(E)-(2-(pyrrolidin-1-yldiazenyl)phenyl)boronic acid

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-(2-(pyrrolidin-1-yldiazenyl)phenyl)boronic acid
• 英文别名: [2-(pyrrolidin-1-yldiazenyl)-phenyl]boronic acid
• 化学式: C₁₀H₁₄BN₃O₂
• 分子量: 219.051
• InChiKey: DYHPTAVIEHOTQV-OUKQBFOZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.46
• 重原子数：
  16.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  68.42
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  (E)-(2-(pyrrolidin-1-yldiazenyl)phenyl)boronic acid 在 双(乙腈)氯化钯(II) 三叔丁基膦 、 potassium carbonate 、 碘甲烷 作用下， 以 1,4-二氧六环 、 水 为溶剂， 反应 32.0h， 生成 2,2''-diiodo-[1,1':4',1'']terphenyl
  参考文献：
  名称：

  Dispirofluorene-indenofluorene (DSFIF):  Synthesis, Electrochemical, and Optical Properties of a Promising New Family of Luminescent Materials

  摘要：

  A series of new dispiro[fluorene-9 ',6,9 '',12-indeno[1,2b]fluorenes] (DSFIFs) that combine indenofluorene (IF) and spirobifluorene (SBF) architectural specificities have been prepared. Their anodic oxidations lead to the formation of nonsoluble transparent polymers. The photophysical and electrochemical properties of these new molecules have been evaluated for further blue OLED applications.

  DOI：

  10.1021/ol0526064
• 作为产物：
  描述：

  N,N-tetramethylene-N'-(2'-iodophenyl)triazene 在 正丁基锂 、 氯化铵 作用下， 以 乙醚 、 正己烷 、 水 为溶剂， 反应 0.25h， 生成 (E)-(2-(pyrrolidin-1-yldiazenyl)phenyl)boronic acid
  参考文献：
  名称：

  Dispirofluorene-indenofluorene (DSFIF):  Synthesis, Electrochemical, and Optical Properties of a Promising New Family of Luminescent Materials

  摘要：

  A series of new dispiro[fluorene-9 ',6,9 '',12-indeno[1,2b]fluorenes] (DSFIFs) that combine indenofluorene (IF) and spirobifluorene (SBF) architectural specificities have been prepared. Their anodic oxidations lead to the formation of nonsoluble transparent polymers. The photophysical and electrochemical properties of these new molecules have been evaluated for further blue OLED applications.

  DOI：

  10.1021/ol0526064

文献信息

• Brönsted Acid-Mediated Intramolecular Cyclization of Biaryl Triazenes for the Synthesis of Fluorenes and 9,10-Dihydro-Phenanthrenes
  作者：Lijun Xu、Weijun Yang、Lili Zhang、Maozhong Miao、Zhigen Yang、Xin Xu、Hongjun Ren

  DOI：10.1021/jo501640d

  日期：2014.10.3

  The efficient synthesis of fluorenes from biaryl triazenes is successfully developed Up to 27 examples of biaryl triazenes are converted into their corresponding fluorene derivatives in the presence of CF3COOH (4.0 equiv). Mechanism research indicates that the reaction undergoes concerted processes, and pentacoordinate carbocations may be involved in these reactions.
• Dispirofluorene-indenofluorene (DSFIF):  Synthesis, Electrochemical, and Optical Properties of a Promising New Family of Luminescent Materials
  作者：David Horhant、Jing-Jing Liang、Morgane Virboul、Cyril Poriel、Gilles Alcaraz、Joëlle Rault-Berthelot

  DOI：10.1021/ol0526064

  日期：2006.1.1

  A series of new dispiro[fluorene-9 ',6,9 '',12-indeno[1,2b]fluorenes] (DSFIFs) that combine indenofluorene (IF) and spirobifluorene (SBF) architectural specificities have been prepared. Their anodic oxidations lead to the formation of nonsoluble transparent polymers. The photophysical and electrochemical properties of these new molecules have been evaluated for further blue OLED applications.