双(4-吡啶甲基)二硫化物 | 1020-71-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 双(4-吡啶甲基)二硫化物
• 英文名称: Bis--disulfid
• 英文别名: 4,4'-(Dithiodimethylene)dipyridine；4-[(pyridin-4-ylmethyldisulfanyl)methyl]pyridine
• CAS: 1020-71-9
• 化学式: C₁₂H₁₂N₂S₂
• 分子量: 248.373
• InChiKey: DAVWLGVBAUGEOK-UHFFFAOYSA-N

物化性质

• 熔点：
  157-158 °C
• 沸点：
  422.4±40.0 °C(Predicted)
• 密度：
  1.258±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  16
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  76.4
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2933399090

反应信息

• 作为反应物：
  描述：

  双(4-吡啶甲基)二硫化物 在 盐酸 作用下， 以 乙醚 、 正丁醇 为溶剂， 生成 bis(4-pyridylmethyl)disulphide dihydrochloride
  参考文献：
  名称：

  N-Heterocyclic compounds as radioprotectors II. Derivatives of pyridine and pyrimidine containing thiol precursors

  摘要：

  DOI：

  10.1016/0223-5234(88)90001-3
• 作为产物：
  描述：

  4-氯甲基吡啶盐酸盐 在 ammonium hydroxide 、 碘 作用下， 以 甲醇 为溶剂， 反应 1.5h， 生成 双(4-吡啶甲基)二硫化物
  参考文献：
  名称：

  N-Heterocyclic compounds as radioprotectors II. Derivatives of pyridine and pyrimidine containing thiol precursors

  摘要：

  DOI：

  10.1016/0223-5234(88)90001-3

文献信息

• Gold nanocluster confined within a cage: template-directed formation of a hexaporphyrin cage and its confinement capability
  作者：Tomohiko Inomata、Katsuaki Konishi

  DOI：10.1039/b302609d

  日期：——

  A novel container complex in which a 1.4 nm gold cluster is confined within a hexaporphyrin cage was synthesized; the cage showed notable confinement capability for the cluster core, but allowed the interpenetration of small molecules into the interstitial space.

  我们合成了一种新型的容器复合物，其中 1.4 nm 的金簇被限制在六卟啉笼中；该笼对金簇核心具有显著的限制能力，但允许小分子穿透进入间隙空间。
• A novel coordination polymer [Co(NCS)2(bpms)2]n (bpms=1,2-bis(4-pyridylmethyl)disulfenyl): synthesis, crystal structure and third-order nonlinear optical properties
  作者：Hongwei Hou、Yinglin Song、Yaoting Fan、Linping Zhang、Chenxia Du、Yu Zhu

  DOI：10.1016/s0020-1693(01)00391-7

  日期：2001.5

  A new 4,4'-bipyridyl-based 'building block', 1,2-bis(4-pyridylmethyl)disulfenyl (bpms) was synthesized. Treatment of the 'building block' with Co(NO,), and KSCN afforded a new type of one-dimensional (1-D) double zigzag chain coordination polymer [Co(NCS)(2)(bpms)(2)](n). Each Co ion is symmetrically bridged by four bpms ligands and also coordinates with two NCS anions. The [Co(NCS)(2)(bpms)(2)](n) can be regarded as a layered structure in the solid state. The 1-D parallel chains are stacked ABAB with a rotation of 90 degrees between A and B. [Co(NCS)(2)(bpms)(2)](n) in DMF solution also shows very strong third-order nonlinear optical (NLO) properties, its third-order susceptibility chi ((3)) is 1.07 x 10(-11) esu in a 2.8 x 10(-3) g cm(-3). DMF solution. The data are comparable to those of C60, phthalocyanine derivations and inorganic clusters. To our knowledge, this is the first reported coordination polymer showing strong third-order NLO properties. (C) 2001 Elsevier Science B.V. All rights reserved.
• BARNES, JOHN H.;FATOME, MARC;JONES, CHRISTOPHER E. L.;MURRAY, STEPHEN G., EUR. J. MED. CHEM., 23,(1988) N 3, 211-216
  作者：BARNES, JOHN H.、FATOME, MARC、JONES, CHRISTOPHER E. L.、MURRAY, STEPHEN G.

  DOI：——

  日期：——