双(2,4,6-三甲基苯基)汞 | 26562-17-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 双(2,4,6-三甲基苯基)汞
• 中文别名: 注:订此产品需国际运费$30
• 英文名称: dimesitylmercury
• 英文别名: Hg(2,4,6-trimethylphenyl)2；{2,4,6-(CH3)3C6H2}2Hg；[Hg(mesityl)2]；Dimesityl-quecksilber；Bis-(2.4.6-trimethyl-phenyl)-quecksilber；bismesityl mercury
• CAS: 26562-17-4
• 化学式: C₁₈H₂₂Hg
• 分子量: 438.963
• InChiKey: PCCZBLRWVAPBFR-UHFFFAOYSA-N

物化性质

• 熔点：
  235 °C

计算性质

• 辛醇/水分配系数(LogP)：
  3.57
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  双(2,4,6-三甲基苯基)汞 以 乙腈 为溶剂， 生成 trichloro(mesityl)stannane
  参考文献：
  名称：

  Berwe, Hermann; Haas, Alois, Chemische Berichte, 1987, vol. 120, p. 1175 - 1182

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 、 sodium iodide 作用下， 生成 双(2,4,6-三甲基苯基)汞
  参考文献：
  名称：

  The Interconversion of Arylmercuric Halides and Diarylmercury Compounds. I

  摘要：

  DOI：

  10.1021/ja01330a044

文献信息

• Crystal Structures and Chemical Properties of Dimesitylcadmium and Dimesitylmercury
  作者：Mari Hayashi、Michael Bolte、Matthias Wagner、Hans-Wolfram Lerner

  DOI：10.1002/zaac.201100049

  日期：2011.5

  Mesityllithium was used to synthesize dimesitylcadmium and dimesitylmercury from CdCl2 and HgCl2, respectively. X-ray-crystallographic data show that the group 12 metal compounds M[Mes]2 (M = Zn, Cd, Hg) are isomorphous (monoclinic, P21/n). The asymmetric unit of M[Mes]2 (M = Zn, Cd, Hg) consists of one mesityl group bonded to the metal atom, which is related to the second substituent by an inversion

  Mesityllithium 用于分别从 CdCl2 和 HgCl2 合成二甲苯镉和二甲苯汞。X 射线晶体学数据显示第 12 族金属化合物 M[Mes]2（M = Zn、Cd、Hg）是同晶的（单斜晶系，P21/n）。M[Mes]2 的不对称单元（M = Zn、Cd、Hg）由一个与金属原子键合的均三甲苯基团组成，该基团通过反转中心与第二个取代基相关。此外，我们研究了 BBr3 与 M[Mes]2 (M = Cd, Hg) 的反应，以了解无供体组 12 甲基化合物的反应性。M[Mes]2 (M = Cd, Hg) 与过量的 BBr3 反应生成 MesBBr2。紫外诱导的苯中 Hg[Mes]2 转化产生了定量的均三甲苯和汞，而将 Hg[Mes]2 的氯仿溶液照射 1290 分钟（λmax = 510 nm）得到均三甲苯、Hg[Mes]Cl、和 HgCl2 的比例为 6:4:1。反应溶液的缓慢浓缩导致两个
• Facile syntheses of homoleptic diarylmercurials via arylboronic acids
  作者：David V. Partyka、Thomas G. Gray

  DOI：10.1016/j.jorganchem.2008.10.024

  日期：2009.1

  A general procedure for the syntheses of diarylmercurials is presented. Reactions proceeded in isopropanol in the presence of a base and arylboronic acid. With one exception, all reactions proceeded in good to excellent yields, and this procedure was applicable to a variety of aromatic and heteroaromatic boronic acids. Products were characterized by multinuclear NMR spectroscopy and microanalysis, and investigated by DFT calculations. The structure of di(4-pyridyl) mercury (6) was further authenticated by X-ray crystallography. Combined with previous work on the formation of arylgold(I) complexes via arylboronic acids, this procedure may be generally useful for the arylation of late transition metals. (C) 2008 Elsevier B. V. All rights reserved.
• Mesityl gold(III) complexes. X-ray structure of mononuclear [Au(mes)2Cl(PPh3)] and the dimer [Au(mes)2Cl]2
  作者：Marı́a Contel、Andrew J Edwards、Julián Garrido、Michael B Hursthouse、Mariano Laguna、Raquel Terroba

  DOI：10.1016/s0022-328x(00)00306-5

  日期：2000.8

  The reaction between PPN[AuCl4] and [Hg(mes)(2)] gives the anionic complex cis-PPN[Au(mes)(2)Cl-2] (1) and [Hg(mes)Cl] as side-product. Complex 1 is a precursor to other compounds both neutral and cationic. Removal of one chloride ligand affords the mononuclear neutral complexes cis-[Au(mes)(2)ClL] (L = PPh3 (2), Pp-tol}(3) (3), AsPh3 (4), SPPh3 (5)) by addition of a neutral ligand or, alternatively if no ligand is added, dimeric cis-[Au(mes)(2)Cl](2) (6). If both chloride groups in 1 are removed, cationic compounds can be obtained by addition of a potentially bidentate ligand affording cis-[Au(mes)(2)(L-L)]X complexes (X = ClO4, L-L = bipy (7), L-L = phen (8), L-L = dppe (9) X = SO3CF3, L-L = dppm (10)). Dithiocarbamate- or acetate salts can be added to solutions of 'Au(mes)(2)X' (obtained by removal of two chloride anions in 1) leading to the neutral compounds cis-[Au(mes),(L-L)] (L-L = S2CNR2 (R = Me (11), Et (12), Bz (13)), O2CCF3 (14)). The structures of cis-[Au(mes)(2)Cl(PPh3)] (2) and cis-[Au(mes)(2)Cl](2) (6) have been established by an X-ray diffraction study. (C) 2000 Elsevier Science S.A. All rights reserved.
• Some platinum(II) and iridium(III) complexes with direct mercury-hydrogen bonds
  作者：Brian S. McGilligan、Luigi M. Venanzi、Martin Wolfer

  DOI：10.1021/om00148a009

  日期：1987.5
• Coupling reaction of organomercury compounds with aryl halides catalyzed by palladium complexes
  作者：N. A. Bumagin、I. O. Kalinovskii、I. P. Beletskaya

  DOI：10.1007/bf00954359

  日期：1983.7