Benzaldehyde, 4-nitro-, 4-methylphenylhydrazone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Benzaldehyde, 4-nitro-, 4-methylphenylhydrazone
• 英文别名: 4-methyl-N-[(E)-(4-nitrophenyl)methylideneamino]aniline
• 化学式: C₁₄H₁₃N₃O₂
• 分子量: 255.276
• InChiKey: UKTPEXMIAYMJOY-XNTDXEJSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  70.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Benzaldehyde, 4-nitro-, 4-methylphenylhydrazone 、 p-methylbenzenediazonium chloride 在 sodium hydroxide 、 sodium acetate 作用下， 以 甲醇 、 水 为溶剂， 反应 5.5h， 以2.1 g的产率得到3-p-nitrophenyl-1,5-di-p-tolylformazan
  参考文献：
  名称：

  Electrochemical Studies of Verdazyl Radicals

  摘要：

  The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and reduction potentials as well as the cell potential (E-cell = |E-ox(degrees) - E-red(degrees)|) for these radicals; a correlation between the electron spin distribution and redox properties is developed.

  DOI：

  10.1021/ol702163a
• 作为产物：
  描述：

  4-甲基苯肼盐酸盐 、 对硝基苯甲醛 在 三乙胺 作用下， 以 甲醇 为溶剂， 反应 0.5h， 生成 Benzaldehyde, 4-nitro-, 4-methylphenylhydrazone
  参考文献：
  名称：

  Electrochemical Studies of Verdazyl Radicals

  摘要：

  The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and reduction potentials as well as the cell potential (E-cell = |E-ox(degrees) - E-red(degrees)|) for these radicals; a correlation between the electron spin distribution and redox properties is developed.

  DOI：

  10.1021/ol702163a

文献信息

• Electrochemical Studies of Verdazyl Radicals
  作者：Joe B. Gilroy、Stephen D. J. McKinnon、Bryan D. Koivisto、Robin G. Hicks

  DOI：10.1021/ol702163a

  日期：2007.11.1

  The redox properties of verdazyl radicals are presented using cyclic voltammetry techniques. These radicals can be reversibly reduced as well as oxidized. Electron-donating and -withdrawing substituents have significant effects on the oxidation and reduction potentials as well as the cell potential (E-cell = |E-ox(degrees) - E-red(degrees)|) for these radicals; a correlation between the electron spin distribution and redox properties is developed.