associated with the compound; and n is an integer in the range of 1 to S.