3,7-dimethyl-10-(p-tolyl)-10H-phenothiazine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,7-dimethyl-10-(p-tolyl)-10H-phenothiazine
• 英文别名: 3,7-Dimethyl-10-(4-methylphenyl)phenothiazine
• 化学式: C₂₁H₁₉NS
• 分子量: 317.455
• InChiKey: FDNONJANDUCEFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙烷,三氯氟- 、 4-甲基环己酮 在 氧气 、 sulfur 、 二甲基亚砜 、 potassium iodide 作用下， 以 氯苯 为溶剂， 反应 14.0h， 以86%的产率得到3,7-dimethyl-10-(p-tolyl)-10H-phenothiazine
  参考文献：
  名称：

  无过渡金属条件下N取代的吩噻嗪的四组分方法

  摘要：

  由容易获得的胺，环己酮和元素硫已开发出N-取代的吩噻嗪的有效合成方法。在氧气气氛中结合使用KI / DMSO可以显着提高反应产率。

  DOI：

  10.1021/acs.orglett.5b03058

文献信息

• POLYMER COMPOUND AND LIGHT-EMITTING DEVICE USING SAME
  申请人：Fukushima Daisuke

  公开号：US20120326140A1

  公开（公告）日：2012-12-27

  It is an object of the invention to provide a polymer compound that, when used in a light-emitting device, results in excellent luminance life for the obtained light-emitting device. The invention provides a polymer compound comprising a constitutional unit represented by formula (1). [In formula (1), R 1A , R 1B , R 2A , R 2B represent an unsubstituted alkyl group, R 3 and R 4 represented an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group, an unsubstituted or substituted aryl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted heterocyclic group, an unsubstituted or substituted silyl group, a halogen atom, an alkoxycarbonyl group, a carboxyl or a cyano group, and R 5 and R 6 represent an unsubstituted or substituted alkyl group, an unsubstituted or substituted alkoxy group or an unsubstituted or substituted aryl group. The letters a, b, c and d each represent an integer of 0 to 3. When multiple R 3 , R 4 , R 5 and R 6 groups are present, they may be the same or different.]

  本发明的目的是提供一种聚合物化合物，当用于发光装置时，能够为所获得的发光装置提供优异的亮度寿命。该发明提供了一种聚合物化合物，其包含由式（1）表示的构成单元。[在式（1）中，R1A、R1B、R2A、R2B表示未取代的烷基，R3和R4表示未取代或取代的烷基，未取代或取代的烷氧基，未取代或取代的芳基，未取代或取代的芳氧基，未取代或取代的杂环基，未取代或取代的硅基，卤素原子，烷氧羰基，羧基或氰基，R5和R6表示未取代或取代的烷基，未取代或取代的烷氧基或未取代或取代的芳基。字母a、b、c和d分别表示0到3的整数。当存在多个R3、R4、R5和R6基团时，它们可以相同或不同。]
• POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：FUKUSHIMA Daisuke

  公开号：US20110187266A1

  公开（公告）日：2011-08-04

  A polymer compound that, when used for fabrication of a light emitting device, results in an excellent luminance lifetime for the obtained light emitting device. A polymer compound comprising a constitutional unit represented by formula (1). (In the formula, R 1 and R 2 each independently represent an unsubstituted alkyl group. R 3 and R 4 each independently represent a group other than an unsubstituted alkyl group. R 5 and R 6 each independently represent an unsubstituted or substituted alkyl, unsubstituted or substituted alkoxy or unsubstituted or substituted aryl group. The letters a and b each independently represent an integer of 0-4. The letters c and d each independently represent an integer of 0-3. When multiple R 3 , R 4 , R 5 and R 6 groups are present, they may be the same or different.)
• NON-AQUEOUS REDOX FLOW BATTERIES INCLUDING 3,7-PERFLUOROALKYLATED PHENOTHIAZINE DERIVATIVES
  申请人：University of Kentucky Research Foundation

  公开号：US20150372333A1

  公开（公告）日：2015-12-24

  A non-aqueous redox flow battery includes a negative electrode immersed in a first non-aqueous liquid electrolyte solution, a positive electrode immersed in a second non-aqueous liquid electrolyte solution, and a semi-permeable separator interposed between the negative and positive electrodes, wherein the second the non-aqueous liquid electrolyte solution comprises a compound of the formula:
• US9331284B2
  申请人：——

  公开号：US9331284B2

  公开（公告）日：2016-05-03
• Four-Component Approach to <i>N</i>-Substituted Phenothiazines under Transition-Metal-Free Conditions
  作者：Jinjin Chen、Guozheng Li、Yanjun Xie、Yunfeng Liao、Fuhong Xiao、Guo-Jun Deng

  DOI：10.1021/acs.orglett.5b03058

  日期：2015.12.4

  An efficient synthesis of N-substituted phenothiazines has been developed from readily available amines, cyclohexanones, and elemental sulfur. The combination use of KI/DMSO in an oxygen atmosphere significantly improved the reaction yields.

  由容易获得的胺，环己酮和元素硫已开发出N-取代的吩噻嗪的有效合成方法。在氧气气氛中结合使用KI / DMSO可以显着提高反应产率。