perfluoro-2,3-dimethyl-3-hydrobutane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氟化物
• 英文名称: perfluoro-2,3-dimethyl-3-hydrobutane
• 英文别名: 1,1,1,2,4,4,4-Heptafluoro-2,3-bis(trifluoromethyl)butane
• 化学式: C₆HF₁₃
• 分子量: 320.053
• InChiKey: CBHBYZYQMASBOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.2
• 重原子数：
  19
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  13

反应信息

• 作为产物：
  描述：

  全氟-2,3,3,4-四甲基戊烷 以 甲苯 为溶剂， 生成 七氟丙烷 、 perfluoro-2,3-dimethyl-3-hydrobutane
  参考文献：
  名称：

  Thermal decomposition of branched-chain perfluoroalkanes

  摘要：

  The pyrolysis of some branched perfluoroalkanes has been studied. Homolytic cleavage of the most hindered carbon-carbon bond occurs, followed by coupling and rearrangement of the radicals so formed. This mechanism accounts for all the reaction products. Some kinetic and thermodynamic data are presented.

  DOI：

  10.1016/s0022-1139(00)80030-5

文献信息

• Thermal decomposition of branched-chain perfluoroalkanes
  作者：V. Tortelli、C. Tonelli、C. Corvaja

  DOI：10.1016/s0022-1139(00)80030-5

  日期：1993.2

  The pyrolysis of some branched perfluoroalkanes has been studied. Homolytic cleavage of the most hindered carbon-carbon bond occurs, followed by coupling and rearrangement of the radicals so formed. This mechanism accounts for all the reaction products. Some kinetic and thermodynamic data are presented.