2,3-H-F-hexene-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: 2,3-H-F-hexene-2
• 英文别名: 1,1,1,4,4,5,5,6,6,6-decafluorohex-2-ene；1,1,1,4,4,5,5,6,6,6-Decafluorohex-2-ene
• 化学式: C₆H₂F₁₀
• 分子量: 264.066
• InChiKey: BRHMFXVXLONVKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  boron triflate 、 2,3-H-F-hexene-2 反应 16.0h， 生成 、 [(E)-1,1,4,4,5,5,6,6,6-nonafluorohex-2-enyl] trifluoromethanesulfonate
  参考文献：
  名称：

  Reaction of Boron Triflate with Polyfluoroolefins. Synthesis of Polyfluorinated Allyl Trifluoromethanesulfonates

  摘要：

  Terminal F-olefins (F designates perfluorinated molecules) react with boron triflate (1) to form corresponding allyl triflates RfCF=CFCF2OSO2CF3 in moderate yield. The reaction of F-pentene-2 is much slower, resulting in insertion of CF3SO2O into the CF3 group of fluorolefin. Mono- and dihydrofluorolefins were found to be more reactive toward 1. Both F-cylobutene and F-cyclopentene were converted into corresponding cyclic allyl triflates by reaction with 1, but F-cyclohexene was found to be resistant to the action of boron triflate. In contrast to terminal fluorolefins, both 5H,6H-F-n-decene-5 and 1H,1H-F-isobutene react with 1 without rearrangement;, producing corresponding allyl triflates in 47 and 63% yields, respectively.

  DOI：

  10.1021/jo972166x
• 作为产物：
  描述：

  2,3-dichloro-1,1,1,4,4,5,5,6,6,6-decafluoro-2-hexene 在 氢气 、 钯 作用下， 生成 2,3-H-F-hexene-2
  参考文献：
  名称：

  WO2023/164125

  摘要：

  公开号：

文献信息

• Reaction of Boron Triflate with Polyfluoroolefins. Synthesis of Polyfluorinated Allyl Trifluoromethanesulfonates
  作者：Viacheslav A. Petrov

  DOI：10.1021/jo972166x

  日期：1998.5.1

  Terminal F-olefins (F designates perfluorinated molecules) react with boron triflate (1) to form corresponding allyl triflates RfCF=CFCF2OSO2CF3 in moderate yield. The reaction of F-pentene-2 is much slower, resulting in insertion of CF3SO2O into the CF3 group of fluorolefin. Mono- and dihydrofluorolefins were found to be more reactive toward 1. Both F-cylobutene and F-cyclopentene were converted into corresponding cyclic allyl triflates by reaction with 1, but F-cyclohexene was found to be resistant to the action of boron triflate. In contrast to terminal fluorolefins, both 5H,6H-F-n-decene-5 and 1H,1H-F-isobutene react with 1 without rearrangement;, producing corresponding allyl triflates in 47 and 63% yields, respectively.
• WO2023/164125
  申请人：——

  公开号：——

  公开（公告）日：——