1,4-diketo-2,5-diethyl-3,6-bis(1-naphthyl)pyrrolo[3,4-c]pyrrole

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,4-diketo-2,5-diethyl-3,6-bis(1-naphthyl)pyrrolo[3,4-c]pyrrole
• 英文别名: 2,5-diethyl-1,4-dinaphthalen-1-ylpyrrolo[3,4-c]pyrrole-3,6-dione
• 化学式: C₃₀H₂₄N₂O₂
• 分子量: 444.533
• InChiKey: HVXMOPHMSZBLBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  34
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  丁二酸二异丙酯 、 碘甲烷 、 氰基萘 在 溶剂黄146 作用下， 以 甲醇 、 2-甲基-2-丁醇 、 二氯甲烷 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 1,4-diketo-2,5-diethyl-3,6-bis(1-naphthyl)pyrrolo[3,4-c]pyrrole
  参考文献：
  名称：

  Pyrromethene metal complex and light emitting device composition and light emitting devices using the same

  摘要：

  一种吡咯甲烷金属配合物被用作荧光染料，形成发光装置。发光装置具有一种物质，在阳极和阴极之间引起发光。通过施加电能，该装置产生具有580到720纳米的发射峰波长的发射。该装置包含以下至少一种：二酮吡咯[3,4-c]吡咯衍生物和具有580到720纳米荧光峰波长的有机荧光材料；以及含有吡咯甲烷金属配合物的发光装置组成。

  公开号：

  US20030082406A1

文献信息

• Luminescent element material and luminescent element comprising the same
  申请人：——

  公开号：US20030168970A1

  公开（公告）日：2003-09-11

  The light emitting device of the present invention relates to a light emitting device which is characterized in that it is a device with an emissive substance present between an anode and cathode, and which emits light by means of electrical energy, and said device has a least one type of compound denoted by (a) to (d) below. (a) A compound having a plurality of 1,7-phenanthroline skeletal structures (b) A benzoquinoline derivative (c) A spiro compound represented by general formula (1) 1 A 1 and A 2 are each selected from single bonds, substituted or unsubstituted alkyl chains, ether chains, thioether chains, ketone chains and substituted or unsubstituted amino chains. However, A 1 ≠A 2 . Z represents carbon or silicon. R 1 to R 16 are each selected from hydrogen, alkyl group, cycloalkyl group, aralkyl group, alkenyl group, cycloalkenyl group, alkynyl group, hydroxyl group, mercapto group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heterocyclic group, halogen, haloalkane, haloalkene, haloalkyne, cyano group, aldehyde group, carbonyl group, carboxyl group, ester group, carbamoyl group, amino group, nitro group, silyl group, siloxanyl group and a cyclic structure formed with an adjacent substituent. (d) A tetraphenylmethane derivative represented by general formula (2) 2 R 17 to R 36 are each selected from hydrogen, alkyl group, cycloalkyl group, aralkyl group, alkenyl group, cycloalkenyl group, alkynyl group, hydroxyl group, mercapto group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heterocyclic group, halogen, haloalkane, haloalkene, haloalkyne, cyano group, aldehyde group, carbonyl group, carboxyl group, ester group, carbamoyl group, amino group, nitro group, silyl group, siloxanyl group and a cyclic structure formed with an adjacent substituent. However, at least one of R 17 to R 36 is selected from substituents represented by general formula (3). —X—Ar   (3) X is a single bond or is selected from the following, and Ar denotes a condensed aromatic ring or heteroaromatic ring. In the case where X is phosphorus oxide, then Ar represents an aromatic hydrocarbon or heteroaromatic ring. 3 n is an natural number.

  本发明的发光装置涉及一种发光装置，其特征在于它是一种在阳极和阴极之间存在发射物质的装置，并通过电能发出光，该装置具有以下至少一种化合物：(a) 具有多个1,7-菲咯啉骨架结构的化合物(b) 苯醌衍生物(c) 由通式(1)表示的螺合物1A1和A2分别选自单键，取代或未取代的烷基链，醚链，硫醚链，酮链和取代或未取代的氨基链。但是，A1≠A2。Z代表碳或硅。R1到R16分别选自氢，烷基，环烷基，芳基烷基，烯基，环烯基，炔基，羟基，巯基，烷氧基，烷硫基，芳基醚基，芳基硫醚基，芳基，杂环基，卤素，卤代烷基，卤代烯基，卤代炔基，氰基，醛基，羰基，羧基，酯基，氨基，硝基，硅烷基，硅氧烷基和与相邻取代基形成的环状结构。(d) 由通式(2)表示的四苯甲烷衍生物2R17到R36分别选自氢，烷基，环烷基，芳基烷基，烯基，环烯基，炔基，羟基，巯基，烷氧基，烷硫基，芳基醚基，芳基硫醚基，芳基，杂环基，卤素，卤代烷基，卤代烯基，卤代炔基，氰基，醛基，羰基，羧基，酯基，氨基，硝基，硅烷基，硅氧烷基和与相邻取代基形成的环状结构。但是，R17到R36中至少有一个选自通式(3)表示的取代基。-X-Ar (3)X是单键或选自以下内容，并且Ar表示紧密芳香环或杂芳香环。在X为氧化磷的情况下，Ar代表芳香烃或杂芳香环。3n是自然数。
• LUMINESCENT ELEMENT MATERIAL AND LUMINESCENT ELEMENT COMPRISING THE SAME
  申请人：Toray Industries, Inc.

