2,2′-(1,3-phenylene)bis(5-methylisoindoline-1,3-dione)

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 2,2′-(1,3-phenylene)bis(5-methylisoindoline-1,3-dione)
• 英文别名: 5-Methyl-2-[3-(5-methyl-1,3-dioxoisoindol-2-yl)phenyl]isoindole-1,3-dione
• 化学式: C₂₄H₁₆N₂O₄
• 分子量: 396.402
• InChiKey: BZKDCAPNDXMWAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  30
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  74.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-甲基-2-丁烯醛 、 N,N'-间苯撑双马来酰亚胺 在 苯甲酸 、 L-脯氨酸 作用下， 以 甲苯 为溶剂， 反应 15.0h， 以83%的产率得到2,2′-(1,3-phenylene)bis(5-methylisoindoline-1,3-dione)
  参考文献：
  名称：

  利用两个亲二烯体的Diels-Alder反应有机催化合成高官能度邻苯二甲酰亚胺

  摘要：

  通过α，β-不饱和醛的两个亲二烯体和马来酰亚胺的1-脯氨酸催化的反应，开发了一种有效且简便的合成生物学和药学上重要的邻苯二甲酰亚胺的方案。该反应涉及有效的苯环化，该苯环化是通过从烯醛和N-取代的马来酰亚胺就地生成的氮杂二烯中间体的正式[4 + 2]环加成反应进行的。该协议提供了多种功能化的邻苯二甲酰亚胺衍生物，包括有效的COX-2酶抑制剂。

  DOI：

  10.1021/acs.joc.0c01991

文献信息

• METHODS OF PREPARING POLYMER-ORGANOCLAY COMPOSITES AND ARTICLES DERIVED THEREFROM
  申请人：Chan Pong Kwok

  公开号：US20080004391A1

  公开（公告）日：2008-01-03

  A method for preparing a polymer-organoclay composite composition comprises combining a solvent and an unexfoliated organoclay to provide a first mixture, wherein the unexfoliated organoclay comprises alternating inorganic silicate layers and organic layers, and has an initial spacing between the silicate layers; exposing the first mixture to an energized condition of a sufficient intensity and duration to increase the initial spacing of the inorganic silicate layers, to provide a second mixture; contacting the second mixture with a polymer composition so that the polymer composition fills at least one region located between at least one pair of silicate layers, wherein the polymer composition is at least partially soluble in the solvent; and removing at least a portion of the solvent from the second mixture, wherein the inorganic silicate layers remain separated by the polymer after removal of the solvent.

  一种制备聚合物-有机粘土复合物的方法，包括将溶剂和未膨胀的有机粘土组合以提供第一混合物，其中未膨胀的有机粘土包括交替的无机硅酸盐层和有机层，并具有初始硅酸盐层之间的间距；将第一混合物暴露于足够强度和持续时间的充能条件下，以增加无机硅酸盐层的初始间距，以提供第二混合物；将第二混合物与聚合物组合物接触，以使聚合物组合物填充至少位于至少一对硅酸盐层之间的至少一个区域，其中聚合物组合物在溶剂中至少部分溶解；从第二混合物中除去至少一部分溶剂，其中在除去溶剂后，无机硅酸盐层仍然被聚合物分开。
• Plastic films
  申请人：Shi Guangda

  公开号：US20070077410A1

  公开（公告）日：2007-04-05

  In one embodiment, a plastic layer can comprise a substrate layer and a contrast layer, wherein the film has a light transmission of less than or equal to about 10% as measured on a 0.050 inch thick film sample. The contrast layer can comprise a virgin plastic, a white pigment, and a non-white colorant. The contrast layer can have a whiteness index of greater than or equal to about 50, a contrast layer yellowness index of less than 10, and a brightness of greater than or equal to 50, as measured on a 3 mm thick color chip under D65 illuminant and 2 degree observer.
• Plastic compositions and products produced therefrom
  申请人：Cao Feng

  公开号：US20070078216A1

  公开（公告）日：2007-04-05

  In one embodiment, a plastic composition can comprise: a plastic, a white pigment, and a non-white colorant. The composition can have a whiteness index of greater than or equal to about 50, and a composition yellowness index of less than 10, as measured on a 3 mm thick color chip under D65 illuminant and 2 degree observer. Also disclosed are articles made from the plastic composition.
• Polyarlyl ether ketone polymer blends
  申请人：Aneja Ashish

  公开号：US20070066765A1

  公开（公告）日：2007-03-22

  Phase separated blends of polyaryl ether ketones, polyaryl ketones, polyether ketones, polyether ether ketones and mixtures thereof with at least one polysulfone etherimide, wherein the polysulfone etherimide has greater than or equal to 50 mole % of the polymer linkages contain at least one aryl sulfone group are described. Such blends have improved load bearing capability at high temperature. In another aspect a high crystallization temperature, especially at fast cooling rates, is achieved.
• POLY ARYL ETHER KETONE POLYMER BLENDS
  申请人：Aneja Ashish

  公开号：US20070197739A1

  公开（公告）日：2007-08-23

  Filled phase-separated blends of polyaryl ether ketones, polyaryl ketones, polyether ketones, polyether ether ketones and mixtures thereof with at least one polysulfone etherimide, wherein the polysulfone etherimide has greater than or equal to 50 mole % of the polymer linkages contain at least one aryl sulfone group are described. Such filled blends have improved load-bearing capability at high temperature. In another aspect the filled blends have a higher crystallization temperature, especially at fast cooling rates.