5-bromo-6-phenyl-norborn-2-ene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-bromo-6-phenyl-norborn-2-ene
• 英文别名: 5-Brom-6-phenyl-norborn-2-en；5-Bromo-6-phenylbicyclo[2.2.1]hept-2-ene
• 化学式: C₁₃H₁₃Br
• 分子量: 249.15
• InChiKey: UQBWZXHQCHIHFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  β-溴苯乙烯 、 endo-Dicyclopentadien 生成 5-bromo-6-phenyl-norborn-2-ene
  参考文献：
  名称：

  Addition rearrangement products of thiocyanic acid and cyclopentadiene-olefinic adducts

  摘要：

  公开号：

  US02411869A1

文献信息

• RETARDATION FILM, AND LIQUID CRYSTAL DISPLAY DEVICE USING THE SAME
  申请人：Nippon Oil Corporation

  公开号：EP2060937A1

  公开（公告）日：2009-05-20

  A retardation film, formed by stretching a film comprising a norbornene-based ring-opening polymer containing a structural unit (A) represented by the following general formula (1): [in the formula (1), n represents an integer any one of 0 and 1, X1 represents any one of a group represented by a formula: -CH=CH- and a group represented by a formula: -CH2CH2-, R1, R2, R3, and R4, which may be the same or different, each represent any one of atoms and groups selected from the group consisting of: a hydrogen atom; halogen atoms; substituted or unsubstituted hydrocarbon groups, each of which may include at least one of linking group selected from the group consisting of an oxygen atom, a nitrogen atom, a sulfur atom, and a silicon atom, and which has a number of 1 to 30 carbon atoms; and polar groups, wavy lines a and b each represent a configuration of any one of an endo or an exo, and a wavy line c represents a configuration of any one of an endo or an exo.]; wherein a content percentage of a structural unit (A-1), in which the wavy line c represents an exo configuration, among the structural units (A) in a range from 35 mol% to 100 mol%.

  一种缓凝薄膜，通过拉伸由降冰片烯基开环聚合物组成的薄膜形成，降冰片烯基开环聚合物含有由以下通式 (1) 表示的结构单元 (A)： [在式(1)中，n 代表 0 和 1 中的任一整数，X1 代表由式：-CH=CH-和由式表示的基团中的任一个：-R1、R2、R3 和 R4 可以相同或不同，各自代表选自以下组成的原子和基团中的任一个：氢原子；卤素原子；取代或未取代的烃基，其中每个烃基可包括至少一个选自由氧原子、氮原子、硫原子和硅原子组成的组的连接基团，其碳原子数为 1 至 30 个；以及极性基团，波浪线 a 和 b 分别代表内向或外向中任何一种构型，波浪线 c 代表内向或外向中任何一种构型。]；其中，波浪线 c 代表外向型构型的结构单元 (A-1) 在结构单元 (A) 中的含量百分比范围为 35 摩尔%至 100 摩尔%。
• INVERSELY DISPERSIVE RETARDATION FILM, AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING SAME
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2390690A1

  公开（公告）日：2011-11-30

  A reverse dispersion retardation film, formed by stretching a film comprising a norbornene-based ring-opening copolymer containing a structural unit (A) represented by the following general formula (1): [in the formula (1), m represents an integer of any one of 0 and 1, R1 represents a hydrogen atom or the like, X1 represents a group represented by a formula: -CH2CH2- or the like, a and b each independently represent an integer of 0 to 6, Y represents a methylene group or the like, and Z represents a methylene group or the like] and a structural unit (B) represented by the following general formula (2) : [in the formula (2), n represents an integer of any one of 0 and 1, X2 represents a group represented by a formula: -CH2CH2- or the like, R2, R3, R4, and R5 each represent a hydrogen atom or the like, wavy lines d and e each represent a configuration of any one of an endo and an exo, and a wavy line f represents a configuration of any one of an endo and an exto], wherein a total amount of the structural unit (A) and an exo-form structural unit, in which the wavy line f represents the exo configuration, among the structural units (B) is not less than 20 mol% but not more than 65 mol% of all the structural units.

  一种反向分散延缓膜，由降冰片烯基开环共聚物拉伸形成，该共聚物含有由下式（1）表示的结构单元（A）： [在式 (1) 中，m 代表 0 和 1 之间的整数，R1 代表氢原子或类似物，X1 代表由式表示的基团：-CH2CH2-或类似的基团，a 和 b 各自独立地代表 0 至 6 的整数，Y 代表亚甲基或类似的基团，Z 代表亚甲基或类似的基团]和由以下通式 (2) 代表的结构单元 (B) ： [在式 (2) 中，n 代表 0 和 1 之间的整数，X2 代表由式表示的基团：-R2、R3、R4 和 R5 分别代表氢原子或类似物，波浪线 d 和 e 分别代表内向型和外向型中任何一种构型，波浪线 f 代表内向型和外向型中任何一种构型]，其中结构单元 (A) 和外向型结构单元（其中波浪线 f 代表外向型构型）在结构单元 (B) 中的总量不低于所有结构单元的 20 摩尔%，但不超过 65 摩尔%。
• US8211514B2
  申请人：——

  公开号：US8211514B2

  公开（公告）日：2012-07-03
• Addition rearrangement products of thiocyanic acid and cyclopentadiene-olefinic adducts
  申请人：RESINOUS PROD & CHEMICAL CO

  公开号：US02411869A1

  公开（公告）日：1946-12-03