作者:Charles W. Bauschlicher、Mingfei Zhou、Lester Andrews
DOI:10.1021/jp993623b
日期:2000.4.1
The products of the reaction of laser-ablated red phosphorus and dioxygen have been studied using experiment and theory. The bands at 480.3 and 1273.3 cm-l, previously attributed to PO3 in the matrix isolation IR experiments, are reassigned to PO3-. Also observed in experiment are PO2, PO2-, P2O, OPOPO, P4, and higher oxides.
用实验和理论研究了激光烧蚀红磷和分子氧的反应产物。在 480.3 和 1273.3 cm-l 处,先前在基质隔离 IR 实验中归因于 PO3 的波段被重新分配给 PO3-。实验中还观察到 PO2、PO2-、P2O、OPOPO、P4 和更高的氧化物。