1,4,7,10-tetra-1-n-octyl-1,4,7,10-tetraaza-cyclododecane

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4,7,10-tetra-1-n-octyl-1,4,7,10-tetraaza-cyclododecane
• 英文别名: 1,4,7,10-Tetra-n-octyl-1,4,7,10-tetraaza-cyclododecane；1,4,7,10-tetraoctyl-1,4,7,10-tetrazacyclododecane
• 化学式: C₄₀H₈₄N₄
• 分子量: 621.134
• InChiKey: FYZCEVFZLBMWEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.8
• 重原子数：
  44
• 可旋转键数：
  28
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-溴辛烷 、 轮环藤宁 在 sodium hydride 作用下， 以 四氢呋喃 、 mineral oil 为溶剂， 反应 2.25h， 以33%的产率得到1,4,7,10-tetra-1-n-octyl-1,4,7,10-tetraaza-cyclododecane
  参考文献：
  名称：

  A polyazamacrocycle extractant for the extraction of americium and europium

  摘要：

  近年来，用于从镧系元素中分离锕系元素的含氮萃取剂备受关注。在这项研究中，我们合成了一种由四个叔烷基氨基组成的多氮杂环型 C8-环烯配体，用于萃取 Am3+ 和 Eu3+。C8-cyclen 对 Am3+ 和 Eu3+ 的萃取和分离能力较弱，且随着水阴离子 "软度 "的增加而增强。Am3+ 和 Eu3+ 的萃取行为表明，C8-环烯与 Am3+ 和 Eu3+ 离子之间存在配位相互作用。酸对 Am3+ 或 Eu3+ 萃取的抑制作用取决于所涉及的介质阴离子。

  DOI：

  10.1007/s11426-014-5259-8

文献信息

• SYNTHESIS OF 1,4,7,10-TETRA-<i>N</i>-ALKYL-1,4,7,10-TETRAAZA-CYCLODODECANES
  作者：Tom Fricke、Šárka Chrápavá、Burkhard König

  DOI：10.1081/scc-120014970

  日期：2002.1

  ABSTRACT We report a concise method for the preparation of 1,4,7,10-tetra-N-alkyl-1,4,7,10-tetraaza-cyclododecanes via deprotonation to the fourfold lithium amide followed by alkylation with alkyl bromides. The procedure circumvents the problem of ammonium salt formation and provides direct access to hydrophobic 1,4,7,10-tetraaza-cyclododecanes in moderate yield. The so obtained hydrophobic macrocycles

  摘要 我们报告了一种通过去质子化成四重氨基锂然后用烷基溴化物烷基化来制备 1,4,7,10-四-N-烷基-1,4,7,10-四氮杂-环十二烷的简明方法。该程序避免了铵盐形成的问题，并以中等产率直接获得疏水性 1,4,7,10-四氮杂-环十二烷。如此获得的疏水大环被转化为相应的锌（II）、铜（II）、镍（II）和钴（II）配合物，它们可用作催化和阴离子提取中的水稳定路易斯酸。
• ELECTROPHORESIS DISPERSION LIQUID, ELECTROPHORESIS SHEET, ELECTROPHORESIS DEVICE, AND ELECTRONIC APPARATUS
  申请人：Seiko Epson Corporation

  公开号：EP3081984A2

  公开（公告）日：2016-10-19

  An electrophoresis dispersion liquid includes first electrophoretic particle of a scattering system having an ionic group on a surface thereof; second electrophoretic particle of a coloring system having a polarization group on the surface thereof; and a dispersion medium. It is preferable that the ionic group is an acidic group, and further includes a ring structure that forms an acidic group and a salt. It is preferable that the polarization group is an organic group having a main skeleton, and a substituent bonded to the main skeleton.

  电泳分散液包括散射体系的第一电泳粒子，其表面带有离子基团；着色体系的第二电泳粒子，其表面带有极化基团；以及分散介质。离子基团最好是酸性基团，并进一步包括形成酸性基团和盐的环状结构。偏振基团最好是具有主骨架和与主骨架键合的取代基的有机基团。
• Electrophoretic particle, method of manufacturing electrophoretic particle, electrophoresis dispersion liquid, electrophoresis sheet, electrophoresis device, and electronic apparatus
  申请人：Seiko Epson Corporation

  公开号：US10113072B2

  公开（公告）日：2018-10-30

  An electrophoretic particle includes a base particle (particle), a first compound, a second compound, and a third compound bonded to the base particle. The first compound is a polymer having a dispersion portion derived from a first monomer, and a bonding portion derived from a second monomer, and is connected to the base particle at the bonding portion. The second compound includes a non-polar group and a second functional group and is connected to the base particle at the second functional group. The third compound includes a charging group and a second functional group and is connected to the base particle at the second functional group.

  电泳粒子包括基粒（颗粒）、第一化合物、第二化合物和与基粒粘合的第三化合物。第一种化合物是一种聚合物，其分散部分来自第一种单体，粘合部分来自第二种单体，并在粘合部分与基质颗粒相连。第二种化合物包括一个非极性基团和一个第二官能团，并在第二官能团处与基质颗粒相连。第三种化合物包括一个带电基团和一个第二官能团，并在第二官能团处与基质颗粒相连。
• ELECTROPHORETIC PARTICLE, METHOD OF MANUFACTURING ELECTROPHORETIC PARTICLE, ELECTROPHORESIS DISPERSION LIQUID, ELECTROPHORESIS SHEET, ELECTROPHORESIS DEVICE, AND ELECTRONIC APPARATUS
  申请人：Seiko Epson Corporation

  公开号：US20170081528A1

  公开（公告）日：2017-03-23

  An electrophoretic particle includes a base particle (particle), a first compound, a second compound, and a third compound bonded to the base particle. The first compound is a polymer having a dispersion portion derived from a first monomer, and a bonding portion derived from a second monomer, and is connected to the base particle at the bonding portion. The second compound includes a non-polar group and a second functional group and is connected to the base particle at the second functional group. The third compound includes a charging group and a second functional group and is connected to the base particle at the second functional group.
• US9804472B2
  申请人：——

  公开号：US9804472B2

  公开（公告）日：2017-10-31