十八碳-9-烯-1-胺盐酸盐 | 19183-31-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 十八碳-9-烯-1-胺盐酸盐
• 英文名称: octadec-9-enylamine; hydrochloride
• 英文别名: octadec-9-enylazanium;chloride
• CAS: 19183-31-4
• 化学式: C₁₈H₃₇N*ClH
• 分子量: 303.959
• InChiKey: LPJKDVHMUUZHRY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  20
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  26
• 氢给体数：
  2
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  lead(II) oxide 、 十八碳-9-烯-1-胺盐酸盐 、 caesium carbonate 在 油酸 、 十八碳烯 作用下， 生成
  参考文献：
  名称：

  所有CsPbX3（X = Cl，Br和I）钙钛矿纳米晶体的近统一光致发光量子效率：通用合成方法

  摘要：

  在一般的合成方法中，报道了具有接近统一的量子产率的所有三种CsPbX 3（X = Cl，Br和I）钙钛矿纳米晶体。通过在优化的反应温度下将所需量的预制烷基卤化铵盐注入等摩尔量的非卤化物Pb和Cs前体中，将所需量的预制卤化烷基铵盐（用作双重源）提供卤化物离子和封端剂，即可实现这一目标。Pb对Cs比的组成敏感性，高温反应和卤化铵的注入仍然是获得高量子产率的关键参数。报告了反应过程，使用不同试剂和设置反应参数的详细信息。

  DOI：

  10.1002/anie.201900374
• 作为产物：
  描述：

  9-十八碳烯-1-胺 在 盐酸 作用下， 反应 0.5h， 生成 十八碳-9-烯-1-胺盐酸盐
  参考文献：
  名称：

  所有CsPbX3（X = Cl，Br和I）钙钛矿纳米晶体的近统一光致发光量子效率：通用合成方法

  摘要：

  在一般的合成方法中，报道了具有接近统一的量子产率的所有三种CsPbX 3（X = Cl，Br和I）钙钛矿纳米晶体。通过在优化的反应温度下将所需量的预制烷基卤化铵盐注入等摩尔量的非卤化物Pb和Cs前体中，将所需量的预制卤化烷基铵盐（用作双重源）提供卤化物离子和封端剂，即可实现这一目标。Pb对Cs比的组成敏感性，高温反应和卤化铵的注入仍然是获得高量子产率的关键参数。报告了反应过程，使用不同试剂和设置反应参数的详细信息。

  DOI：

  10.1002/anie.201900374

文献信息

• HYDRAZONYL GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20190177319A1

  公开（公告）日：2019-06-13

  An object of the present invention is to develop and provide a novel agricultural and horticultural insecticide in view of the still immense damage caused by insect pests etc. and the emergence of insect pests resistant to existing insecticides in crop production in the fields of agriculture, horticulture and the like. Provided is a hydrazonyl group-containing condensed heterocyclic compound or a salt thereof, preferably a condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents, for example, an alkyl group, R 2 represents, for example, a hydrogen atom, R 3 and R 4 each represent, for example, an alkyl group, a haloalkyl group or an acyl group, A 1 represents, for example, a nitrogen atom, A 2 represents, for example, N-Me or an oxygen atom, A 3 represents, for example, a carbon atom or a nitrogen atom, A 4 represents, for example, C—H, m represents, for example, 2, and n represents, for example, 1}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  本发明的一个目的是开发并提供一种新型农艺和园艺杀虫剂，鉴于昆虫害虫等造成的损害仍然巨大，以及在农业、园艺等领域作物生产中出现的对现有杀虫剂具有抗性的昆虫害虫。 提供了一种含有肼酰基的稠合杂环化合物或其盐，优选为通式(1)表示的稠合杂环化合物： 其中R1代表例如烷基，R2代表例如氢原子，R3和R4各自代表例如烷基、卤代烷基或酰基，A1代表例如氮原子，A2代表例如N-Me或氧原子，A3代表例如碳原子或氮原子，A4代表例如C—H，m代表例如2，n代表例如1}，或其盐；一种包含该化合物或其盐作为活性成分的农艺和园艺杀虫剂；以及使用该杀虫剂的方法。
• HETEROCYCLE-BOUND CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20200361940A1

  公开（公告）日：2020-11-19

  In crop production in the fields of agriculture, horticulture and the like, the damage caused by insect pests etc. is still immense, and insect pests resistant to existing insecticides have emerged. To solve the problems, the present invention has been made, and an object of the present invention is to develop and provide a novel agricultural and horticultural insecticide. The present invention provides a heterocycle-bound condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents an ethyl group, R 2 represents a haloalkyl group, A 1 represents a N-methyl group, A 2 and A 3 represent a nitrogen atom, n represents 1, m represents 2, and Q represents an oxadiazole}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  在农业、园艺等领域的作物生产中，由昆虫害等造成的损害仍然巨大，并且出现了对现有杀虫剂具有抗性的昆虫害。为解决这些问题，已经制定了本发明，本发明的目的是开发并提供一种新型的农业和园艺杀虫剂。 本发明提供了一种由通式（1）表示的杂环结合的缩合杂环化合物： 其中R1代表乙基基团，R2代表卤代烷基基团，A1代表N-甲基基团，A2和A3代表氮原子，n代表1，m代表2，Q代表噁二唑基}，或其盐；一种以该化合物或其盐为活性成分的农业和园艺杀虫剂；以及使用该杀虫剂的方法。
• OXIME GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND, AND METHOD FOR USING THE INSECTICIDE
  申请人：NIHON NOHYAKU CO., LTD.

