6,7-dihydro-1,3,4-tripropyl-5H-cyclopenta[c]pyridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6,7-dihydro-1,3,4-tripropyl-5H-cyclopenta[c]pyridine
• 英文别名: 1,3,4-tripropyl-6,7-dihydro-5H-cyclopenta[c]pyridine
• 化学式: C₁₇H₂₇N
• 分子量: 245.408
• InChiKey: UQTOWVNWCVFJJI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  丁腈 、 alkaline earth salt of/the/ methylsulfuric acid 在 chromium chloride 作用下， 以84%的产率得到6,7-dihydro-1,3,4-tripropyl-5H-cyclopenta[c]pyridine
  参考文献：
  名称：

  Formation of Linear Tetramers of Diarylalkynes by the Zr/Cr System

  摘要：

  The reaction of diarylalkynes with Cp2ZrBu2 and successive treatment with CrCl3 afforded linear tetramers of diarylalkynes, (1E,3E,5E,7E)-octatetraenes. On the other hand, dialkylalkynes did not give the corresponding octatetraenes but cyclized products, such as pyridines and pyridones, by the reaction with nitriles and isocyanates.

  DOI：

  10.1021/ja052864w

文献信息

• Formation of Linear Tetramers of Diarylalkynes by the Zr/Cr System
  作者：Tamotsu Takahashi、Yuanhong Liu、Atsushi Iesato、Shinji Chaki、Kiyohiko Nakajima、Ken-ichiro Kanno

  DOI：10.1021/ja052864w

  日期：2005.8.1

  The reaction of diarylalkynes with Cp2ZrBu2 and successive treatment with CrCl3 afforded linear tetramers of diarylalkynes, (1E,3E,5E,7E)-octatetraenes. On the other hand, dialkylalkynes did not give the corresponding octatetraenes but cyclized products, such as pyridines and pyridones, by the reaction with nitriles and isocyanates.