2-(4-vinylbenzylthio)benzo[d]oxazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并恶唑类
• 英文名称: 2-(4-vinylbenzylthio)benzo[d]oxazole
• 英文别名: 2-[(4-Ethenylphenyl)methylsulfanyl]-1,3-benzoxazole
• 化学式: C₁₆H₁₃NOS
• 分子量: 267.351
• InChiKey: HBFVZLNCMLGDCL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  51.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-乙烯基苄基溴 、 2-巯基苯并恶唑 在 potassium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 48.0h， 以80%的产率得到2-(4-vinylbenzylthio)benzo[d]oxazole
  参考文献：
  名称：

  一系列 2-取代苯并 [d] [1,3] 唑的合成、表征和初步体外细胞毒性评估

  摘要：

  合成了一系列被苄基和烯丙基硫烷基 2-取代的苯并 [ d ] [1,3] 唑，并针对一组 6 种人类癌细胞系在体外评估了它们的细胞毒活性。结果表明，化合物BTA-1和BMZ-2的抑制作用最好，化合物BMZ-2在某些情况下与参考药物他莫昔芬相当，对健康细胞的细胞毒性作用较低。在 ERα 和 GPER 受体的他莫昔芬结合位点的计算机分子偶联研究揭示了两种化合物 BTA-1 和 BMZ-2 的亲和力和可能的相互作用模式。

  DOI：

  10.3390/molecules26092780

文献信息

• IR-CUT FILTER AND MANUFACTURING METHOD THEREOF, SOLID STATE IMAGE PICKUP DEVICE, AND LIGHT BLOCKING FILM FORMATION METHOD
  申请人：FUJIFILM Corporation

  公开号：EP2927718A1

  公开（公告）日：2015-10-07

  An IR cut filter for inhibiting occurrences of flare and ghost is provided. A solid-state imaging device comprises a CMOS sensor, a circuit board, a ceramic plate, an IR cut filter, a taking lens, a lens holder, and a support barrel. The CMOS sensor is mounted on the circuit board. The circuit board is fixed to the ceramic plate such that the CMOS sensor is placed inside an opening of the ceramic plate. The sides of the CMOS sensor are surrounded by the ceramic plate. The IR cut filter is fixed to the ceramic plate so as to cover the opening. The CMOS sensor is disposed behind the taking lens. The IR cut filter is disposed between the taking lens and the CMOS sensor. A light-shielding layer is formed over the entire periphery of edge portions of an incident surface of the IR cut filter. Harmful rays such as reflective light is blocked by the light-shielding layer.

  提供了一种用于抑制耀斑和鬼影发生的红外截止滤光片。 固态成像装置包括 CMOS 传感器、电路板、陶瓷板、红外滤光片、取景镜头、镜头支架和支撑筒。CMOS 传感器安装在电路板上。电路板固定在陶瓷板上，使 CMOS 传感器位于陶瓷板的开口内。CMOS 传感器的两侧被陶瓷板包围。红外滤光片固定在陶瓷板上，以覆盖开口。CMOS 传感器位于摄录镜头的后面。红外滤光片位于摄录镜头和 CMOS 传感器之间。在红外滤光片入射面边缘部分的整个外围形成一个遮光层。遮光层可阻挡反射光等有害光线。
• Near-infrared absorption composition, curable composition, cured film, near-infrared cut filter, solid-state imaging device, infrared sensor, camera module, processed coloring agent, and method of manufacturing processed coloring agent
  申请人：FUJIFILM Corporation

  公开号：US10208212B2

  公开（公告）日：2019-02-19

  The near-infrared absorption composition includes a processed coloring agent obtained by coating a near-infrared absorption coloring agent with a resin having one or more selected from a coloring agent structure, a heterocyclic structure, and an acyclic hetero atom-containing group. The near-infrared absorption coloring agent is preferably one or more selected from a phthalocyanine coloring agent, a perylene coloring agent, a pyrrolopyrrole coloring agent, a cyanine coloring agent, a dithiol metal complex coloring agent, a naphthoquinone coloring agent, a diimmonium coloring agent, an azo coloring agent, and a squarylium coloring agent and more preferably a pyrrolopyrrole coloring agent.

  近红外吸收组合物包括一种经过加工的着色剂，该着色剂是通过将一种近红外吸收着色剂涂覆在一种具有选自着色剂结构、杂环结构和含无环杂原子基团中的一种或多种的树脂上而得到的。近红外吸收着色剂最好是选自酞菁着色剂、过烯着色剂、吡咯啉着色剂、氰基着色剂、二硫醇金属络合物着色剂、萘醌着色剂、二铵着色剂、偶氮着色剂和鳞片着色剂中的一种或多种，更优选吡咯啉着色剂。
• Light screening composition
  申请人：FUJIFILM Corporation

  公开号：US10290669B2

  公开（公告）日：2019-05-14

  The present invention is to provide a light screening composition that allow forming of a light screening film having excellent adhesiveness to a substrate and excellent residue removability at the time of development. The light screening composition according to the invention contains (A) any one of light screening particles and a light screening dye; (B) a dispersing resin; (C) a binder polymer having an acid value of 50 mg KOH/g or less and a weight-average molecular weight of 8,000 to 50,000; and (D) a polymerizable compound.

  本发明旨在提供一种光屏蔽组合物，该组合物可形成光屏蔽膜，该膜对基材具有极佳的粘附性，并且在显影时具有极佳的残留物去除性。根据本发明的加光组合物包含：(A) 加光颗粒和加光染料中的任意一种；(B) 分散树脂；(C) 粘结剂聚合物，其酸值为 50 毫克 KOH/g 或以下，重量平均分子量为 8,000 至 50,000；以及 (D) 可聚合化合物。
• Coloring composition, method for producing coloring composition, color filter, pattern forming method, solid-state imaging device, and image display device
  申请人：FUJIFILM Corporation

  公开号：US11002895B2

  公开（公告）日：2021-05-11

  Provided are a coloring composition capable of producing a film having excellent light fastness, and the like, a method for producing a coloring composition, a color filter, a pattern forming method, a solid-state imaging device, and an image display device. The coloring composition includes a coated pigment in which at least a portion of a surface of a yellow pigment is coated with a resin, a halogenated phthalocyanine pigment, a dispersant having an acid value of 40 mgKOH/g or more, and a curable compound.

  本发明提供了一种能够生产出具有优异耐光性的薄膜的着色组合物等、一种着色组合物的生产方法、一种彩色滤光片、一种图案形成方法、一种固态成像装置和一种图像显示装置。该着色组合物包括涂布颜料（其中黄色颜料的至少一部分表面涂有树脂）、卤代酞菁颜料、酸值大于或等于 40 mgKOH/g 的分散剂和固化化合物。
• Pigment dispersion composition, photocurable composition and color filter
  申请人：FUJIFILM Corporation

  公开号：EP2042921B1

  公开（公告）日：2017-10-25