5-(ethylthio)carbonyloxy-1-methylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenyl ketone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-(ethylthio)carbonyloxy-1-methylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenyl ketone
• 英文别名: 5-(ethylthio)carbonyloxy-1-methylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenylketone；5-(Ethylthio)carbonyloxy-1-methylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenyl ketone；methyl 3-(5-ethylsulfanylcarbonyloxy-1-methylpyrazole-4-carbonyl)-2-methyl-6-methylsulfonylbenzoate
• 化学式: C₁₈H₂₀N₂O₇S₂
• 分子量: 440.498
• InChiKey: CNWUBVZFJJOBPD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  29
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  155
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  5-Hydroxy-1-ethylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenyl ketone 、 硫代氯甲酸乙酯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 1.5h， 以66%的产率得到5-(ethylthio)carbonyloxy-1-methylpyrazol-4-yl 3-(methoxycarbonyl)-2-methyl-4-(methylsulfonyl)phenyl ketone
  参考文献：
  名称：

  WO2007/69771

  摘要：

  公开号：

文献信息

• BENZOYLPYRAZOLE COMPOUNDS AND HERBICIDES CONTAINING THEM
  申请人：Shimoharada Hiroshi

  公开号：US20090286683A1

  公开（公告）日：2009-11-19

  A benzoylpyrazole compound represented by the formula (I) or its salt, useful as herbicides and intermediates thereof.

  一种苯甲酰吡唑化合物，其化学式为（I）或其盐，可用作除草剂及其中间体。
• HERBICIDAL COMPOSITIONS CONTAINING BENZOYLPYRAZOLE COMPOUNDS
  申请人：Shimoharada Hiroshi

  公开号：US20100099563A1

  公开（公告）日：2010-04-22

  To provide a herbicidal composition which can be applied at a low dose as compared with individual application, and thus is effective to reduce the environmental load on a place where the composition is applied or a periphery thereof, of which the herbicidal spectrum is enlarged, and of which the herbicidal effects last over a long period of time. A herbicidal composition which comprises as active ingredients (a) a herbicidal benzoylpyrazole compound represented by the formula (I) or its salt: wherein Q is —C(O)SR 3 or a hydrogen atom, R 1 is alkyl or cycloalkyl, R 2 is a hydrogen atom or alkyl, R 3 is alkyl, cycloalkyl or the like, R 4 is alkyl, haloalkyl or the like, R 5 is a hydrogen atom, alkyl or the like, R 6 is haloalkyl, halogen or the like, and (b) other herbicidal compound.

  提供一种除草剂组合物，可与单独应用相比低剂量使用，因此可有效减少组合物应用地点或周围环境的负荷，其除草谱系扩大，除草效果持续时间长。该除草剂组合物包含以下活性成分：（a）由式（I）或其盐表示的除草苯甲酰吡唑化合物，其中Q为—C（O）SR3或氢原子，R1为烷基或环烷基，R2为氢原子或烷基，R3为烷基、环烷基或类似基团，R4为烷基、卤代烷基或类似基团，R5为氢原子、烷基或类似基团，R6为卤代烷基、卤素或类似基团，以及（b）其他除草化合物。
• Benzoylpyrazole compounds and herbicides containing them
  申请人：Ishihara Sangyo Kaisha, Ltd.

  公开号：US08030498B2

  公开（公告）日：2011-10-04

  A benzoylpyrazole compound represented by the formula (I) or its salt, useful as herbicides and intermediates thereof.

  一种苯甲酰吡唑化合物，其化学式为（I）或其盐，可用作除草剂及其中间体。
• Herbicidal compositions containing benzoylpyrazole compounds
  申请人：Shimoharada Hiroshi

  公开号：US08466088B2

  公开（公告）日：2013-06-18

  Provided is an herbicidal composition which can be applied at a low dose as compared with individual application, and thus is effective to reduce the environmental load on a place where the composition is applied or a periphery thereof, of which the herbicidal spectrum is enlarged, and of which the herbicidal effects last over a long period of time. The herbicidal composition has as active ingredients (a) a herbicidal benzoylpyrazole compound represented by the formula (I) or its salt: wherein Q is —C(O)SR3 or a hydrogen atom, R1 is alkyl or cycloalkyl, R2 is a hydrogen atom or alkyl, R3 is alkyl, cycloalkyl or the like, R4 is alkyl, haloalkyl or the like, R5 is a hydrogen atom, alkyl or the like, R6 is haloalkyl, halogen or the like, and (b) a further herbicidal compound.

  提供了一种除草组合物，与单独应用相比，可以以低剂量应用，因此有效减少了组合物应用地点或其周围的环境负荷，其除草谱增大，且除草效果持续时间长。该除草组合物的活性成分为（a）表示为式（I）或其盐的除草苯甲酰吡唑化合物：其中Q为—C(O)SR3或氢原子，R1为烷基或环烷基，R2为氢原子或烷基，R3为烷基、环烷基或类似物，R4为烷基、卤代烷基或类似物，R5为氢原子、烷基或类似物，R6为卤代烷基、卤素或类似物，以及（b）进一步的除草化合物。
• EP2106697
  申请人：——

  公开号：——

  公开（公告）日：——