2-dimethylamino-2',3',4',5',6'-pentafluorobiphenyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-dimethylamino-2',3',4',5',6'-pentafluorobiphenyl
• 英文别名: 2'-(dimethylamino)-2,3,4,5,6-pentafluorobiphenyl；N,N-dimethyl-2-(2,3,4,5,6-pentafluorophenyl)aniline
• 化学式: C₁₄H₁₀F₅N
• 分子量: 287.232
• InChiKey: YNQWTMWCXLUBTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  [1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethyl] 2,3,4,5,6-pentafluorobenzenesulfonate 在 N,N-二甲基苯胺 作用下， 反应 8.0h， 以34%的产率得到2-dimethylamino-2',3',4',5',6'-pentafluorobiphenyl
  参考文献：
  名称：

  Pentafluorophenylation of aromatics with pentafluorophenyl perfluoro- and polyfluoroalkanesulfonates. A photoinduced electron-transfer cation diradical coupling process

  摘要：

  Irradiation of pentafluorophenyl perfluoro- and polyfluoroalkanesulfonates 1 with arenes, aromatic ethers, anilines, pyrroles, indoles, and phenols results in the corresponding pentafluorophenylated aromatic compounds. An electron-transfer mechanism is proposed.

  DOI：

  10.1021/jo00061a041

文献信息

• Chen, Qing-Yun; Li, Zhan-Ting, Journal of the Chemical Society. Perkin transactions I, 1993, # 14, p. 1705 - 1710
  作者：Chen, Qing-Yun、Li, Zhan-Ting

  DOI：——

  日期：——
• Pentafluorophenylation of aromatics with pentafluorophenyl perfluoro- and polyfluoroalkanesulfonates. A photoinduced electron-transfer cation diradical coupling process
  作者：Qing Yun Chen、Zhan Ting Li

  DOI：10.1021/jo00061a041

  日期：1993.4

  Irradiation of pentafluorophenyl perfluoro- and polyfluoroalkanesulfonates 1 with arenes, aromatic ethers, anilines, pyrroles, indoles, and phenols results in the corresponding pentafluorophenylated aromatic compounds. An electron-transfer mechanism is proposed.