2-[2-(3-Methoxyhexafluoropropoxy)hexafluoropropoxy]-tetrafluoropropionyl fluoride

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: 2-[2-(3-Methoxyhexafluoropropoxy)hexafluoropropoxy]-tetrafluoropropionyl fluoride
• 英文别名: 2-[2-(3-Methoxyhexafluoropropoxy)hexafluoropropoxy]tetrafluoropropionyl fluoride；2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3-hexafluoro-3-methoxypropoxy)propoxy]propanoyl fluoride
• 化学式: C₁₀H₃F₁₇O₄
• 分子量: 510.104
• InChiKey: LYZUUGVRIAANNT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  2-[2-(3-Methoxyhexafluoropropoxy)hexafluoropropoxy]-tetrafluoropropionyl fluoride 生成 1,1,1,2,3,3-hexafluoro-2-(1,1,2,2,3,3-hexafluoro-3-methoxypropoxy)-3-(1,2,2-trifluoroethenoxy)propane
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  3-Methoxytetrafluoropropionyl fluoride 、 六氟环氧丙烷 生成 2-[2-(3-Methoxyhexafluoropropoxy)hexafluoropropoxy]-tetrafluoropropionyl fluoride
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Process and intermediates for fluorinated vinyl ether monomer
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04675453A1

  公开（公告）日：1987-06-23

  Vinyl ether monomers of the formula ##STR1## wherein n is 0 or 1 and R is CH.sub.3 or C.sub.2 H.sub.5, precursors thereto, and copolymers with, e.g., tetrafluoroethylene, are provided. The copolymers are useful as electrical insulation and as the sheath portion of optical fibers, and can be converted to known ion exchange polymers having carboxylic groups which are useful, e.g., in the form of permionic membrane for separating the compartments of a chloralkali cell. The vinyl ether monomers can also be converted to vinyl ether monomers which contain carboxylate functional groups, which in turn can be copolymerized to useful copolymers.

  提供公式为##STR1##的乙烯醚单体，其中n为0或1，R为CH.sub.3或C.sub.2 H.sub.5，其前体，以及与四氟乙烯等共聚物。这些共聚物可用作电气绝缘材料和光纤的护套部分，并可转化为已知的具有羧基的离子交换聚合物，例如，作为氯碱电池隔室的离子交换膜。乙烯醚单体也可转化为含有羧酸盐官能团的乙烯醚单体，然后可以共聚合成有用的共聚物。
• Fluorinated vinyl ethers, copolymers thereof, and precursors thereto
  申请人：E. I. Du Pont de Nemours and Company

  公开号：US04556747A1

  公开（公告）日：1985-12-03

  Vinyl ether monomers of the formula ##STR1## wherein n is 0 or 1 and R is CH.sub.3 or C.sub.2 H.sub.5, precursors thereto, and copolymers with, e.g., tetrafluoroethylene, are provided. The copolymers are useful as electrical insulation and as the sheath portion of optical fibers, and can be converted to known ion exchange polymers having carboxylic groups which are useful, e.g., in the form of permionic membrane for separating the compartments of a chloralkali cell. The vinyl ether monomers can also be converted to vinyl ether monomers which contain carboxylate functional groups, which in turn can be copolymerized to useful copolymers.

  提供具有以下结构的乙烯醚单体##STR1##其中n为0或1，R为CH.sub.3或C.sub.2 H.sub.5，其前体以及与四氟乙烯等共聚物。这些共聚物可用作电气绝缘材料和光纤的护套部分，并可转化为已知的具有羧基的离子交换聚合物，例如，用作氯碱电池的隔膜形式。乙烯醚单体还可以转化为含有羧酸酯官能团的乙烯醚单体，进而可以共聚合成有用的共聚物。
• Fluorinated vinyl ethers, copolymers thereof, and precursors thereof
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0150618A2

  公开（公告）日：1985-08-07

  @ Vinyl ethers and acyl fluorides of the formula wherein Y is CF2=CF-or n is 0 or 1 and R is CH3 or C2H5. The vinyl ethers can be copolymerized with, e.g., tetrafluoroethylene, to provide copolymers which are useful as electrical insulation and as the sheath portion of optical fibers, and can be converted to known ion exchange polymers having carboxylic groups which are useful, e.g. in the form of permionic membrane, for separating the compartments of a chloralkali cell.

  @ 式中的乙烯基醚和酰氟 其中 Y 是 CF2=CF-or n 为 0 或 1，R 为 CH3 或 C2H5。乙烯基醚可与四氟乙烯等共聚，以提供可用作电绝缘和光纤护套部分的共聚物，并可转化为已知的具有羧基的离子交换聚合物，这种聚合物可用作氯碱电池隔室的过离子膜等。
• Process for fluorinated ion exchange polymer precursor
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0150617A2

  公开（公告）日：1985-08-07

  The -CF2OR groups in a starting copolymer comprising random-CX2CX2 units and units, where the four X's are four fluorines or three fluorines and one chlorine, n is 0 or 1 and R is CH3 or C2H5, are converted into-COZ groups, where Z is F or OR' and R' is CH3 or C2H5, by treatment with a strong acid at a temperature of at least 50 °C but below the decomposition temperature of the reactants and product. The product copolymer can be hydrolyzed to give copolymers having carboxylic groups which are useful, e.g. in the form of a permionic membrane, for separating the compartments of a chloralkali cell.

  由无规-CX2CX2 单元和-CF2OR 单元组成的起始共聚物中的-CF2OR 基团 单元（其中 4 个 X 为 4 个氟或 3 个氟和 1 个氯、n 为 0 或 1、R 为 CH3 或 C2H5）中的-CF2OR 基团通过强酸处理转化为-COZ 基团（其中 Z 为 F 或 OR'、R'为 或 ），处理温度至少为 50℃，但低于反应物和产物的分解温度。产物共聚物经水解后可得到具有羧基的共聚物，这种共聚物可用作氯碱池的隔室，例如以过离子膜的形式。
• ——
  作者：RESNICK P. R.

  DOI：——

  日期：——