  公开号：EP1341403A1

  公开（公告）日：2003-09-03

  The light emitting device of the present invention relates to a light emitting device which is characterized in that it is a device with an emissive substance present between an anode and cathode, and which emits light by means of electrical energy, and said device has a least one type of compound denoted by (a) to (d) below. (a) A compound having a plurality of 1,7-phenanthroline skeletal structures (b) A benzoquinoline derivative (c) A spiro compound represented by general formula (1) A1 and A2 are each selected from single bonds, substituted or unsubstituted alkyl chains, ether chains, thioether chains, ketone chains and substituted or unsubstituted amino chains. However, A1 ≠ A2. Z represents carbon or silicon. R1 to R16 are each selected from hydrogen, alkyl group, cycloalkyl group, aralkyl group, alkenyl group, cycloalkenyl group, alkynyl group, hydroxyl group, mercapto group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heterocyclic group, halogen, haloalkane, haloalkene, haloalkyne, cyano group, aldehyde group, carbonyl group, carboxyl group, ester group, carbamoyl group, amino group, nitro group, silyl group, siloxanyl group and a cyclic structure formed with an adjacent substituent. (d) A tetraphenylmethane derivative represented by general formula (2) R17 to R36 are each selected from hydrogen, alkyl group, cycloalkyl group, aralkyl group, alkenyl group, cycloalkenyl group, alkynyl group, hydroxyl group, mercapto group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heterocyclic group, halogen, haloalkane, haloalkene, haloalkyne, cyano group, aldehyde group, carbonyl group, carboxyl group, ester group, carbamoyl group, amino group, nitro group, silyl group, siloxanyl group and a cyclic structure formed with an adjacent substituent. However, at least one of R17 to R36 is selected from substituents represented by general formula (3).         ―X―Ar     (3) X is a single bond or is selected from the following, and Ar denotes a condensed aromatic ring or heteroaromatic ring. In the case where X is phosphorus oxide, then Ar represents an aromatic hydrocarbon or heteroaromatic ring. n is an natural number.

  本发明的发光装置涉及一种发光装置，其特征在于它是一种在阳极和阴极之间有发光物质的装置，它通过电能发光，所述装置至少有一种化合物，如下文(a)至(d)所示。 (a) 具有多个 1，7-菲罗啉骨架结构的化合物 (b) 苯并喹啉衍生物 (c) 通式(1)代表的螺环化合物 A1 和 A2 分别选自单键、取代或未取代的烷基链、醚链、硫醚链、酮链和取代或未取代的氨基链。但是，A1≠A2。Z 代表碳或硅。R1 至 R16 各自选自氢、烷基、环烷基、芳烷基、烯基、环烯基、炔基、羟基、巯基、烷氧基、烷硫基、芳基醚基、芳基硫醚基、芳基杂环基、卤素、卤代烷烃、卤代烯烃、卤代炔烃、氰基、醛基、羰基、 羧基、酯基、氨基甲酰基、氨基、硝基、硅烷基、硅氧烷基以及与相邻取代基 形成的环状结构。 (d) 由通式(2)代表的四苯基甲烷衍生物 R17 至 R36 分别选自氢、烷基、环烷基、芳烷基、烯基、环烯基、炔基、羟基、巯基、烷氧基、烷硫基、芳基醚基、芳基硫醚基、芳基、杂环基、卤素、杂环基、卤素、卤代烷烃、卤代烯烃、卤代炔烃、氰基、醛基、羰基、羧基、酯基、氨基甲酰基、氨基、硝基、硅烷基、硅氧烷基以及与相邻取代基形成的环状结构。但 R17 至 R36 中至少有一个选自通式（3）所代表的取代基。 -X-Ar（3） X 是单键或选自下列各项，Ar 表示缩合芳香环或杂芳环。在 X 为氧化磷的情况下，Ar 代表芳香烃或杂芳环。 n 是自然数。
• US6805978B2
  申请人：——

  公开号：US6805978B2

  公开（公告）日：2004-10-19
• US7318966B2
  申请人：——

  公开号：US7318966B2

  公开（公告）日：2008-01-15
• Pyrromethene metal complex and light emitting device composition and light emitting devices using the same
  申请人：——

  公开号：US20030082406A1

  公开（公告）日：2003-05-01

  A pyrromethene metal complex is used as a fluorescent dye to form a light emitting device. The light emitting device has a substance which brings about light emission between an anode and a cathode. By applying electrical energy, the device generates emission having an emission peak wavelength of 580 to 720 nm. The device contains at least one of: a diketopyrrolo[3,4-c]pyrrole derivative and an organic fluorescent material having a fluorescent peak wavelength of 580 to 720 nm; and a light emitting device composition containing a pyrromethene metal complex.

  一种吡咯甲烷金属配合物被用作荧光染料，形成发光装置。发光装置具有一种物质，在阳极和阴极之间引起发光。通过施加电能，该装置产生具有580到720纳米的发射峰波长的发射。该装置包含以下至少一种：二酮吡咯[3,4-c]吡咯衍生物和具有580到720纳米荧光峰波长的有机荧光材料；以及含有吡咯甲烷金属配合物的发光装置组成。