5,6,11,12-tetrahydro-5,11-methanodibenzo[a,e][8]annulene-2,3,8,9-tetramethoxyl

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 5,6,11,12-tetrahydro-5,11-methanodibenzo[a,e][8]annulene-2,3,8,9-tetramethoxyl
• 英文别名: 4,5,12,13-Tetramethoxytetracyclo[7.7.1.02,7.010,15]heptadeca-2,4,6,10,12,14-hexaene；4,5,12,13-tetramethoxytetracyclo[7.7.1.02,7.010,15]heptadeca-2,4,6,10,12,14-hexaene
• 化学式: C₂₁H₂₄O₄
• 分子量: 340.419
• InChiKey: JHJYOSQFMJXZHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5,6,11,12-tetrahydro-5,11-methanodibenzo[a,e][8]annulene-2,3,8,9-tetramethoxyl 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 以86%的产率得到5,6,11,12-tetrahydro-5,11-methanodibenzo[a,e][8]annulene-2,3,8,9-tetrayl tetraol
  参考文献：
  名称：

  固有特性的微孔聚合物，源于Tröger碱的碳环类似物

  摘要：

  Tröger的碱（TB）由于具有刚性的双环V形结构，经常被用作合成本征微孔聚合物（PIM）的基础材料。在这项研究中，PIM结构中的TB成分被2,3：6,7-二苯并双环[3.3.1]壬烷（一种纯粹的TB碳环类似物）取代。如使用氮吸附所确定的，这种修饰仅导致微孔量略微减少。与以前报道的PIM的进一步比较表明，该建筑单元（因此TB）在生成固有的微孔性方面比螺双双辛烷（PIM合成中常用的结构单元）的效率明显降低。似乎2,3：6,7-二苯并双环[3.3.1]壬烷和TB单元的V形允许聚合物链之间更紧密的接触，从而提高包装效率。

  DOI：

  10.1016/j.polymer.2017.03.037
• 作为产物：
  描述：

  3,4-二甲氧基苯乙腈 在 hydrazine hydrate 、 sodium methylate 、 乙二醇 、 potassium hydroxide 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 反应 18.0h， 生成 5,6,11,12-tetrahydro-5,11-methanodibenzo[a,e][8]annulene-2,3,8,9-tetramethoxyl
  参考文献：
  名称：

  固有特性的微孔聚合物，源于Tröger碱的碳环类似物

  摘要：

  Tröger的碱（TB）由于具有刚性的双环V形结构，经常被用作合成本征微孔聚合物（PIM）的基础材料。在这项研究中，PIM结构中的TB成分被2,3：6,7-二苯并双环[3.3.1]壬烷（一种纯粹的TB碳环类似物）取代。如使用氮吸附所确定的，这种修饰仅导致微孔量略微减少。与以前报道的PIM的进一步比较表明，该建筑单元（因此TB）在生成固有的微孔性方面比螺双双辛烷（PIM合成中常用的结构单元）的效率明显降低。似乎2,3：6,7-二苯并双环[3.3.1]壬烷和TB单元的V形允许聚合物链之间更紧密的接触，从而提高包装效率。

  DOI：

  10.1016/j.polymer.2017.03.037

文献信息

• PSEUDO TRÖGER'S BASE-DERIVED DIANHYDRIDES AND POLYIMIDES DERIVED FROM PSEUDO TRÖGER'S BASE-DERIVED DIANHYDRIDES
  申请人：King Abdullah University of Science and Technology

  公开号：US20200199141A1

  公开（公告）日：2020-06-25

  Embodiments of the present disclosure describe pseudo Tröger's base-derived dianhydrides. Embodiments of the present disclosure also describe polyimides based on pseudo Tröger's base-derived dianhydrides, including intrinsically microporous polyimides. Embodiments of the present disclosure further describe a method of separating chemical species in a fluid composition comprising contacting a polymeric membrane with a fluid composition including at least two chemical species, wherein the polymeric membrane includes one or more of an intrinsically microporous polyimide, and capturing at least one of the chemical species from the fluid composition.

  本公开的实施例描述了基于伪特罗格氏碱衍生二酐的聚合物。本公开的实施例还描述了基于伪特罗格氏碱衍生二酐的聚酰亚胺，包括固有微孔聚酰亚胺。本公开的实施例进一步描述了一种在包括至少两种化学物种的流体组分中分离化学物种的方法，其中该聚合物膜与包括至少两种化学物种的流体组分接触，其中该聚合物膜包括一种或多种固有微孔聚酰亚胺，并从流体组分中捕获至少一种化学物种。
• Design and Synthesis of Polyimides Based on Carbocyclic Pseudo-Tröger’s Base-Derived Dianhydrides for Membrane Gas Separation Applications
  作者：Xiaohua Ma、Mahmoud A. Abdulhamid、Ingo Pinnau

  DOI：10.1021/acs.macromol.7b01054

  日期：2017.8.8

  Two novel carbocyclic pseudo-Troger's base-derived dianhydrides, 5,6,11,12-tetrahydro-5,11-methanodibenzo [a,e][8]annulene-2,3,8,9-tetracarboxylic anhydride (CTB1) and its dione-substituted analogue 6,12-dioxo-5,6,11,12-tetrahydro-5,11-methanodibenzo [a,e][8]annulene-2,3,8,9-tetracarboxylic dianhydride (CTB2), were made and used for the synthesis of soluble polyimides of intrinsic microporosity with 3,3'-dimethylnaphthidine (DMN). The polyimides CTB1-DMN and CTB2-DMN exhibited excellent thermal stability of similar to 500 degrees C and high BET surface areas of 580 and 469 m(2) g(-1), respectively. A freshly made dione-substituted CTB2-DMN membrane demonstrated promising gas separation performance with O-2 permeability of 206 barrer and, O-2/N-2 selectivity of 5.2. A higher O-2 permeability of 320 barter and lower O-2/N-2 selectivity of 4.2 were observed for a fresh CTB1-DMN film due to its higher surface area and less tightly packed structure as indicated by weaker charge-transfer complex interactions. Physical aging over 60 days resulted in reduction in gas permeability and moderately enhanced selectivity. CTB2-DMN exhibited notable performance with gas permeation data located between the 2008 and 2015 permeability/selectivity upper bounds for O-2/N-2 and H-2/CH4.
• [EN] PSEUDO TRÖGER'S BASE-DERIVED DIANHYDRIDES AND POLYIMIDES DERIVED FROM PSEUDO TRÖGER'S BASE-DERIVED DIANHYDRIDES<br/>[FR] DIANHYDRIDES DÉRIVÉS DE LA BASE DE PSEUDOTRÖGER ET POLYIMIDES DÉRIVÉS DE DIANHYDRIDES DÉRIVÉS DE LA BASE DE PSEUDOTRÖGER
  申请人：UNIV KING ABDULLAH SCI & TECH

  公开号：WO2019012347A1

  公开（公告）日：2019-01-17

  Embodiments of the present disclosure describe pseudo Tröger's base- derived dianhydrides. Embodiments of the present disclosure also describe polyimides based on pseudo Tröger's base-derived dianhydrides, including intrinsically microporous polyimides. Embodiments of the present disclosure further describe a method of separating chemical species in a fluid composition comprising contacting a polymeric membrane with a fluid composition including at least two chemical species, wherein the polymeric membrane includes one or more of an intrinsically microporous polyimide, and capturing at least one of the chemical species from the fluid composition.