tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platinum(IV)

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platinum(IV)
• 英文别名: hexyl(phenyldiazenyl)azanide;platinum(4+)
• 化学式: C₄₈H₇₂N₁₂Pt
• 分子量: 1012.26
• InChiKey: VKWUITCRVOXVCN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  18.55
• 重原子数：
  61
• 可旋转键数：
  28
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  103
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  氯化铂 、 1-phenyl-3-n-hexyltriazene 在 n-butyllithium 作用下， 以 四氢呋喃 为溶剂， 以79.5%的产率得到tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platinum(IV)
  参考文献：
  名称：

  Tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platin(IV), der erste homoleptische Arylalkyltriazenidoplatin(IV)komplex

  摘要：

  The first homoleptic tetrakis(arylalkyltriazenido) derivative of platinum, [C6H5NNN(CH2)5CH3]4Pt (3), has been prepared by reacting platinumtetrachloride with 1-phenyl-3-n-hexyltriazene and n-butyllithium in THF. The readily soluble, yellow complex, stable towards air and water, has been characterized by single cristal x-ray cristallography and Pt-195 NMR spectroscopy. Compound 3 crystallizes in the triclinic space group P1BAR (a = 1090.3(3) pm, b = 1081.1(2) pm, c = 1174.4(2) pm, alpha = 93.86(1)-degrees, beta = 108.07(2)-degrees, gamma = 99.00(2), V = 1.289(1) nm3, Z = 1 and R/R(w) = 0.038/0.035). The thermo- and photochemical decomposition of the complex was investigated by DSC- and UV-measurements.

  DOI：

  10.1016/0022-328x(93)86089-z

文献信息

• Tetrakis(η1-1-phenyl-3-n-hexyltriazenido)platin(IV), der erste homoleptische Arylalkyltriazenidoplatin(IV)komplex
  作者：Jochen Dauth、Bernward Deubzer、Johann Weis

  DOI：10.1016/0022-328x(93)86089-z

  日期：1993.10

  The first homoleptic tetrakis(arylalkyltriazenido) derivative of platinum, [C6H5NNN(CH2)5CH3]4Pt (3), has been prepared by reacting platinumtetrachloride with 1-phenyl-3-n-hexyltriazene and n-butyllithium in THF. The readily soluble, yellow complex, stable towards air and water, has been characterized by single cristal x-ray cristallography and Pt-195 NMR spectroscopy. Compound 3 crystallizes in the triclinic space group P1BAR (a = 1090.3(3) pm, b = 1081.1(2) pm, c = 1174.4(2) pm, alpha = 93.86(1)-degrees, beta = 108.07(2)-degrees, gamma = 99.00(2), V = 1.289(1) nm3, Z = 1 and R/R(w) = 0.038/0.035). The thermo- and photochemical decomposition of the complex was investigated by DSC- and UV-measurements.