2,2',4,4',6-pentakis(2-naphthylamino)-6'-chlorocyclotriphosphazene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,2',4,4',6-pentakis(2-naphthylamino)-6'-chlorocyclotriphosphazene
• 英文别名: 6-chloro-2-N,2-N',4-N,4-N',6-N-pentanaphthalen-2-yl-1,3,5-triaza-2lambda5,4lambda5,6lambda5-triphosphacyclohexa-1,3,5-triene-2,2,4,4,6-pentamine；6-chloro-2-N,2-N',4-N,4-N',6-N-pentanaphthalen-2-yl-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-triene-2,2,4,4,6-pentamine
• 化学式: C₅₀H₄₀ClN₈P₃
• 分子量: 881.295
• InChiKey: NQDDIGVSDWPPLS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17
• 重原子数：
  62
• 可旋转键数：
  10
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  97.2
• 氢给体数：
  5
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-萘胺 在 六氯环三磷腈 、 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 96.0h， 以7%的产率得到2,2',4-tris(2-naphthylamino)-4',6,6'-trichlorocyclotriphosphazene
  参考文献：
  名称：

  Structural and fluorescence properties of 2-naphthylamine substituted cyclotriphosphazenes

  摘要：

  The reactions of hexachlorocyclotriphosphazene, N3P3Cl6 (trimer) (1), with 2-naphthylamine (2) in tetrahydrofuran solution were studied and six new 2-naphthylamine substituted cyclotriphosphazene compounds (3-8) were obtained in this study. All of these compounds were fully characterized by elemental analyses, MALDI-TOF mass spectrometry, H-1, C-13, P-31 NMR, electronic absorption and fluorescence spectroscopies. The molecular structure of compounds; mono- (3), geminal bis (4) and tetrakis (6) 2-naphthylaminocyclotriphosphazenes were also determined by X-ray crystallography. The fluorescence properties of newly synthesized compounds (3-8) were investigated and compared in tetrahydrofuran solution. The fluorescence quantum yield (Phi(F)) values of newly synthesized 2-naphthylamine substituted cyclotriphosphazenes (3-8) were also determined and compared in this solution. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.09.001

文献信息

• Structural and fluorescence properties of 2-naphthylamine substituted cyclotriphosphazenes
  作者：Gönül Yenilmez Çiftçi、Elif Şenkuytu、Mahmut Durmuş、Fatma Yuksel、Adem Kılıç

  DOI：10.1016/j.ica.2014.09.001

  日期：2014.11

  The reactions of hexachlorocyclotriphosphazene, N3P3Cl6 (trimer) (1), with 2-naphthylamine (2) in tetrahydrofuran solution were studied and six new 2-naphthylamine substituted cyclotriphosphazene compounds (3-8) were obtained in this study. All of these compounds were fully characterized by elemental analyses, MALDI-TOF mass spectrometry, H-1, C-13, P-31 NMR, electronic absorption and fluorescence spectroscopies. The molecular structure of compounds; mono- (3), geminal bis (4) and tetrakis (6) 2-naphthylaminocyclotriphosphazenes were also determined by X-ray crystallography. The fluorescence properties of newly synthesized compounds (3-8) were investigated and compared in tetrahydrofuran solution. The fluorescence quantum yield (Phi(F)) values of newly synthesized 2-naphthylamine substituted cyclotriphosphazenes (3-8) were also determined and compared in this solution. (C) 2014 Elsevier B.V. All rights reserved.