3,3'-tellurobispyridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 3,3'-tellurobispyridine
• 英文别名: 3-Pyridin-3-yltellanylpyridine
• 化学式: C₁₀H₈N₂Te
• 分子量: 283.787
• InChiKey: OLMUFRVMMRLDDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.13
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-碘吡啶 在 碲化氢 、 potassium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 反应 10.0h， 以84%的产率得到3,3'-tellurobispyridine
  参考文献：
  名称：

  Catalyst free one-pot synthesis of symmetrical diaryl tellurides with Te0/KOH

  摘要：

  A highly efficient new protocol for C-Te bond formation leading to symmetrical diaryl tellurides has been developed. The synthesis employed aryl iodides and elemental tellurium as starting materials in the presence of KOH. It is a one-pot reaction without using any catalyst. Utilizing this new protocol, a variety of aryl and heteroaryl iodides are reacted with elemental tellurium to afford the corresponding diaryl tellurides in good to excellent yields. Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2013.02.084

文献信息

• Dunne, Simon J.; Summers, Lindsay A.; Nagy-Felsobuki, Ellak I. von, Journal of Heterocyclic Chemistry, 1993, vol. 30, # 2, p. 409 - 412
  作者：Dunne, Simon J.、Summers, Lindsay A.、Nagy-Felsobuki, Ellak I. von

  DOI：——

  日期：——
• Catalyst free one-pot synthesis of symmetrical diaryl tellurides with Te0/KOH
  作者：Shaozhong Zhang、Kranthi Karra、Adam Koe、Jin Jin

  DOI：10.1016/j.tetlet.2013.02.084

  日期：2013.5

  A highly efficient new protocol for C-Te bond formation leading to symmetrical diaryl tellurides has been developed. The synthesis employed aryl iodides and elemental tellurium as starting materials in the presence of KOH. It is a one-pot reaction without using any catalyst. Utilizing this new protocol, a variety of aryl and heteroaryl iodides are reacted with elemental tellurium to afford the corresponding diaryl tellurides in good to excellent yields. Published by Elsevier Ltd.