  公开号：US20210371424A1

  公开（公告）日：2021-12-02

  Provided are an oxime group-containing condensed heterocyclic compound or a salt thereof, preferably a condensed heterocyclic compound represented by general formula (1): (wherein the symbols are defined in the specification); an agricultural and horticultural insecticide comprising the compound or a salt thereof as an active ingredient; and a method for using the insecticide.

  提供的是含有肟基的缩合杂环化合物或其盐，优选是由通式（1）表示的缩合杂环化合物： （其中符号在规范中定义）；包括该化合物或其盐作为活性成分的农业和园艺杀虫剂；以及使用该杀虫剂的方法。
• OXIME GROUP-CONTAINING CONDENSED HETEROCYCLIC COMPOUND OR SALT THEREOF, AGRICULTURAL AND HORTICULTURAL INSECTICIDE COMPRISING THE COMPOUND OR THE SALT, AND METHOD FOR USING THE INSECTICIDE
  申请人：Nihon Nohyaku Co., Ltd.

  公开号：US20200085054A1

  公开（公告）日：2020-03-19

  In crop production in the fields of agriculture, horticulture and the like, the damage caused by insect pests etc. is still immense, and insect pests resistant to existing insecticides have emerged. The present invention has been made in view of such circumstances, and an object of the present invention is to develop and provide a novel agricultural and horticultural insecticide. The present invention provides an oxime group-containing condensed heterocyclic compound represented by the general formula (1): wherein R 1 represents an alkoxy group, R 2 represents a haloalkyl group, R 3 represents a haloalkylthio group, A represents an oxygen atom, A 1 represents a CH group, m represents 2, and n represents 1}, or a salt thereof; an agricultural and horticultural insecticide comprising the compound or the salt as an active ingredient; and a method for using the insecticide.

  在农业、园艺等领域的作物生产中，由昆虫害等造成的损害仍然巨大，并且出现了对现有杀虫剂具有抗性的昆虫害。鉴于这种情况，本发明的目的是开发并提供一种新型的农业和园艺杀虫剂。本发明提供了一种含有肟基的缩合杂环化合物，其通式表示为（1）：其中R1代表烷氧基，R2代表卤代烷基，R3代表卤代烷硫基，A代表氧原子，A1代表CH基团，m代表2，n代表1}，或其盐；一种以该化合物或盐为活性成分的农业和园艺杀虫剂；以及使用该杀虫剂的方法。
• RING-FUSED 2-PYRIDONE DERIVATIVES AND HERBICIDES
  申请人：Takabe Fumiaki

  公开号：US20110287937A1

  公开（公告）日：2011-11-24

  Provided are 2-pyridone derivatives which have excellent herbicidal activity and exhibit high safety to useful crops and so on; salts thereof; and herbicides containing same. In more detail, 2-pyridone derivatives represented by general formula [I] or agrochemically acceptable salts thereof, and herbicides containing these compounds are provided. In general formula [I], X 1 is an oxygen atom or a sulfur atom; X 2 , X 3 , and X 4 are to each CH or N(O) m ; m is an integer of 0 or 1; R 1 is a hydrogen atom, a C 1-12 alkyl group, or the like; R 2 is a halogen atom, a cyano group, or the like; n is an integer of 0 to 4; R 3 is a hydroxyl group, a halogen atom, or the like; A 1 is C(R 11 R 12 ); A 2 is C(R 13 R 14 ) or C═O; A 3 is C(R 15 R 16 ); and R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 are each independently a hydrogen atom or a C 1-6 alkyl group.

  提供了具有优异除草活性并对有用作物等表现出高安全性的2-吡啶酮衍生物；其盐；以及含有这些化合物的除草剂。更详细地说，提供了通式[I]所表示的2-吡啶酮衍生物或其农药可接受的盐，以及含有这些化合物的除草剂。在通式[I]中，X1是氧原子或硫原子；X2、X3和X4分别为CH或N(O)m；m是0或1的整数；R1是氢原子，C1-12烷基或类似物；R2是卤素原子，氰基或类似物；n是0到4的整数；R3是羟基，卤素原子或类似物；A1是C(R11R12)；A2是C(R13R14)或C═O；A3是C(R15R16)；R11、R12、R13、R14、R15和R16分别独立地是氢原子或C1-6烷基基团。